konjes

Konya Journal of Engineering Sciences

2667-8055

Konya Technical University

10.36306/konjes.1558191

Architectural Engineering Construction Materials

Mimari Mühendislik Yapı Malzemeleri

CHARACTERIZATION OF EPOXY RESIN AND SILLE STONE POWDER BASED COMPOSITE MORTARS

https://orcid.org/0000-0002-4690-8968

Arı

Ahmet Cihat

BOZOK ÜNİVERSİTESİ

https://orcid.org/0000-0002-0718-4100

Tosun

Mustafa

KONYA TEKNİK ÜNİVERSİTESİ

03 01 2025

13 1 74 97 09 30 2024 01 07 2025

2004

Konya Journal of Engineering Sciences

Sille stone, extracted from the Sille region of Konya (Türkiye) province, is an andesitic stone used in the construction of historical buildings. Sille stone is subject to deterioration due to long-term natural and environmental factors. Repair mortars are used to prevent damage to the stones used in the construction of historical buildings. In this study, Epoxy resin (ER)/Sille stone powder (SSP) composite mortars were produced for the restoration of historical buildings and the properties of these composite mortars were investigated. In the production of composite mortars were prepared by contributing SSP into epoxy resin in varied ratios such as 60-75% wt.%. When 60% SSP filler was added to the ER matrix, the compressive strength of the resulting composite increased by approximately 66% compared to neat ER. Moreover, an increase in mechanical strength and a decrease in water absorption were observed in composite mortars due to the increase in SSP. In conclusion, the high strength, low water absorption rate and pore properties of epoxy matrix composite mortars provide great potential for restoration applications of historical buildings constructed from Sille stone.

Characterization Composite Mortar Cultural Heritage Sille Stone

Konya Technical University

211120045

A. Isebaert, L. Van Parys, and V. Cnudde, "Composition and compatibility requirements of mineral repair mortars for stone–A review," Construction and Building Materials, vol. 59, pp. 39-50, 2014.

L. Schueremans, Ö. Cizer, E. Janssens, G. Serré, and K. Van Balen, "Characterization of repair mortars for the assessment of their compatibility in restoration projects: Research and practice," Construction and building materials, vol. 25, no. 12, pp. 4338-4350, 2011.

J.-D. Mertz, M. Guiavarc’h, and P. Pagnin, "Dilation behaviour of lime mortars for restoration work: application to the compatibility of cracked stone reassembling," European Journal of Environmental and Civil Engineering, vol. 16, no. 5, pp. 527-542, 2012.

M. Fener and İ. İnce, "Effects of the freeze–thaw (F–T) cycle on the andesitic rocks (Sille-Konya/Turkey) used in construction building," Journal of African Earth Sciences, vol. 109, pp. 96-106, 2015.

M. E. Hatır, "Determining the weathering classification of stone cultural heritage via the analytic hierarchy process and fuzzy inference system," Journal of Cultural Heritage, vol. 44, pp. 120-134, 2020.

M. E. Hatır, M. Barstuğan, and I. İnce, "Deep learning-based weathering type recognition in historical stone monuments," Journal of Cultural Heritage, vol. 45, pp. 193-203, 2020.

M. Korkanç et al., "Interpreting sulfated crusts on natural building stones using sulfur contour maps and infrared thermography," Environmental Earth Sciences, vol. 78, pp. 378, 2019.

A. Ozdemir, "Capillary water absorption potential of some building materials," Geological Engineering, vol. 26, no. 1, pp. 19-32, 2002.

V. Zedef, K. Kocak, A. Doyen, H. Ozsen, and B. Kekec, "Effect of salt crystallization on stones of historical buildings and monuments, Konya, Central Turkey," Building and Environment, vol. 42, no. 3, pp. 1453-1457, 2007.

Ç. Öztürk, S. Akpınar, and M. Tarhan, "Investigation of the usability of Sille stone as additive in floor tiles," Journal of the Australian Ceramic Society, vol. 57, pp. 567-577, 2021.

J. Lanas, J. P. Bernal, M. Bello, and J. A. Galindo, "Mechanical properties of natural hydraulic lime-based mortars," Cement and concrete research, vol. 34, no. 12, pp. 2191-2201, 2004.

E. Navrátilová and P. Rovnaníková, "Pozzolanic properties of brick powders and their effect on the properties of modified lime mortars," Construction and Building Materials, vol. 120, pp. 530-539, 2016.

Y. Zeng, B. Zhang, and X. Liang, "A case study and mechanism investigation of typical mortars used on ancient architecture in China," Thermochimica Acta, vol. 473, no. 1-2, pp. 1-6, 2008.

G. F. Huseien and K. W. Shah, "Performance evaluation of alkali-activated mortars containing industrial wastes as surface repair materials," Journal of Building Engineering, vol. 30, p. 101234, 2020.

R. A. Alves, K. Strecker, R. B. Pereira, and T. H. Panzera, "Mixture design applied to the development of composites for steatite historical monuments restoration," Journal of Cultural Heritage, vol. 45, pp. 152-159, 2020.

B. Dębska and L. Lichołai, "A study of the effect of corrosive solutions on selected physical properties of modified epoxy mortars," Construction and Building Materials, vol. 65, pp. 604-611, 2014.

E. Tesser, L. Lazzarini, and S. Bracci, "Investigation on the chemical structure and ageing transformations of the cycloaliphatic epoxy resin EP2101 used as stone consolidant," Journal of Cultural Heritage, vol. 31, pp. 72-82, 2018.

E. M. Alonso-Villar, T. Rivas, and J. S. Pozo-Antonio, "Adhesives applied to granite cultural heritage: effectiveness, harmful effects and reversibility," Construction and Building Materials, vol. 223, pp. 951-964, 2019.

J.-L. Roig-Salom, M.-T. Doménech-Carbó, J. de la Cruz-Cañizares, F. Bolívar-Galiano, M.-J. Pelufo-Carbonell, and Y. Peraza-Zurita, "SEM/EDX and vis spectrophotometry study of the stability of resin-bound mortars used for casting replicas and filling missing parts of historic stone fountains," Analytical and bioanalytical chemistry, vol. 375, pp. 1176-1181, 2003.

A. C. Ari, M. Tosun, and Y. R. Eker, "Polymer matrix and stone powder based composite mortar for the restoration of sille stone structures," Studies in Conservation, vol. 69, no. 1, pp. 50-57, 2024.

F. Güyer et al., "Konya İli Çevre Jeolojisi ve Doğal Kaynaklar," MTA Rap, no. 42149, 1998.

A. C. Arı, M. Tosun, İ. Oral, and Y. R. Eker, "Ultrasonic characterization of polymer based sille stone powder composite mortars," Turkish Journal of Civil Engineering, vol. 35, no. 3, pp. 21-46, 2024.

ASTM-D2734, Standard test method for void content of reinforced plastics, 2009.

URL1. (19.07.2022). Available: https://www.erbakan.edu.tr/bitam/sayfa/3297.

ASTM-D570, Standard test method for water absorptionof plastics, 2005.

ASTM-D790, Standard test methods for flexural properties of unreinforced and reinforced plastics and electrical insulating materials, 2000.

ASTM-D695, Standard test method for compressive properties of polymer matrix composite materials, 2010.

ASTM-D638, Standard test method for tensile properties of plastic, 2005.

ASTM-D2240, Standard test method for rubber property-durometer hardness, 2010.

J. Lanas and J. I. Alvarez-Galindo, "Masonry repair lime-based mortars: factors affecting the mechanical behavior," Cement and concrete research, vol. 33, no. 11, pp. 1867-1876, 2003.

Á. Török and B. Szemerey-Kiss, "Freeze-thaw durability of repair mortars and porous limestone: compatibility issues," Progress in Earth and Planetary Science, vol. 6, pp. 42, 2019.

Z. Zheng, Y. Li, X. Ma, X. Zhu, and S. Li, "High density and high strength cement-based mortar by modification with epoxy resin emulsion," Construction and Building Materials, vol. 197, pp. 319-330, 2019.

L. Korat, B. Mirtič, A. Mladenovič, A. M. Pranjić, and S. Kramar, "Formulation and microstructural evaluation of tuff repair mortar," Journal of Cultural Heritage, vol. 16, no. 5, pp. 705-711, 2015.

M. M. Rahman and M. A. Islam, "Effect of epoxy resin on the intrinsic properties of masonry mortars," Iranian Polymer Journal, vol. 21, pp. 621-629, 2012.

V. Rajput, S. K. Somani, A. Agrawal, and V. S. Pagey, "Mechanical properties of epoxy composites filled with micro-sized kota stone dust," Materials Today: Proceedings, vol. 47, pp. 2673-2676, 2021.

R. Karthikeyan, R. Girimurugan, G. Sahoo, P. Maheskumar, and A. Ramesh, "Experimental investigations on tensile and flexural properties of epoxy resin matrix waste marble dust and tamarind shell particles reinforced bio-composites," Materials Today: Proceedings, vol. 68, pp. 2215-2219, 2022.

M. L. P. Gomes, E. A. Carvalho, L. N. Sobrinho, S. N. Monteiro, R. J. Rodriguez, and C. M. F. Vieira, "Production and characterization of a novel artificial stone using brick residue and quarry dust in epoxy matrix," Journal of materials research and technology, vol. 7, no. 4, pp. 492-498, 2018.

K. A. Gour, R. Ramadoss, and T. Selvaraj, "Revamping the traditional air lime mortar using the natural polymer–Areca nut for restoration application," Construction and Building Materials, vol. 164, pp. 255-264, 2018.

F. Iucolano, B. Liguori, and C. Colella, "Fibre-reinforced lime-based mortars: A possible resource for ancient masonry restoration," Construction and Building Materials, vol. 38, pp. 785-789, 2013.

J. A. V. Gonçalves, D. A. T. Campos, G. d. J. Oliveira, M. d. L. d. S. Rosa, and M. A. Macêdo, "Mechanical properties of epoxy resin based on granite stone powder from the Sergipe fold-and-thrust belt composites," Materials Research, vol. 17, no. 4, pp. 878-887, 2014.

M. L. Santarelli, F. Sbardella, M. Zuena, J. Tirillò, and F. Sarasini, "Basalt fiber reinforced natural hydraulic lime mortars: A potential bio-based material for restoration," Materials & Design, vol. 63, pp. 398-406, 2014.

B. Kekeç, "Investigation of the texture, physical and mechanical properties of the rocks used as building stone," Seljuk University Graduate School of Natural Sciences, MS Thesis, Konya, 2005.

C. Borsellino, L. Calabrese, and G. Di Bella, "Effects of powder concentration and type of resin on the performance of marble composite structures," Construction and Building Materials, vol. 23, no. 5, pp. 1915-1921, 2009.

D. Olmos, A. Aznar, and J. González-Benito, "Kinetic study of the epoxy curing at the silica particles/epoxy interface using the fluorescence of pyrene label," Polymer testing, vol. 24, no. 3, pp. 275-283, 2005.

M. A. R. Bhutta, "Effects of polymer–cement ratio and accelerated curing on flexural behavior of hardener-free epoxy-modified mortar panels," Materials and structures, vol. 43, pp. 429-439, 2010.

K. Hassan, P. Robery, and L. Al-Alawi, "Effect of hot-dry curing environment on the intrinsic properties of repair materials," Cement and Concrete Composites, vol. 22, no. 6, pp. 453-458, 2000.

A. Mallat and A. Alliche, "Mechanical investigation of two fiber-reinforced repair mortars and the repaired system," Construction and building materials, vol. 25, no. 4, pp. 1587-1595, 2011.

M. Medeiros, P. Helene, and S. Selmo, "Influence of EVA and acrylate polymers on some mechanical properties of cementitious repair mortars," Construction and building materials, vol. 23, no. 7, pp. 2527-2533, 2009.

S.-Y. Fu, X.-Q. Feng, B. Lauke, and Y.-W. Mai, "Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites," Composites Part B: Engineering, vol. 39, no. 6, pp. 933-961, 2008.

T. T. L. Doan, H. M. Brodowsky, U. Gohs, and E. Mäder, "Re‐use of marble stone powders in producing unsaturated polyester composites," Advanced Engineering Materials, vol. 20, no. 7, p. 1701061, 2018.

S. Ramesh, K. H. Leen, K. Kumutha, and A. Arof, "FTIR studies of PVC/PMMA blend based polymer electrolytes," Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 66, no. 4-5, pp. 1237-1242, 2007.

M. R. Reddy, A. Subrahmanyam, M. M. Reddy, J. S. Kumar, V. Kamalaker, and M. J. Reddy, "X-RD, SEM, FT-IR, DSC Studies of Polymer Blend Films of PMMA and PEO," Materials Today: Proceedings, vol. 3, no. 10, pp. 3713-3718, 2016.

M. R. M. Hafiezal, A. Khalina, Z. A. Zurina, M. D. M. Azaman, and Z. M. Hanafee, "Thermal and flammability characteristics of blended jatropha bio-epoxy as matrix in carbon fiber–reinforced polymer," Journal of Composites Science, vol. 3, no. 1, pp. 6, 2019.

F. Kasim, M. Mahdi, J. Hassan, S. Al-Ani, and S. Kasim, "Preparation and optical properties of CdS/Epoxy nanocomposites," International Journal of Nanoelectronics and Materials, vol. 5, pp. 57-66, 2012.

G. Nikolic, S. Zlatkovic, M. Cakic, S. Cakic, C. Lacnjevac, and Z. Rajic, "Fast fourier transform IR characterization of epoxy GY systems crosslinked with aliphatic and cycloaliphatic EH polyamine adducts," Sensors, vol. 10, no. 1, pp. 684-696, 2010.

A. Carrillo-Castillo and J. G. Osuna-Alarcón, "Preparation and characterization of hybrid materials of epoxy resin type bisphenol a with silicon and titanium oxides by sol gel process," Journal of the Mexican Chemical Society, vol. 55, no. 4, pp. 233-237, 2011.