Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites

Seyfullah Madakbaş; Memet Vezir Kahraman; Ferhat Şen; Kadir Esmer

doi:10.7240/201332503

Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites

Year 2013, Volume: 25 Issue: 3, 134 - 139, 27.12.2013

Seyfullah Madakbaş Memet Vezir Kahraman Ferhat Şen Kadir Esmer

Abstract

The aim of this study was to improve thermal properties of polypyrrole and polyacrylonitrile. For this purpose, polypyrrole and polyacrylonitrile / clay composites were prepared by different methods. The thermal properties of the prepared composites were examined by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques. The results obtained showed that thermal properties of the composites were a significantly increased with the increase in clay content in the formulation of composite.

Keywords

Conductive polymers;polypyrrole;polyacrylonitrile;clay;composites;thermal properties

References

Goh, S.H., Chan, H.S.O. ve Ong, C.H. (1998). Miscible blends of conductive polyaniline with tertiary amide polymers. J. Appl. Polym. Sci., 68, 1839-1844.
Chen, K.H. ve Yang, S.M. (2003). Polyaniline-montmorillonite composite synthesized by electrochemical method. Synth. Met., 135, 151-152.
Omastova, M. ve Micusık, M. (2012). Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation. Chem. Pap., 66, 392-414.
Chang, L.T. ve Yen, C.C. (1995). Studies on the preparation and properties of conductive polymers. VIII. Use of heat treatment to prepare metallized films from silver chelate of PVA and PAN. J. Appl. Polym. Sci., 55, 371-374.
Madakbaş, S., Çakmakçı, E., Kahraman, M.V. ve Esmer, K. (2013). Preparation, characterisation, and dielectric properties of polypyrrole-clay composites. Chem. Pap., 67, 1048-1053.
Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang, C.K. ve Heeger, A.J. (1977). Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x . J. Chem. Soc. Chem. Com., 16, 578-580.
Pant, H.C., Patra, M.K., Negi, S.C., Bhatia, A., Vadera, S.R. ve Kumar, N. (2006). Studies on conductivity and dielectric properties of polyaniline-zinc sulphide composites. Bull. Mater. Sci. 29, 379-384.
Madakbaş¸ S., Çakmakçı, E., Kahraman, M.V. (2013). Preparation and thermal properties of polyacrylonitrile/hexagonal boron nitride composites. Thermochim. Acta, 552, 1-4. Şen, F. Ve Kahraman, M.V. (2013). Preparation and Properties of Nano Diamond / 6FBisphenol A Based Cyanate Ester Composites. Polym. Composite., 34, 1977-1985.

Polipirol ve Poliakrilonitril / Kil Kompozitlerin Hazırlanması ve Termal Özelliklerinin İncelenmesi

Year 2013, Volume: 25 Issue: 3, 134 - 139, 27.12.2013

Seyfullah Madakbaş Memet Vezir Kahraman Ferhat Şen Kadir Esmer

Abstract

Bu çalışmada polipirol ve poliakrilonitrilin termal özelliklerinin geliştirilmesi amaçlandı. Bu amaç için polipirol ve poliakrilonitril / kil kompozitler farklı metotlar ile hazırlandı. Hazırlanan kompozitlerin termal özellikleri termal gravimetrik analiz (TGA) ve diferansiyel taramalı kalorimetri (DSC) teknikleri ile incelendi. Elde edilen sonuçlar kompozit formülasyonlarında kil içeriğinin artması ile kompozitlerin termal özelliklerinde önemli bir artış olduğunu gösterdi.

Keywords

İletken polimerler;polipirol;poliakrilonitril;kil;kompozitler;termal özellikler

References

Goh, S.H., Chan, H.S.O. ve Ong, C.H. (1998). Miscible blends of conductive polyaniline with tertiary amide polymers. J. Appl. Polym. Sci., 68, 1839-1844.
Chen, K.H. ve Yang, S.M. (2003). Polyaniline-montmorillonite composite synthesized by electrochemical method. Synth. Met., 135, 151-152.
Omastova, M. ve Micusık, M. (2012). Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation. Chem. Pap., 66, 392-414.
Chang, L.T. ve Yen, C.C. (1995). Studies on the preparation and properties of conductive polymers. VIII. Use of heat treatment to prepare metallized films from silver chelate of PVA and PAN. J. Appl. Polym. Sci., 55, 371-374.
Madakbaş, S., Çakmakçı, E., Kahraman, M.V. ve Esmer, K. (2013). Preparation, characterisation, and dielectric properties of polypyrrole-clay composites. Chem. Pap., 67, 1048-1053.
Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang, C.K. ve Heeger, A.J. (1977). Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x . J. Chem. Soc. Chem. Com., 16, 578-580.
Pant, H.C., Patra, M.K., Negi, S.C., Bhatia, A., Vadera, S.R. ve Kumar, N. (2006). Studies on conductivity and dielectric properties of polyaniline-zinc sulphide composites. Bull. Mater. Sci. 29, 379-384.
Madakbaş¸ S., Çakmakçı, E., Kahraman, M.V. (2013). Preparation and thermal properties of polyacrylonitrile/hexagonal boron nitride composites. Thermochim. Acta, 552, 1-4. Şen, F. Ve Kahraman, M.V. (2013). Preparation and Properties of Nano Diamond / 6FBisphenol A Based Cyanate Ester Composites. Polym. Composite., 34, 1977-1985.

There are 8 citations in total.

Details

Primary Language	English
Journal Section	Research Articles
Authors	Seyfullah Madakbaş Memet Vezir Kahraman Ferhat Şen Kadir Esmer
Publication Date	December 27, 2013
Published in Issue	Year 2013 Volume: 25 Issue: 3

Cite

APA	Madakbaş, S., Kahraman, M. V., Şen, F., Esmer, K. (2013). Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. Marmara Fen Bilimleri Dergisi, 25(3), 134-139. https://doi.org/10.7240/201332503
AMA	Madakbaş S, Kahraman MV, Şen F, Esmer K. Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. MAJPAS. December 2013;25(3):134-139. doi:10.7240/201332503
Chicago	Madakbaş, Seyfullah, Memet Vezir Kahraman, Ferhat Şen, and Kadir Esmer. “Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites”. Marmara Fen Bilimleri Dergisi 25, no. 3 (December 2013): 134-39. https://doi.org/10.7240/201332503.
EndNote	Madakbaş S, Kahraman MV, Şen F, Esmer K (December 1, 2013) Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. Marmara Fen Bilimleri Dergisi 25 3 134–139.
IEEE	S. Madakbaş, M. V. Kahraman, F. Şen, and K. Esmer, “Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites”, MAJPAS, vol. 25, no. 3, pp. 134–139, 2013, doi: 10.7240/201332503.
ISNAD	Madakbaş, Seyfullah et al. “Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites”. Marmara Fen Bilimleri Dergisi 25/3 (December 2013), 134-139. https://doi.org/10.7240/201332503.
JAMA	Madakbaş S, Kahraman MV, Şen F, Esmer K. Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. MAJPAS. 2013;25:134–139.
MLA	Madakbaş, Seyfullah et al. “Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites”. Marmara Fen Bilimleri Dergisi, vol. 25, no. 3, 2013, pp. 134-9, doi:10.7240/201332503.
Vancouver	Madakbaş S, Kahraman MV, Şen F, Esmer K. Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. MAJPAS. 2013;25(3):134-9.