Research Article
BibTex RIS Cite

Su örneklerindeki Pb(II)-vitamin B6 komplekslerinin Bulutlanma Noktası Ekstraksiyonu

Year 2022, Volume: 11 Issue: 2, 40 - 47, 08.12.2022
https://doi.org/10.17100/nevbiltek.1192873

Abstract

Bu çalışma esas olarak kurşun iyonlarının bulutlanma noktası ekstraksiyonu (CPE) prosedürü ile zenginleştirme ve alevli atomik absorpsiyon spektrometrik tayinine odaklanmıştır. Yöntemde, Pb2+ ve B6 vitamininin, önderiştirilmesinden önce, bulutlanma noktası ekstraksiyonu ile kompleksleştirilmesi sağlanmıştır. Çözelti pH'sı, yüzey aktif madde ve B6 vitamini konsantrasyonları, girişim yapan iyonlar, inkübasyon sıcaklığı ve numune hacmi optimize edilmiştir. Yöntemin gözlenebilme sınırı (LOQ) ve tayin sınırı (LOD) değerleri sırasıyla 7,88 ve 25,99 olarak bulunmuştur. CPE yönteminin validasyonu, doğal kaynak suları ve maden suları gibi su örneklerine analit eklenmesi (bilinen Pb2+ konsantrasyonu) ile sağlanmıştır.

References

  • [1] Ravi Kumar K., Shyamala P., “Catanionic mixed micellar cloud point extraction of metal ions in coal fly ash samples and their determination by CS-ETAAS’’ Journal of Environmental Chemical Engineering, 7, 103119-103124, 2019
  • [2] Mohammadi S.Z., Shamspur T., Afzali D., Taher M. A., Baghelani Y. M., “Applicability of cloud point extraction for the separation trace amount of lead ion in environmental and biological samples prior to determination by flame atomic absorption spectrometry’’ Arabian Journal of Chemistry, 9, 610-615, 2016
  • [3] Blanchet-Chouinard G., Larivière D., “Determination of Pb in environmental samples after cloud point extraction using crown ether” Talanta, 179, 300-306, 2018
  • [4] Mortada W. I., “Recent developments and applications of cloud point extraction: A critical review” Microchemical Journal, 157, 105055-105068, 2020
  • [5] Mortada W.I., Kenawy I.M.M, Abdel-Rhman M.H., El-Gamal G.G., Moalla S.M.N., “A new thiourea derivative [2-(3-ethylthioureido)benzoic acid] for cloud point extraction of some trace metals in water, biological and food samples” Journal of Trace Elements in Medicine and Biology, 44, 266-273, 2017
  • [6] Talpur S., Kazi T.G., Afridi H.I., Talpur F.N., Nizamani S., Lashari A., Akhtar A., Khan M., “Ultrasonically dispersed ionic liquid-based microextraction of lead in biological samples of malnourished children prior to analysis by flame atomic absorption spectrometry” Journal of AOAC International, 101, (3), 883–890, 2018
  • [7] Vatankhah G., Ebrahimi M., Kahani M., “Determination of trace amount of lead (11) and cadmium (11) ions in real water and real samples by flame atomic absorption spectrometry after cloud point extraction using selective synthesis ligand2-(3- indolyl)–4,5 di phynyl imidazole” Eurasian Journal of Analytical Chemistry, 2, (7), 987-1000, 2017
  • [8]https://www.dow.com/content/dam/dcc/documents/en-us/productdatasheet/119/119-01915-01-tergitol-np-7-surfactant-tds.pdf.
  • [9] Rihana -Abdallah A., Li Z., Lanigan K. C., “Using cloud point extraction for preconcentration and determination of ıron, lead, and cadmium in drinking water by flame atomic absorption spectrometry” Analytical Letters, 55, (8), 1296–1305, 2021
  • [10] E.L. Silva and P. Santos Roldan, “Simultaneous flow injection preconcentration of lead and cadmium using cloud point extraction and determination by atomic absorption spectometry”, Journal of Hazardous Materials 2009 Art. no. 161 pp 142–147.

Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples

Year 2022, Volume: 11 Issue: 2, 40 - 47, 08.12.2022
https://doi.org/10.17100/nevbiltek.1192873

Abstract

This study mainly centered on the preconcentration and flame atomic absorption spectrometric determination of lead ions by cloud point extraction (CPE) procedure. Complexation of Pb2+ and vitamin B6 prior to its preconcentration by cloud point extraction was achieved in the method. The solution pH, surfactant and vitamin B6 concentrations, interfering ions, incubation temperature and sample volume were optimized. The limit of quantication (LOQ) and limit of detection (LOD) values of the method were found as 7.88 and 25.99 respectively. The validation of the CPE method was achieved by the analyte adding (known concentration of Pb2+) to water samples such as natural spring waters and mineral waters.

References

  • [1] Ravi Kumar K., Shyamala P., “Catanionic mixed micellar cloud point extraction of metal ions in coal fly ash samples and their determination by CS-ETAAS’’ Journal of Environmental Chemical Engineering, 7, 103119-103124, 2019
  • [2] Mohammadi S.Z., Shamspur T., Afzali D., Taher M. A., Baghelani Y. M., “Applicability of cloud point extraction for the separation trace amount of lead ion in environmental and biological samples prior to determination by flame atomic absorption spectrometry’’ Arabian Journal of Chemistry, 9, 610-615, 2016
  • [3] Blanchet-Chouinard G., Larivière D., “Determination of Pb in environmental samples after cloud point extraction using crown ether” Talanta, 179, 300-306, 2018
  • [4] Mortada W. I., “Recent developments and applications of cloud point extraction: A critical review” Microchemical Journal, 157, 105055-105068, 2020
  • [5] Mortada W.I., Kenawy I.M.M, Abdel-Rhman M.H., El-Gamal G.G., Moalla S.M.N., “A new thiourea derivative [2-(3-ethylthioureido)benzoic acid] for cloud point extraction of some trace metals in water, biological and food samples” Journal of Trace Elements in Medicine and Biology, 44, 266-273, 2017
  • [6] Talpur S., Kazi T.G., Afridi H.I., Talpur F.N., Nizamani S., Lashari A., Akhtar A., Khan M., “Ultrasonically dispersed ionic liquid-based microextraction of lead in biological samples of malnourished children prior to analysis by flame atomic absorption spectrometry” Journal of AOAC International, 101, (3), 883–890, 2018
  • [7] Vatankhah G., Ebrahimi M., Kahani M., “Determination of trace amount of lead (11) and cadmium (11) ions in real water and real samples by flame atomic absorption spectrometry after cloud point extraction using selective synthesis ligand2-(3- indolyl)–4,5 di phynyl imidazole” Eurasian Journal of Analytical Chemistry, 2, (7), 987-1000, 2017
  • [8]https://www.dow.com/content/dam/dcc/documents/en-us/productdatasheet/119/119-01915-01-tergitol-np-7-surfactant-tds.pdf.
  • [9] Rihana -Abdallah A., Li Z., Lanigan K. C., “Using cloud point extraction for preconcentration and determination of ıron, lead, and cadmium in drinking water by flame atomic absorption spectrometry” Analytical Letters, 55, (8), 1296–1305, 2021
  • [10] E.L. Silva and P. Santos Roldan, “Simultaneous flow injection preconcentration of lead and cadmium using cloud point extraction and determination by atomic absorption spectometry”, Journal of Hazardous Materials 2009 Art. no. 161 pp 142–147.
There are 10 citations in total.

Details

Primary Language English
Journal Section Araştırma Makalesi
Authors

Nilgün Başata This is me 0000-0002-9106-0759

Yavuz Sürme 0000-0003-4368-6658

Early Pub Date December 8, 2022
Publication Date December 8, 2022
Acceptance Date November 15, 2022
Published in Issue Year 2022 Volume: 11 Issue: 2

Cite

APA Başata, N., & Sürme, Y. (2022). Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples. Nevşehir Bilim Ve Teknoloji Dergisi, 11(2), 40-47. https://doi.org/10.17100/nevbiltek.1192873
AMA Başata N, Sürme Y. Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples. Nevşehir Bilim ve Teknoloji Dergisi. December 2022;11(2):40-47. doi:10.17100/nevbiltek.1192873
Chicago Başata, Nilgün, and Yavuz Sürme. “Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples”. Nevşehir Bilim Ve Teknoloji Dergisi 11, no. 2 (December 2022): 40-47. https://doi.org/10.17100/nevbiltek.1192873.
EndNote Başata N, Sürme Y (December 1, 2022) Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples. Nevşehir Bilim ve Teknoloji Dergisi 11 2 40–47.
IEEE N. Başata and Y. Sürme, “Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples”, Nevşehir Bilim ve Teknoloji Dergisi, vol. 11, no. 2, pp. 40–47, 2022, doi: 10.17100/nevbiltek.1192873.
ISNAD Başata, Nilgün - Sürme, Yavuz. “Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples”. Nevşehir Bilim ve Teknoloji Dergisi 11/2 (December 2022), 40-47. https://doi.org/10.17100/nevbiltek.1192873.
JAMA Başata N, Sürme Y. Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples. Nevşehir Bilim ve Teknoloji Dergisi. 2022;11:40–47.
MLA Başata, Nilgün and Yavuz Sürme. “Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples”. Nevşehir Bilim Ve Teknoloji Dergisi, vol. 11, no. 2, 2022, pp. 40-47, doi:10.17100/nevbiltek.1192873.
Vancouver Başata N, Sürme Y. Cloud Point Extraction Of Pb (II)-Vitamin B6 Complex In Aqueous Samples. Nevşehir Bilim ve Teknoloji Dergisi. 2022;11(2):40-7.

Dergimizin tarandığı indeksler


12300          20980     2097822081