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KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ

Year 2020, Volume: 9 Issue: 1, 114 - 127, 30.01.2020

Mehtap Erşan Ülker Aslı Güler Hatice Doğan Batoul Sarraj

https://doi.org/10.28948/ngumuh.681256
Cited By: 1

Abstract

Bu çalışmada, kolemanit destekli nZVI (K-nZVI) kullanılarak metilen mavisinin adsorpsiyonprosesiyle giderimi araştırılmıştır. Yapılan çalışmada öncelikle kolemanit destekli nZVI sentezlenmiştir. Sentezlenen bu yeni materyal ile sulu çözeltilerden metilen mavisi giderimini etkileyen çözelti pH değeri, K-nZV miktarı, temas süresi, sıcaklık ve başlangıç boya konsantrasyonu gibi adsorpsiyon parametrelerinde çalışılmıştır. Metilen mavisinin K-nZVI ile adsorpsiyonunun, Freundlich izoterm modeline ve yalancı ikinci dereceden kinetiğe daha uygun olduğu belirlenmiştir. Minitab 18 (trial) deneysel regrasyon analizinin sonuçlarına bakılarak verilerin optimizasyonu desteklenmiştir. Maksimum adsorpsiyon giderim verimi pH 4’te 5 g/L K-nZVI miktarı ile 120 dk temas süresi sonunda %90,78 olarak elde edilmiştir. Ayrıca elde edilen optimum koşullarda gerçek tekstil endüstrisi atıksuyu yapılan renk giderim çalışmasında da %94,48 oranında bir giderim verimi elde edilmiştir. Sonuç olarak K-nZVI’nın metilen mavisi gibi katyonik boyaların gideriminde yeni ekonomik bir adsorbent olarak kullanılabileceği sonucuna varılmıştır.

Keywords

Adsorpsiyon nZVI Kolemanit Metilen Mavisi

References

  • [1] Z. Huang, Y. Li, W. Chen, J. Shi, X. Wang, Z. Li, L. Gao, and Y. Zhang, “Modified bentonite adsorption of organic pollutants of dye wastewater,” Materials Chemistry and Physics, vol. 202, no. 11, Dec., pp. 266-276, 2017.
  • [2] N. Kannan, M. M. Sundaram, “Kinetics and mechanism of removal of methylene blue by adsorption on various carbons-a comparative study,” Dyes and Pigments, vol. 51, no.1, Oct., pp. 25-40, 2001.
  • [3] M. E. Cakmak, Basic blue 41 boyar maddesinin anaerobik ve aktif çamur biyokütlesi tarafından adsorplanabilirliğinin incelenmesi, Yüksek Lisans tezi, Çukurova Üniversitesi, Adana, 2004.
  • [4] M. Sarıoğlu Cebeci, Ü. A. Güler, “Doğal ve aktifleştirilmiş anaerobik çamur kullanılarak metilen mavi boyasının biyosorpsiyonu: denge, kinetik ve termodinamik çalışmalar,” DEÜ Mühendislik Fakültesi Mühendislik Bilimleri Dergisi, vol. 13 no. 41, May., pp. 13-28, 2012.
  • [5] S. Syamsiah, I. Santosohadi, “Adsorption cycle sand effect of microbial population on phenol removal using natural zeolit,” Separation and PurificationTechnology, vol. 34, pp. 125-133, 2004.
  • [6] S. Koonaphapdeelert, J. Moran, P. Aggarangsi, and A. Bunkham, “Low pressure biomethane gas adsorption by activated carbon,” Energy for Sustainable Development, vol. 43, no. 1, pp.196-202, 2018.
  • [7] Z. Rogala, P. Kolasinski, and Z. Gnutek, “Modelling and experimental analyzes on air-fluidised silica gel-water adsorption and desorption”, Applied Thermal Engineering, vol. 127, no. 25, Dec., pp.950-962, 2017.
  • [8] Z. Aksu, “Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modelling,” Biochemical Eng., vol. 7, no. 1, Jan., pp. 79-84, 2001.
  • [9] Z. Fang, J. Chen, X. Qiu, W. Cheng, and L., Zhu, “Effective removal of antibiotic metronidazole from water by nanoscale zero-valent iron particles,” Desalination, vol. 268, no. 1-3, pp. 60-67, 2011.
  • [10] W. Li, F. Fu, Z. Ding, and B. Tang, “Zero valent iron as an electron transfer agent in a reaction system based on zerovalent iron/magnetite nano composites for adsorption and oxidation of Sb(III),” Journal of the Taiwan Institute of Chemical Engineers, vol. 85, April, 155-164, 2018.
  • [11] Z. Li, L. Wang, J. Meng, X. and Liu,, X., “Zeolite-supported nanoscale zero-valent iron: new findings on simultaneous adsorption of Cd(II), Pb(II), and As(III) in aqueous solution and soil,” Journal of Hazardous Materials, vol. 15, no. 344, Feb., pp. 1-11, 2018.
  • [12] Z. Li, H. Dong, Y. Zhang, J. L. Yimin, “Enhanced removal of Ni(II) by nano scale zero valent iron supported on Na-saturated bentonite,” Journal of Colloid and Interface Science, vol. 497, Feb., pp. 34-49, 2017.
  • [13] Borun Kulanım Alanları. [Online]. Available: http://www.etimaden.gov.tr (Accessed Feb. 03, 2018).
  • [14] M. Başıbüyük, C. F. Forster, “An examination of adsorption characteristics of a basic dye (MaxilonRed BL-N) and live activated sludge system,” Process Biochemistry, vol. 38, no. 9, April, pp. 1311-1316, 2003.
  • [15] A. Kapoor, T. Viraraghavan, D. R. Cullimore, “Removal of heavy metals using the fungus Aspergillus niger,” BioresourceTechno., vol. 70, pp. 95-104, 1999.
  • [16] O. Keskinkan, M. Z. L. Göksu, A. Yüceer, M. Başıbüyük, and C. F. Forster, “Heavy metal adsorption characteristics of a submerged aquatic plant (Myriophyllumspicatum),” Process Biochemistry, vol. 39, no. 2, Oct., pp. 179-183, 2003.
  • [17] O. Tünay, I. Kabdaşlı, Fiziksel Kimya, 1. baskı, İ.T.Ü. Yayınları, İstanbul, 1996.
  • [18] H. Nollet, M. Roels, P. Lutgen, P. Van Der Meeren, and W. Verstraete, “Removal of PCBs from wastewater using fly ash,”, Chemosphere, vol. 53, pp. 655-665, 2003.
  • [19] A. M. Pınar, A. Güllü, “Sayısal Denetimli Hidrolik Pozisyonlama Sisteminin Taguchi Metodu ile Optimizasyonu,” Gazi Üniv. Müh. Mim. Fak. Der. Vol. 25, no 1, pp. 93- 100, 2010.
  • [20] E. Canıyılmaz, F. Kutay, “Kalite Geliştirmede Taguchi Metodu ve Bir Uygulama,” Yüksek Lisans Tezi, Gazi Üniversitesi, 2001.
  • [21] B. Xu, H. Zheng, H. Zhou,Y. Wang, K. Luo, C. Zhao, Y. Peng, and X. Zheng, “Adsorptive removal of anionic dyes by chitosan-based magnetic microspheres with pH- responsive properties,” vol. 256, pp. 424-432, 2018.
  • [22] S. Sadaf, H. N. Bhatti, “Batch and fixed bed column studies for the removal of Indosol Yellow BG dye by peanut husk,” Journal of the Taiwan Institute of Chemical Engineers, vol. 45, no. 2, pp. 541-553, 2014.
  • [23] Y. Fu, T. Viraraghavan, “Fungal decolorization of dye wastewaters: a review,” Bioresource Technology, vol. 79, no. 9, Sept., pp. 251-262, 2001.
  • [24] E. Moral, “Farklı İyon Değiştirici Reçineler ve Doğal Adsorbanlarla Hazırlanan Katı-Faz Kolonlarla Krom Türleri Tayini”, Yüksek Lisans Tezi, Kimya Anabilim Dalı, Isparta, 2006.
  • [25] L. Mouni, L. Belkhiri, J. C. Bollinger, A. Bouzza, A. Assadi, A. Tirri, F. Dahmoune, K. Madani, and H. Remini, “Removal of methylene blue from aqueous solutions by adsorption on kaolin: kinetic and equilibrium studies,” Appl. Clay Sci., vol. 153, no. 1, March, pp. 38-45, 2018.
  • [26] Y. Liu, S. Huang, X. Zhao, and Y. Zhang, “Fabrication of three-dimensional porous β-cyclo dextrin/chitosan functionalized graphene oxide hydro gel for methylene blue,” Colloids Surf., vol. 539, pp. 1-10, 2018.
  • [27] Z. Zhang, J. Kong, “Novel magnetic Fe3O4/C nanoparticles as adsorbents for removal of organic dyes from aqueous solution,” vol. 15, no. 193, Oct., pp. 325-329, 2011.
  • [28] A. Bee, L. Obeid, R. Mbolantenaina, M. Welschbillig, D. Talbot, “Magnetic chitosan/clay beads: a magsorbent for the removal of cationic dye from water,” J. Magn. Mater., vol. 421, pp. 59-64, 2017.
  • [29] S. Fan, J. Tang, Y. Wang, H. Li, H. Zhang, Z. Wang, and X. Li, “Biochar prepared from co-pyrolysis of municipal sewage sludge and tea waste for the adsporption of methylene blue from aqueous solutions: Kinetics, isoterm, thermodynamic and mechanism,” vol. 15, no. 7, pp. 432-441, 2016.
  • [30] M. Rezakazemi, S. Shirazian, “Lignin-chitosan blend for metylene blue removal: adsorption modeling,” J. of Molecular Liquids, vol. 274, pp. 778-791, 2019.
  • [31] K. LU, T. Wang, L. Zihai, W. Wu, S. Dong, S. Gao, and L. Mao, “Adsorption behavior and mechanism of Fe-Mn binary oxide nanoparticles: Adsorption of methylene blue,” Journal of Colloid and Interface Science, vol. 539, pp. 553-562, 2019.
  • [32] Minitab support. [Online]. Available: https://support.minitab.com/en-us/minitab/18 (Accessed April 15, 2018).
  • [33] F. Özyonar, Z. Yılmaz, and B. Karagözoğlu, “Taguchi Metodu Kullanılarak Gerçek Tekstil Atıksuyunun Arıtımında Elektrokoagülasyon,” Uluslararası Katılımlı Çevre Sempozyumu, Gümüşhane, 24-26 Oct 2013.
  • [34] Gage Studies for Continuous Data. [online]. Available: http://www.Gage StudiesforContinuous Data- Minitab.pdf (Accessed April 03, 2018).
  • [35] M. Altan, “Reducing shrink age in injection moldings via the Taguchi, ANOVA and neural network methods,” Materials& Design, vol. 31, no. 1, Jan.pp. 599-604, 2010.

Year 2020, Volume: 9 Issue: 1, 114 - 127, 30.01.2020

Mehtap Erşan Ülker Aslı Güler Hatice Doğan Batoul Sarraj

https://doi.org/10.28948/ngumuh.681256
Cited By: 1

Abstract

References

  • [1] Z. Huang, Y. Li, W. Chen, J. Shi, X. Wang, Z. Li, L. Gao, and Y. Zhang, “Modified bentonite adsorption of organic pollutants of dye wastewater,” Materials Chemistry and Physics, vol. 202, no. 11, Dec., pp. 266-276, 2017.
  • [2] N. Kannan, M. M. Sundaram, “Kinetics and mechanism of removal of methylene blue by adsorption on various carbons-a comparative study,” Dyes and Pigments, vol. 51, no.1, Oct., pp. 25-40, 2001.
  • [3] M. E. Cakmak, Basic blue 41 boyar maddesinin anaerobik ve aktif çamur biyokütlesi tarafından adsorplanabilirliğinin incelenmesi, Yüksek Lisans tezi, Çukurova Üniversitesi, Adana, 2004.
  • [4] M. Sarıoğlu Cebeci, Ü. A. Güler, “Doğal ve aktifleştirilmiş anaerobik çamur kullanılarak metilen mavi boyasının biyosorpsiyonu: denge, kinetik ve termodinamik çalışmalar,” DEÜ Mühendislik Fakültesi Mühendislik Bilimleri Dergisi, vol. 13 no. 41, May., pp. 13-28, 2012.
  • [5] S. Syamsiah, I. Santosohadi, “Adsorption cycle sand effect of microbial population on phenol removal using natural zeolit,” Separation and PurificationTechnology, vol. 34, pp. 125-133, 2004.
  • [6] S. Koonaphapdeelert, J. Moran, P. Aggarangsi, and A. Bunkham, “Low pressure biomethane gas adsorption by activated carbon,” Energy for Sustainable Development, vol. 43, no. 1, pp.196-202, 2018.
  • [7] Z. Rogala, P. Kolasinski, and Z. Gnutek, “Modelling and experimental analyzes on air-fluidised silica gel-water adsorption and desorption”, Applied Thermal Engineering, vol. 127, no. 25, Dec., pp.950-962, 2017.
  • [8] Z. Aksu, “Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modelling,” Biochemical Eng., vol. 7, no. 1, Jan., pp. 79-84, 2001.
  • [9] Z. Fang, J. Chen, X. Qiu, W. Cheng, and L., Zhu, “Effective removal of antibiotic metronidazole from water by nanoscale zero-valent iron particles,” Desalination, vol. 268, no. 1-3, pp. 60-67, 2011.
  • [10] W. Li, F. Fu, Z. Ding, and B. Tang, “Zero valent iron as an electron transfer agent in a reaction system based on zerovalent iron/magnetite nano composites for adsorption and oxidation of Sb(III),” Journal of the Taiwan Institute of Chemical Engineers, vol. 85, April, 155-164, 2018.
  • [11] Z. Li, L. Wang, J. Meng, X. and Liu,, X., “Zeolite-supported nanoscale zero-valent iron: new findings on simultaneous adsorption of Cd(II), Pb(II), and As(III) in aqueous solution and soil,” Journal of Hazardous Materials, vol. 15, no. 344, Feb., pp. 1-11, 2018.
  • [12] Z. Li, H. Dong, Y. Zhang, J. L. Yimin, “Enhanced removal of Ni(II) by nano scale zero valent iron supported on Na-saturated bentonite,” Journal of Colloid and Interface Science, vol. 497, Feb., pp. 34-49, 2017.
  • [13] Borun Kulanım Alanları. [Online]. Available: http://www.etimaden.gov.tr (Accessed Feb. 03, 2018).
  • [14] M. Başıbüyük, C. F. Forster, “An examination of adsorption characteristics of a basic dye (MaxilonRed BL-N) and live activated sludge system,” Process Biochemistry, vol. 38, no. 9, April, pp. 1311-1316, 2003.
  • [15] A. Kapoor, T. Viraraghavan, D. R. Cullimore, “Removal of heavy metals using the fungus Aspergillus niger,” BioresourceTechno., vol. 70, pp. 95-104, 1999.
  • [16] O. Keskinkan, M. Z. L. Göksu, A. Yüceer, M. Başıbüyük, and C. F. Forster, “Heavy metal adsorption characteristics of a submerged aquatic plant (Myriophyllumspicatum),” Process Biochemistry, vol. 39, no. 2, Oct., pp. 179-183, 2003.
  • [17] O. Tünay, I. Kabdaşlı, Fiziksel Kimya, 1. baskı, İ.T.Ü. Yayınları, İstanbul, 1996.
  • [18] H. Nollet, M. Roels, P. Lutgen, P. Van Der Meeren, and W. Verstraete, “Removal of PCBs from wastewater using fly ash,”, Chemosphere, vol. 53, pp. 655-665, 2003.
  • [19] A. M. Pınar, A. Güllü, “Sayısal Denetimli Hidrolik Pozisyonlama Sisteminin Taguchi Metodu ile Optimizasyonu,” Gazi Üniv. Müh. Mim. Fak. Der. Vol. 25, no 1, pp. 93- 100, 2010.
  • [20] E. Canıyılmaz, F. Kutay, “Kalite Geliştirmede Taguchi Metodu ve Bir Uygulama,” Yüksek Lisans Tezi, Gazi Üniversitesi, 2001.
  • [21] B. Xu, H. Zheng, H. Zhou,Y. Wang, K. Luo, C. Zhao, Y. Peng, and X. Zheng, “Adsorptive removal of anionic dyes by chitosan-based magnetic microspheres with pH- responsive properties,” vol. 256, pp. 424-432, 2018.
  • [22] S. Sadaf, H. N. Bhatti, “Batch and fixed bed column studies for the removal of Indosol Yellow BG dye by peanut husk,” Journal of the Taiwan Institute of Chemical Engineers, vol. 45, no. 2, pp. 541-553, 2014.
  • [23] Y. Fu, T. Viraraghavan, “Fungal decolorization of dye wastewaters: a review,” Bioresource Technology, vol. 79, no. 9, Sept., pp. 251-262, 2001.
  • [24] E. Moral, “Farklı İyon Değiştirici Reçineler ve Doğal Adsorbanlarla Hazırlanan Katı-Faz Kolonlarla Krom Türleri Tayini”, Yüksek Lisans Tezi, Kimya Anabilim Dalı, Isparta, 2006.
  • [25] L. Mouni, L. Belkhiri, J. C. Bollinger, A. Bouzza, A. Assadi, A. Tirri, F. Dahmoune, K. Madani, and H. Remini, “Removal of methylene blue from aqueous solutions by adsorption on kaolin: kinetic and equilibrium studies,” Appl. Clay Sci., vol. 153, no. 1, March, pp. 38-45, 2018.
  • [26] Y. Liu, S. Huang, X. Zhao, and Y. Zhang, “Fabrication of three-dimensional porous β-cyclo dextrin/chitosan functionalized graphene oxide hydro gel for methylene blue,” Colloids Surf., vol. 539, pp. 1-10, 2018.
  • [27] Z. Zhang, J. Kong, “Novel magnetic Fe3O4/C nanoparticles as adsorbents for removal of organic dyes from aqueous solution,” vol. 15, no. 193, Oct., pp. 325-329, 2011.
  • [28] A. Bee, L. Obeid, R. Mbolantenaina, M. Welschbillig, D. Talbot, “Magnetic chitosan/clay beads: a magsorbent for the removal of cationic dye from water,” J. Magn. Mater., vol. 421, pp. 59-64, 2017.
  • [29] S. Fan, J. Tang, Y. Wang, H. Li, H. Zhang, Z. Wang, and X. Li, “Biochar prepared from co-pyrolysis of municipal sewage sludge and tea waste for the adsporption of methylene blue from aqueous solutions: Kinetics, isoterm, thermodynamic and mechanism,” vol. 15, no. 7, pp. 432-441, 2016.
  • [30] M. Rezakazemi, S. Shirazian, “Lignin-chitosan blend for metylene blue removal: adsorption modeling,” J. of Molecular Liquids, vol. 274, pp. 778-791, 2019.
  • [31] K. LU, T. Wang, L. Zihai, W. Wu, S. Dong, S. Gao, and L. Mao, “Adsorption behavior and mechanism of Fe-Mn binary oxide nanoparticles: Adsorption of methylene blue,” Journal of Colloid and Interface Science, vol. 539, pp. 553-562, 2019.
  • [32] Minitab support. [Online]. Available: https://support.minitab.com/en-us/minitab/18 (Accessed April 15, 2018).
  • [33] F. Özyonar, Z. Yılmaz, and B. Karagözoğlu, “Taguchi Metodu Kullanılarak Gerçek Tekstil Atıksuyunun Arıtımında Elektrokoagülasyon,” Uluslararası Katılımlı Çevre Sempozyumu, Gümüşhane, 24-26 Oct 2013.
  • [34] Gage Studies for Continuous Data. [online]. Available: http://www.Gage StudiesforContinuous Data- Minitab.pdf (Accessed April 03, 2018).
  • [35] M. Altan, “Reducing shrink age in injection moldings via the Taguchi, ANOVA and neural network methods,” Materials& Design, vol. 31, no. 1, Jan.pp. 599-604, 2010.
There are 35 citations in total.

Details

Primary Language Turkish
Subjects Environmental Engineering
Journal Section Environmental Engineering
Authors

Mehtap Erşan This is me

Ülker Aslı Güler This is me

Hatice Doğan This is me

Batoul Sarraj This is me

Publication Date January 30, 2020
Submission Date May 14, 2018
Acceptance Date April 12, 2019
Published in Issue Year 2020 Volume: 9 Issue: 1

Cite

APA Erşan, M., Güler, Ü. A., Doğan, H., Sarraj, B. (2020). KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 9(1), 114-127. https://doi.org/10.28948/ngumuh.681256
AMA Erşan M, Güler ÜA, Doğan H, Sarraj B. KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ. NOHU J. Eng. Sci. January 2020;9(1):114-127. doi:10.28948/ngumuh.681256
Chicago Erşan, Mehtap, Ülker Aslı Güler, Hatice Doğan, and Batoul Sarraj. “KOLEMANİT DESTEKLİ NZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 9, no. 1 (January 2020): 114-27. https://doi.org/10.28948/ngumuh.681256.
EndNote Erşan M, Güler ÜA, Doğan H, Sarraj B (January 1, 2020) KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 9 1 114–127.
IEEE M. Erşan, Ü. A. Güler, H. Doğan, and B. Sarraj, “KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ”, NOHU J. Eng. Sci., vol. 9, no. 1, pp. 114–127, 2020, doi: 10.28948/ngumuh.681256.
ISNAD Erşan, Mehtap et al. “KOLEMANİT DESTEKLİ NZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 9/1 (January 2020), 114-127. https://doi.org/10.28948/ngumuh.681256.
JAMA Erşan M, Güler ÜA, Doğan H, Sarraj B. KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ. NOHU J. Eng. Sci. 2020;9:114–127.
MLA Erşan, Mehtap et al. “KOLEMANİT DESTEKLİ NZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 9, no. 1, 2020, pp. 114-27, doi:10.28948/ngumuh.681256.
Vancouver Erşan M, Güler ÜA, Doğan H, Sarraj B. KOLEMANİT DESTEKLİ nZVI KULLANILARAK SULU ÇÖZELTİLERDEN METİLEN MAVİSİNİN GİDERİMİ. NOHU J. Eng. Sci. 2020;9(1):114-27.

Cited By

LAVANTA BİTKİSİ ÖZÜTÜ KULLANILARAK SİNH2@FeNP NANOKOMPOZİTİNİN YEŞİL SENTEZİ İLE SULU ÇÖZELTİDEN METİLEN MAVİSİNİN GİDERİMİ: DENEYSEL TASARIM YAKLAŞIMI
Mühendislik Bilimleri ve Tasarım Dergisi
https://doi.org/10.21923/jesd.1005031
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