ADSORPTION OF REMAZOL BRILLANT BLUE R FROM AQUATIC SOLUTION USING NATURAL ADSORBENT (Pistachio Hull)
Abstract
This study examines that adsorption of Remazol Brillant Blue R (RBBR) from aquatic solution was studied using pistachio hull (PH) as an adsorbent. The removal efficiency of pistachio hull was studied as a function of, pH, initial dye concentration, adsorbent dose and time via batch method at room temperature. Langmuir and Freundlich Isotherms applied to obtained data from experiments. The correlation coefficient values shown that the data fit the Langmuir Isotherm (R2=0.9989) compare to Freundlich Isotherm (R2=0.7825). Maximum adsorption capacity was observed as 16.739mg/g. Thermodynamic parameters also studied. The value of Gibbs Free Energy, (ΔG=2.696kJ/mol) is positive. This value is indicated that the adsorption was not a spontaneous one. According to the experimental data, pistachio hull can be used as an appropriate, no cost and easy obtainable adsorbent for the removal of Remazol Brillant Blue R dye.
Keywords
References
- [1] Mittal, J., Mittal, A., Malviya, V.K., and Gupta, V.K., (2009). Adsorptive Removal of Hazardous Anionic Dye Congo Red from Wastewater Using Waste Materials and Recovery by Desorption. J. Colloid Interface Sci. Volume:340, Number:1, pp:16-26.
- [2] Liu, C.H., Wu, J.S., Chiu, H.C., Suen, S.Y., and Chu, K.H., (2007). Removal of Anionic Reactive Dyes from Water Using Anion Exchange Membranes as Adsorbers. Water Res. Volume:41, Number:1, pp:1491-1500.
- [3] Osugi, M.E., Rajeshwar, K., Ferraz, E.R.A., de Oliveira, D.P., Araújo, A.R., and Zanoni, M.V.B., (2009). Comparison of Oxidation Efficiency of Disperse Dyes by Chemical and Photoelectrocatalytic Chlorination and Removal of Mutagenic Activity. Electrochim. Acta. Volume: 54, pp: 2086-2093.
- [4] Wang, Q., Gao, D., Gao, C., Wei, Q., Cai, Y., Xu, J., Liu, X. and Xu, Y., (2012). Removal of a Cationic Dye by Adsorption/Photodegradation Using Electrospun PAN/O-MMT Composite Nanofibrous membranes coated with TiO2. Int. J. Photoenergy. Volume:2012, pp:680419-680426.
- [5] Deveci, T., Unyayar, A., and Mazmanci, M.A., (2004). Production of Remazol Brilliant Blue R Decolourising Oxygenase from the Culture Filtrate of Funalia trogii ATCC 200800. Journal of Molecular Catalysis B: Enzymatic. Volume:30, pp:25-32.
- [6] Amin, N.K., (2008). Removal of Reactive Dye from Aqueous Solutions by Adsorption onto Activated carbons Prepared from Sugarcane Bagasse Pith. Desalination. Volume:223, pp:152-161.
- [7] Sathishkumara, P., Arulkumarb, M., and Palvannanb, T., (2012). Utilization of Agro-Industrial Waste Jatropha curcas Pods as an Activated Carbon for the Adsorption of Reactive Dye Remazol Brilliant Blue R (RBBR). Journal of Cleaner Production. Volume:22, pp:67-75. [8] Ergene, A., Ada, K., Tan, S., and Katırcıoğlu, H., (2009). Removal of Remazol Brilliant Blue R Dye from Aqueous Solutions by Adsorption onto Immobilized Scenedesmus quadricauda: Equilibrium and Kinetic Modeling Studies. Desalination. Volume:249, pp:1308-1314.
- [9] Sathishkumar, P., Arulkumar, M., and Palvannan, T., (2012). Utilization of Agro-Industrial Waste Jatropha curcas Pods as an Activated Carbon for the Adsorption of Reactive Dye Remazol Brilliant Blue R (RBBR). Journal of Cleaner Production. Volume:22, Number:1, pp:67-75.
Details
Primary Language
English
Subjects
-
Journal Section
Research Article
Publication Date
April 21, 2018
Submission Date
October 31, 2017
Acceptance Date
March 29, 2018
Published in Issue
Year 2018 Volume: 13 Number: 2