Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K

Bourayou Euchi N.; Meniai A-h.; Gouaoura A.

Research Article

Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K

Year 2017, Volume: 20 Issue: 1, 129 - 135, 01.03.2017

Bourayou Euchi N. Meniai A-h. Gouaoura A.

Abstract

The present study concerns experimental measurements of the salting-out effect on liquid-liquid phase equilibrium (LLE) of partially miscible systems such as water/ ethanol/1- butanol /Potassium chloride at 298.15K. The salt KCl was used at different mass percentages of 5, 10 and 15. The binodal and tie line data were determined by the cloud point method. The addition of the salt showed to be effective in altering the LLE of water/ ethanol/1- butanol system in favor of the solvent extraction of ethanol from the aqueous solution particularly at high salt concentrations. The experimental data were correlated considering the modified version of the NRTL model for the activity coefficient, with the estimation of new binary interaction parameters corresponding to salt-solvent and solvent-solvent pairs. The deviations between experimental and calculated compositions in both phases for the ternary system using these new interaction parameters showed the ability of NRTL to determine liquid-liquid equilibrium data of the studied systems in the presence of the salts.

Keywords

Salt Effect, Solubility, LLE, NRTL Model, Interaction Parameter

References

1. Ramana, R. and Subba Reddy. Salt Effect on Solute Distribution in Liquid-Liquid Equilibria , 13:9, 79-81, (1978).
2. Narayana, A.S.; Nischal, R.; Patel, R.; Parikh, K.G. and Singh, R.K. Salt Effect in Liquid-liquid Equilibria of Acetic Acid-Water-Benzene System. J. Chem. Eng. Comm, 95: 41-46, (1990).
3. Edwin,O.; Eisen and Joseph Joffe.. Salt effects in Liquid-Liquid Equilibria, J. Chm. Eng., 11: 4, (1996).
4. Santos, G.R.; d'Avila, S.G. and Aznar. Brazilian Journal of Chemical Engineering.17: (04-07), 721-734, (2000).
5. Stragevitch, L. and S.G. d'Avila. Application of a generalized Maximum Likelihood Method in the Reduction of Multicomponent Phase Equilibrium Data. Braz. J. Chem. Eng, 41-52, (1997).
6. Tan, T.C.. Trans. Inst. Chem. Eng., Part A, 68: 93-103, (1990).
7. Tan,T.C., Aravinth,S. Liquid-Liquid equilibria of water/acetic acid/1-butanol system effect of sodium potassium) chloride and correlation. Fluid Phase Equilibria, 163: 243- 257, (1999).
8. Yitzhak, M.. The Properties of Solvents. , John Wiley and Sons ,4: 239, (1999).
9. Letcher, T. M.; Sizwana, P. M.. Liquid-liquid equilibria for mixtures of alkanol +water + methyl substituted benzene at 25 °C, Fluid Phase Equilibria. 74: 203-217, (1992).
10. Briggs, S. W.; Comings, E. W. Tie-line correlations and plait point determination, Ind. Eng. Chem., 35: 411-415, (1943).
11. Sorensen, J.M.; Arlt, W. Liquid-liquid equilibrium data collection. Dechema. Chemistry data series,5(2): (1987).
12. Nelder, J.A.; Mead, R..Comp, 7: 7-308, (1965).
13. Renon, H., Prausnitz, J. M. Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures. AlChE J. USA, 14(1): 135-44l, (1968).

Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K

Year 2017, Volume: 20 Issue: 1, 129 - 135, 01.03.2017

Bourayou Euchi N. Meniai A-h. Gouaoura A.

Abstract

The present study concerns experimental measurements of the salting-out effect on liquid-liquid phase equilibrium (LLE) of partially miscible systems such as water/ ethanol/1- butanol /Potassium chloride at 298.15K. The salt KCl was used at different mass percentages of 5, 10 and 15. The binodal and tie line data were determined by the cloud point method. The addition of the salt showed to be effective in altering the LLE of water/ ethanol/1- butanol system in favor of the solvent extraction of ethanol from the aqueous solution particularly at high salt concentrations. The experimental data were correlated considering the modified version of the NRTL model for the activity coefficient, with the estimation of new binary interaction parameters corresponding to salt-solvent and solvent-solvent pairs. The deviations between experimental and calculated compositions in both phases for the ternary system using these new interaction parameters showed the ability of NRTL to determine liquid-liquid equilibrium data of the studied systems in the presence of the salts.

Keywords

Salt Effect, Solubility, LLE, NRTL Model, Interaction Parameter

References

1. Ramana, R. and Subba Reddy. Salt Effect on Solute Distribution in Liquid-Liquid Equilibria , 13:9, 79-81, (1978).
2. Narayana, A.S.; Nischal, R.; Patel, R.; Parikh, K.G. and Singh, R.K. Salt Effect in Liquid-liquid Equilibria of Acetic Acid-Water-Benzene System. J. Chem. Eng. Comm, 95: 41-46, (1990).
3. Edwin,O.; Eisen and Joseph Joffe.. Salt effects in Liquid-Liquid Equilibria, J. Chm. Eng., 11: 4, (1996).
4. Santos, G.R.; d'Avila, S.G. and Aznar. Brazilian Journal of Chemical Engineering.17: (04-07), 721-734, (2000).
5. Stragevitch, L. and S.G. d'Avila. Application of a generalized Maximum Likelihood Method in the Reduction of Multicomponent Phase Equilibrium Data. Braz. J. Chem. Eng, 41-52, (1997).
6. Tan, T.C.. Trans. Inst. Chem. Eng., Part A, 68: 93-103, (1990).
7. Tan,T.C., Aravinth,S. Liquid-Liquid equilibria of water/acetic acid/1-butanol system effect of sodium potassium) chloride and correlation. Fluid Phase Equilibria, 163: 243- 257, (1999).
8. Yitzhak, M.. The Properties of Solvents. , John Wiley and Sons ,4: 239, (1999).
9. Letcher, T. M.; Sizwana, P. M.. Liquid-liquid equilibria for mixtures of alkanol +water + methyl substituted benzene at 25 °C, Fluid Phase Equilibria. 74: 203-217, (1992).
10. Briggs, S. W.; Comings, E. W. Tie-line correlations and plait point determination, Ind. Eng. Chem., 35: 411-415, (1943).
11. Sorensen, J.M.; Arlt, W. Liquid-liquid equilibrium data collection. Dechema. Chemistry data series,5(2): (1987).
12. Nelder, J.A.; Mead, R..Comp, 7: 7-308, (1965).
13. Renon, H., Prausnitz, J. M. Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures. AlChE J. USA, 14(1): 135-44l, (1968).

There are 13 citations in total.

Details

Primary Language	English
Subjects	Engineering
Journal Section	Research Article
Authors	Bourayou Euchi N. This is me Meniai A-h. This is me Gouaoura A. This is me
Publication Date	March 1, 2017
Submission Date	September 26, 2016
Published in Issue	Year 2017 Volume: 20 Issue: 1

Cite

APA	N., B. E., A-h., M., & A., G. (2017). Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K. Politeknik Dergisi, 20(1), 129-135.
AMA	N. BE, A-h. M, A. G. Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K. Politeknik Dergisi. March 2017;20(1):129-135.
Chicago	N., Bourayou Euchi, Meniai A-h., and Gouaoura A. “Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K”. Politeknik Dergisi 20, no. 1 (March 2017): 129-35.
EndNote	N. BE, A-h. M, A. G (March 1, 2017) Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K. Politeknik Dergisi 20 1 129–135.
IEEE	B. E. N., M. A-h., and G. A., “Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K”, Politeknik Dergisi, vol. 20, no. 1, pp. 129–135, 2017.
ISNAD	N., Bourayou Euchi et al. “Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K”. Politeknik Dergisi 20/1 (March 2017), 129-135.
JAMA	N. BE, A-h. M, A. G. Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K. Politeknik Dergisi. 2017;20:129–135.
MLA	N., Bourayou Euchi et al. “Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K”. Politeknik Dergisi, vol. 20, no. 1, 2017, pp. 129-35.
Vancouver	N. BE, A-h. M, A. G. Modeling Of Liquid-Liquid Equilibrium Data and Estimation of New Binary Interaction Parameters for NRTL Model for the Quaternary System Water/ Ethanol/1- Butanol / KCL at 298.15K. Politeknik Dergisi. 2017;20(1):129-35.