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Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu

Year 2019, Volume: 22 Issue: 2, 367 - 373, 01.06.2019
https://doi.org/10.2339/politeknik.498477

Abstract

Bu çalışmada, benzilamin ince
filmleri ile kovalent bir şekilde modifiye edilmiş yüzeyler üzerinde
sitrat-kaplı altın nanopartiküllerin üretimi amaçlanmıştır. Bu amaçla ilk
olarak, p-tipi Si (100) elektrotlar aril diazonyum tuzlarının elektrokimyasal
indirgenmesi (+N2-benzilamin) ile benzilamin tabakaları ile modifiye
edilmiştir. Daha sonra, modifiye edilmiş elektrotlar altın nanopartikül içeren
bir çözelti içine daldırılmıştır. Son olarak, Au nanopartiküller elektrostatik
olarak pozitif yüklü benzilamin tabakaları ile birleştirilmiştir. Benzilamin
filmlerin özellikleri voltametrik yöntemler kullanılarak incelenmiştir.
Modifiye edilmiş p-tipi Si (100) yüzeylerinin bariyer özellikleri redoks probların
varlığında (Fe(CN)63- ve Ru(NH3)63+)
dönüşümlü voltametri kullanılarak çalışılmıştır. Ayrıca elde edilen sonuç
filmlerin karakterizasyonu ve morfolojik analizi taramalı elektron mikroskopu
(SEM) ile araştırılmıştır.

References

  • [1] Katz, E., Willner, I., Wang, J., “Electroanalytical and Bioelectroanalytical Systems Based on Metal and Semiconductor Nanoparticles”, Electroanal, 16: 19-26, (2004).
  • [2] Dobrzanski, L.A., Pawlyta, M., Krzton, A., Lizzka, B., Labizz, K., “Synthesis and Characterization of Carbon Nanotubes Decorated with Platinum Nanoparticles”, J. Achiev. Mater. and Manuf. Eng., 39: 2, (2010).
  • [3] Honciuc, A., Jaiswal, A., Gong, A., Ashworth,K., Spangler, C.W., Peterson, R., Dalton, L., Metzger,R.M., “Current Rectification in a Langmuir-Schaefer Monolayer of Fullerene-bis-[4-diphenylamino-4-(N-ethyl-N 2-ethyl)amino-1,4-diphenyl-1,3-butadiene] Malonate between Au Electrodes”, J. Phys. Chem. B, 109: 857-871, (2005).
  • [4] Metzger, R.M., Chen, B., Ho1pfner, U., Lakshmikantham, M.V., Vuillaume, D., Kawai, T., Wu, X., Tachibana, H., Hughes, T.V., Sakurai, H., Baldwin, J.W., Hosch, C., Cava, M.P., Brehmer, L., Ashwell, G.J., 1997. “Unimolecular Electrical Rectification in Hexadecylquinolinium Tricyanoquinodimethanide”, J. Am. Chem. Soc, 119: 10455-10466, (1997).
  • [5] Blum, A.S., Kushmerick, J.G., Long, D.P., Patterson, C.H., Yang, J. C., Henderson, J.C., Yao, Y.X., Tour, J.M., Shashidhar, R., Ratna, B.R., “Molecularly Inherent Voltage-Controlled Conductance Switching”, Nature Materials, 4: 167-172, (2005).
  • [6] Collier, C.P., Jeppesen, J.O., Luo, Y., Perkins, J., Wong, E.W., Heath, J.R., Stoddart, J.F., “Molecular-Based Electronically Switchable Tunnel Junction Devices”, J. Am. Chem. Soc, 123: 12632-12641, (2001).
  • [7] Moore, A. M., Dameron, A. A., Mantooth, B. A., Smith, R. K., Fuchs, D. J. , Ciszek, J. W., Maya, F., Yao, Y., Tour, J.M., Weiss, P.S., “Molecular Engineering and Measurements to Test Hypothesized Mechanisms in Single Molecule Conductance Switching”, J. Am. Chem. Soc, 128, 1959-1967, (2006).
  • [8] Bernard, M.C., Chausse, A., Cabert-Deliry, E., Chemimi, M.M., Pinson, J., Podvorica, F., Vautrin-U, C., “Organic Layers Bonded to Industrial, Coinage, and Noble Metals through Electrochemical Reduction of Aryldiazonium Salts”, Chem. Mater, 15: 3450-3462, (2003).
  • [9] Delamarche, E., Michel, B., Kong, H., Gerber, C.,“Thermal Stability of Self- Assembled Monolayers”, Langmuir, 10: 4103-4108, (1994).
  • [10] Yourdshahyan, Y. and Rappe, A. M., “Structure and Energetics of Alkanethiol Adsorption on The Au (111) Surface”, J. Chem. Phys, 117: 825-833, (2002).
  • [11] Obeng, Y.S., Bard, A.J., “Langmuir Films of C60 at the Air-Water Interface”, J. Am. Chem. Soc, 113: 6279-6280, (1991).
  • [12] Graves-Abe, T., Bao, Z., Sturm, J.C., “Self-Aligned, Insulating-Layer StructureforIntegrated Fabrication of Organic Self-Assembled Multilayer Electronic Devices”, Nano Letters, 4(12): 2489-2492, (2004).
  • [13] Green, J.E., Choi, J.W., Boukai, A., Bunimovich, Y., Halperin, E.J., DeIonno, E., Luo, Y., Sheriff, B.E., Xu, K., Shin, Y.S., Tseng, H.R., Heath, J., “160-Kilobit Molecular Electronic Memory Patterned at 10” Bits Per Square Centimeter”, Nature, 445: 414-417, (2007).
  • [14] Delamar, M., Hitmi, R., Pinson, J., Saveant, J.M., “Covalent Modification of Carbon Surfaces by Grafting of Functionalized Aryl Radicals Produced from Electrochemical Reduction of Diazonium Salts”, J. Am. Chem. Soc, 114: 5883-5884, (1992).
  • [15] Dunker, M. F. W., Starkey, E. B., Jenkins, G. L., “The Preparation of Some Organic Mercurials from Diazonium Borofluorides”, J. Am. Chem. Soc, 58: 2308–2309, (1936).
  • [16] Graber, K.C., Freman, R.G., Hommer, M.B., Natan, M.C., “Preparation and Characterision of Au Colloid Monalayers”, Anal. Chem, 69(4): 735-743, (1995).
  • [17] Swalen, J.D., Rabolt, J.F., “In Fourier Transform Infrared Spectroscopy” Academic Press, New York, 4: (1997).
  • [18] Saby, C., Ortiz, B., Champagne, G.Y., Belanger, D., “Electrochemical Modification of Glassy Carbon Electrode Using Aromatic Diazonium Salts. 1. Blocking Effect of 4-Nitrophenyl and 4-Carboxyphenyl Groups”, Langmuir, 13: 6805-6813, (1997).
  • [19] Kim, K., Lee, I., “Chemical Lithography by Ag-Nanoparticle-Mediated Photoreduction of Aromatic Nitro Monolayers on Au”, Langmuir, 20: 7351-7354, (2004).
  • [20] Mendes, P. M., Jacke, S., Critchley, K., Plaza, J., Chen, Y., Nikitin, K., Palmer, R. E., Preece, J. A., Evans, S. D., Fitzmaurice, D., “Gold Nanoparticle Patterning of Silicon Wafers using Chemical e-Beam Lithography”, Langmuir, 20: 3766-3768, (2004).

Synthesis and Characterization of Citrate-Capped Gold Nanoparticles on Covalently Modified Silicon Surfaces by Benzylamine Thin Films

Year 2019, Volume: 22 Issue: 2, 367 - 373, 01.06.2019
https://doi.org/10.2339/politeknik.498477

Abstract

In this study, we aimed to assembly of citrate-capped
gold nanoparticles on benzylamine thin films that covalently modified surfaces.
For this purpose, firstly, p-type Si (100) electrodes were modified with
benzylamine layers by electrochemical reduction of aryl diazonium salts        (+N2-benzylamine). Then, the
modified electrodes were submerged in a solution containing Au nanoparticles.
Finally, Au nanoparticles were electrostatically assembled on positively
charged benzylamine layers. The properties of the benzylamine films were
investigated using voltammetric methods. The barrier properties of modified
p-type Si (100) surfaces were studied by cyclic voltammetry in the presence of
redox probes (Fe(CN)63- and Ru(NH3)63+).
Also the final films generated for characterization and morphological analysis
were examined by scanning electron microscopy (SEM). 

References

  • [1] Katz, E., Willner, I., Wang, J., “Electroanalytical and Bioelectroanalytical Systems Based on Metal and Semiconductor Nanoparticles”, Electroanal, 16: 19-26, (2004).
  • [2] Dobrzanski, L.A., Pawlyta, M., Krzton, A., Lizzka, B., Labizz, K., “Synthesis and Characterization of Carbon Nanotubes Decorated with Platinum Nanoparticles”, J. Achiev. Mater. and Manuf. Eng., 39: 2, (2010).
  • [3] Honciuc, A., Jaiswal, A., Gong, A., Ashworth,K., Spangler, C.W., Peterson, R., Dalton, L., Metzger,R.M., “Current Rectification in a Langmuir-Schaefer Monolayer of Fullerene-bis-[4-diphenylamino-4-(N-ethyl-N 2-ethyl)amino-1,4-diphenyl-1,3-butadiene] Malonate between Au Electrodes”, J. Phys. Chem. B, 109: 857-871, (2005).
  • [4] Metzger, R.M., Chen, B., Ho1pfner, U., Lakshmikantham, M.V., Vuillaume, D., Kawai, T., Wu, X., Tachibana, H., Hughes, T.V., Sakurai, H., Baldwin, J.W., Hosch, C., Cava, M.P., Brehmer, L., Ashwell, G.J., 1997. “Unimolecular Electrical Rectification in Hexadecylquinolinium Tricyanoquinodimethanide”, J. Am. Chem. Soc, 119: 10455-10466, (1997).
  • [5] Blum, A.S., Kushmerick, J.G., Long, D.P., Patterson, C.H., Yang, J. C., Henderson, J.C., Yao, Y.X., Tour, J.M., Shashidhar, R., Ratna, B.R., “Molecularly Inherent Voltage-Controlled Conductance Switching”, Nature Materials, 4: 167-172, (2005).
  • [6] Collier, C.P., Jeppesen, J.O., Luo, Y., Perkins, J., Wong, E.W., Heath, J.R., Stoddart, J.F., “Molecular-Based Electronically Switchable Tunnel Junction Devices”, J. Am. Chem. Soc, 123: 12632-12641, (2001).
  • [7] Moore, A. M., Dameron, A. A., Mantooth, B. A., Smith, R. K., Fuchs, D. J. , Ciszek, J. W., Maya, F., Yao, Y., Tour, J.M., Weiss, P.S., “Molecular Engineering and Measurements to Test Hypothesized Mechanisms in Single Molecule Conductance Switching”, J. Am. Chem. Soc, 128, 1959-1967, (2006).
  • [8] Bernard, M.C., Chausse, A., Cabert-Deliry, E., Chemimi, M.M., Pinson, J., Podvorica, F., Vautrin-U, C., “Organic Layers Bonded to Industrial, Coinage, and Noble Metals through Electrochemical Reduction of Aryldiazonium Salts”, Chem. Mater, 15: 3450-3462, (2003).
  • [9] Delamarche, E., Michel, B., Kong, H., Gerber, C.,“Thermal Stability of Self- Assembled Monolayers”, Langmuir, 10: 4103-4108, (1994).
  • [10] Yourdshahyan, Y. and Rappe, A. M., “Structure and Energetics of Alkanethiol Adsorption on The Au (111) Surface”, J. Chem. Phys, 117: 825-833, (2002).
  • [11] Obeng, Y.S., Bard, A.J., “Langmuir Films of C60 at the Air-Water Interface”, J. Am. Chem. Soc, 113: 6279-6280, (1991).
  • [12] Graves-Abe, T., Bao, Z., Sturm, J.C., “Self-Aligned, Insulating-Layer StructureforIntegrated Fabrication of Organic Self-Assembled Multilayer Electronic Devices”, Nano Letters, 4(12): 2489-2492, (2004).
  • [13] Green, J.E., Choi, J.W., Boukai, A., Bunimovich, Y., Halperin, E.J., DeIonno, E., Luo, Y., Sheriff, B.E., Xu, K., Shin, Y.S., Tseng, H.R., Heath, J., “160-Kilobit Molecular Electronic Memory Patterned at 10” Bits Per Square Centimeter”, Nature, 445: 414-417, (2007).
  • [14] Delamar, M., Hitmi, R., Pinson, J., Saveant, J.M., “Covalent Modification of Carbon Surfaces by Grafting of Functionalized Aryl Radicals Produced from Electrochemical Reduction of Diazonium Salts”, J. Am. Chem. Soc, 114: 5883-5884, (1992).
  • [15] Dunker, M. F. W., Starkey, E. B., Jenkins, G. L., “The Preparation of Some Organic Mercurials from Diazonium Borofluorides”, J. Am. Chem. Soc, 58: 2308–2309, (1936).
  • [16] Graber, K.C., Freman, R.G., Hommer, M.B., Natan, M.C., “Preparation and Characterision of Au Colloid Monalayers”, Anal. Chem, 69(4): 735-743, (1995).
  • [17] Swalen, J.D., Rabolt, J.F., “In Fourier Transform Infrared Spectroscopy” Academic Press, New York, 4: (1997).
  • [18] Saby, C., Ortiz, B., Champagne, G.Y., Belanger, D., “Electrochemical Modification of Glassy Carbon Electrode Using Aromatic Diazonium Salts. 1. Blocking Effect of 4-Nitrophenyl and 4-Carboxyphenyl Groups”, Langmuir, 13: 6805-6813, (1997).
  • [19] Kim, K., Lee, I., “Chemical Lithography by Ag-Nanoparticle-Mediated Photoreduction of Aromatic Nitro Monolayers on Au”, Langmuir, 20: 7351-7354, (2004).
  • [20] Mendes, P. M., Jacke, S., Critchley, K., Plaza, J., Chen, Y., Nikitin, K., Palmer, R. E., Preece, J. A., Evans, S. D., Fitzmaurice, D., “Gold Nanoparticle Patterning of Silicon Wafers using Chemical e-Beam Lithography”, Langmuir, 20: 3766-3768, (2004).
There are 20 citations in total.

Details

Primary Language Turkish
Journal Section Research Article
Authors

Ali Yeşildağ This is me

Publication Date June 1, 2019
Submission Date January 10, 2018
Published in Issue Year 2019 Volume: 22 Issue: 2

Cite

APA Yeşildağ, A. (2019). Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu. Politeknik Dergisi, 22(2), 367-373. https://doi.org/10.2339/politeknik.498477
AMA Yeşildağ A. Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu. Politeknik Dergisi. June 2019;22(2):367-373. doi:10.2339/politeknik.498477
Chicago Yeşildağ, Ali. “Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi Ve Karakterizasyonu”. Politeknik Dergisi 22, no. 2 (June 2019): 367-73. https://doi.org/10.2339/politeknik.498477.
EndNote Yeşildağ A (June 1, 2019) Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu. Politeknik Dergisi 22 2 367–373.
IEEE A. Yeşildağ, “Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu”, Politeknik Dergisi, vol. 22, no. 2, pp. 367–373, 2019, doi: 10.2339/politeknik.498477.
ISNAD Yeşildağ, Ali. “Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi Ve Karakterizasyonu”. Politeknik Dergisi 22/2 (June 2019), 367-373. https://doi.org/10.2339/politeknik.498477.
JAMA Yeşildağ A. Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu. Politeknik Dergisi. 2019;22:367–373.
MLA Yeşildağ, Ali. “Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi Ve Karakterizasyonu”. Politeknik Dergisi, vol. 22, no. 2, 2019, pp. 367-73, doi:10.2339/politeknik.498477.
Vancouver Yeşildağ A. Benzilamin İnce Filmleri İle Kovalent Bir Şekilde Modifiye Edilmiş Silisyum Yüzeyleri Üzerinde Sitrat-Kaplı Altın Nanopartiküllerin Üretimi ve Karakterizasyonu. Politeknik Dergisi. 2019;22(2):367-73.