saujs

Sakarya University Journal of Science

2147-835X

Sakarya University

Inorganic Chemistry (Other) Material Production Technologies Materials Engineering (Other)

İnorganik Kimya (Diğer) Malzeme Üretim Teknolojileri Malzeme Mühendisliği (Diğer)

Eco-Friendly Green Synthesis of Zinc Oxide Nano/Microparticles Using Aqueous Leaf Extract of Polygonum cognatum Meisn. Plant

https://orcid.org/0000-0003-3391-627X

Akça

Erdem

SİVAS CUMHURİYET ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, METALURJİ VE MALZEME MÜHENDİSLİĞİ BÖLÜMÜ

10 25 2024

28 5 984 999 05 04 2024 08 06 2024

1997

Sakarya University Journal of Science

The environmentally friendly plant-based green synthesis approach provides a fabulous opportunity to produce versatile zinc oxide powders with multifarious morphology and/or size. In this study, it was mainly aimed at using Polygonum cognatum Meisn. extract to synthesize zinc oxide powder via a simple green synthesis route. For this purpose, zinc nitrate solution was mixed with an aqueous extract of fresh Polygonum cognatum Meisn. plant leaves to obtain a zinc-based precursor, and then zinc oxide powder was synthesized by means of calcination conducted at 400°C for 2 hours in air. Phase, spectroscopic, and microstructural analysis techniques, as well as Rietveld refinement method and Williamson-Hall analysis, were performed to investigate the powder characteristics. It was found that the synthesized high-purity zinc oxide powder had a hexagonal wurtzite crystal structure. Zinc oxide powder was observed to have a particularly large amount of nano-sized equiaxed particles (~25 nm in average diameter) together with micron-sized hourglass-like particles consisting of two hexagonal prisms (each <1 μm in height). All in all, the main implication of our research is that the Polygonum cognatum Meisn. plant can be potentially used as a biomass source for the green synthesis of zinc oxide nano/microparticles.

Green synthesis Polygonum cognatum Meisn Zinc oxide Powder characterization Nanoparticles

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