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<article  article-type="research-article"        dtd-version="1.4">
            <front>

                <journal-meta>
                                                                <journal-id>saujs</journal-id>
            <journal-title-group>
                                                                                    <journal-title>Sakarya University Journal of Science</journal-title>
            </journal-title-group>
                                        <issn pub-type="epub">2147-835X</issn>
                                                                                            <publisher>
                    <publisher-name>Sakarya University</publisher-name>
                </publisher>
                    </journal-meta>
                <article-meta>
                                        <article-id pub-id-type="doi">10.16984/saufenbilder.1506764</article-id>
                                                                <article-categories>
                                            <subj-group  xml:lang="en">
                                                            <subject>Material Production Technologies</subject>
                                                    </subj-group>
                                            <subj-group  xml:lang="tr">
                                                            <subject>Malzeme Üretim Teknolojileri</subject>
                                                    </subj-group>
                                    </article-categories>
                                                                                                                                                        <title-group>
                                                                                                                        <article-title>Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching</article-title>
                                                                                                                                        </title-group>
            
                                                    <contrib-group content-type="authors">
                                                                        <contrib contrib-type="author">
                                                                    <contrib-id contrib-id-type="orcid">
                                        https://orcid.org/0000-0002-4348-8865</contrib-id>
                                                                <name>
                                    <surname>Algül</surname>
                                    <given-names>Hasan</given-names>
                                </name>
                                                                    <aff>SAKARYA ÜNİVERSİTESİ</aff>
                                                            </contrib>
                                                    <contrib contrib-type="author">
                                                                    <contrib-id contrib-id-type="orcid">
                                        https://orcid.org/0000-0002-0314-1613</contrib-id>
                                                                <name>
                                    <surname>Algül</surname>
                                    <given-names>Figen</given-names>
                                </name>
                                                                    <aff>SAKARYA ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, METALURJİ VE MALZEME MÜHENDİSLİĞİ BÖLÜMÜ, ÜRETİM METALURJİSİ ANABİLİM DALI</aff>
                                                            </contrib>
                                                                                </contrib-group>
                        
                                        <pub-date pub-type="pub" iso-8601-date="20241025">
                    <day>10</day>
                    <month>25</month>
                    <year>2024</year>
                </pub-date>
                                        <volume>28</volume>
                                        <issue>5</issue>
                                        <fpage>1000</fpage>
                                        <lpage>1009</lpage>
                        
                        <history>
                                    <date date-type="received" iso-8601-date="20240628">
                        <day>06</day>
                        <month>28</month>
                        <year>2024</year>
                    </date>
                                                    <date date-type="accepted" iso-8601-date="20240902">
                        <day>09</day>
                        <month>02</month>
                        <year>2024</year>
                    </date>
                            </history>
                                        <permissions>
                    <copyright-statement>Copyright © 1997, Sakarya University Journal of Science</copyright-statement>
                    <copyright-year>1997</copyright-year>
                    <copyright-holder>Sakarya University Journal of Science</copyright-holder>
                </permissions>
            
                                                                                                <abstract><p>This study investigates the effect of mechanical activation parameters such as mechanical activation rotation speed (0-550 rpm), mechanical activation time (15-75 min), and solid/ball ratio (1/20-1/50) on the leaching efficiencies in the recycling of lithium-ion batteries. In addition to mechanical activation, the study explores the use of organic acids, specifically citric acid, as leaching agents to enhance metal recovery. A green and innovative recycling process is developed, focusing on optimal conditions of 15 minutes activation time, 450 rpm rotational speed, and a 1/20 solid/ball ratio. The synergistic effect of mechanical activation and organic acid leaching is examined to optimize the process for sustainability and efficiency in recovering valuable metals from lithium-ion batteries. Results indicate that these parameters significantly influence leaching efficiencies, with the highest yields achieved under the identified conditions. This research contributes to advancing sustainable practices in battery recycling by integrating mechanical activation and organic acid leaching as effective and environmentally friendly approaches. The findings highlight the potential of these methods in advancing green technology and materials science, paving the way for more efficient and eco-friendly battery recycling processes.</p></abstract>
                                                                                    
            
                                                            <kwd-group>
                                                    <kwd>Batery recycling</kwd>
                                                    <kwd>  Citric acid leaching</kwd>
                                                    <kwd>  Li and co extraction</kwd>
                                                    <kwd>  Mechanical activation rotation speed</kwd>
                                                    <kwd>  Mechanical activation time</kwd>
                                            </kwd-group>
                                                        
                                                                                                                                                <funding-group specific-use="FundRef">
                    <award-group>
                                                    <funding-source>
                                <named-content content-type="funder_name">Sakarya University Science Research Projects Coordinators</named-content>
                            </funding-source>
                                                                            <award-id>SAU BAP 2022-6-23-63</award-id>
                                            </award-group>
                </funding-group>
                                </article-meta>
    </front>
    <back>
                            <ref-list>
                                    <ref id="ref1">
                        <label>1</label>
                        <mixed-citation publication-type="journal">D. J. Garole, R. Hossain, V. J. Garole, V. Sahajwalla, J. Nerkar, D. P. Dubal, “Recycle, Recover and Repurpose Strategy of Spent Li-ion Batteries and Catalysts: Current Status and Future Opportunities,” ChemSusChem, vol. 13, pp. 3079-3100, 2020.</mixed-citation>
                    </ref>
                                    <ref id="ref2">
                        <label>2</label>
                        <mixed-citation publication-type="journal">G. Harper, R. Sommerville, E. Kendrick, L. Driscoll, P. Slater, R. Stolkin, A. Walton, P. Christensen, O. Heidrich, S. Lambert, A. Abbott, K. Ryder, L. Gaines, P. Anderson, “Recycling lithium-ion batteries from electric vehicles,” Nature, vol. 575, pp. 75-86, 2019.</mixed-citation>
                    </ref>
                                    <ref id="ref3">
                        <label>3</label>
                        <mixed-citation publication-type="journal">Y. Miao, L. Liu, Y. Zhang, Q. Tan, J. Li, “An overview of global power lithium-ion batteries and associated critical metal recycling,” Journal of Hazardous Materials, vol. 425, pp. 1279001-14, 2022.</mixed-citation>
                    </ref>
                                    <ref id="ref4">
                        <label>4</label>
                        <mixed-citation publication-type="journal">M. Jiao, Y. Wang, C. Ye, C. Wang, W. Zhang, C. Liang, &quot;High-capacity SiOx (0≤x≤2) as promising anode materials for next-generation lithium-ion batteries,&quot; Journal of Alloys and Compounds, vol. 482, pp.155774 1-21, 2020.</mixed-citation>
                    </ref>
                                    <ref id="ref5">
                        <label>5</label>
                        <mixed-citation publication-type="journal">X. Zhang, S. Han, P. Xiao, C. Fan, W. Zhang, “Thermal reduction of graphene oxide mixed with hard carbon and their high performance as lithium ion battery anode,” Carbon, vol. 100, pp. 600-607, 2016.</mixed-citation>
                    </ref>
                                    <ref id="ref6">
                        <label>6</label>
                        <mixed-citation publication-type="journal">S. L. Chou, Y. Pan, J. Z. Wang, H. K. Liu, S. X. Dou, “Small things make a big difference: Binder effects on the performance of Li and Na batteries,” Physical Chemistry Chemical Physics, vol. 16, pp.  20347-20359, 2014.</mixed-citation>
                    </ref>
                                    <ref id="ref7">
                        <label>7</label>
                        <mixed-citation publication-type="journal">E. Asadi Dalini, G. Karimi, S. Zandevakili, M. Goodarzi, “A Review on Environmental, Economic and Hydrometallurgical Processes of Recycling Spent Lithium-ion Batteries,” Mineral Processing and Extractive Metallurgy Review, vol. 42, no. 7, pp. 451-472, 2020.</mixed-citation>
                    </ref>
                                    <ref id="ref8">
                        <label>8</label>
                        <mixed-citation publication-type="journal">Y. Yang, G. Huang, S. Xu, Y. He, X. Liu, “Thermal treatment process for the recovery of valuable metals from spent lithium-ion batteries,” Hydrometallurgy, vol. 165, pp. 390-396, 2016.</mixed-citation>
                    </ref>
                                    <ref id="ref9">
                        <label>9</label>
                        <mixed-citation publication-type="journal">R. Golmohammadzadeh, F. Rashchi, E. Vahidi, “Recovery of lithium and cobalt from spent lithium-ion batteries using organic acids: Process optimization and kinetic aspects,” Waste Management, vol. 64, pp. 244-254, 2017.</mixed-citation>
                    </ref>
                                    <ref id="ref10">
                        <label>10</label>
                        <mixed-citation publication-type="journal">G. Mishra, R. Jha, A. Meshram, K. K. Singh, &quot;A review on recycling of lithium-ion batteries to recover critical metals,&quot; Journal of Environmental Chemical Engineering, vol. 10 (6), pp. 108534 1-15, 2022.</mixed-citation>
                    </ref>
                                    <ref id="ref11">
                        <label>11</label>
                        <mixed-citation publication-type="journal">M. Joulié, E. Billy, R. Laucournet, D. Meyer, “Current collectors as reducing agent to dissolve active materials of positive electrodes from Li-ion battery wastes,” Hydrometallurgy, vol. 169, pp. 426-432, 2017.</mixed-citation>
                    </ref>
                                    <ref id="ref12">
                        <label>12</label>
                        <mixed-citation publication-type="journal">W. Gao, C. Liu, H. Cao, X. Zheng, X. Lin, H. Wang, Y. Zhang, Z. Sun, “Comprehensive evaluation on effective leaching of critical metals from spent lithium-ion batteries,” Waste Management, vol. 75, pp.477-485, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref13">
                        <label>13</label>
                        <mixed-citation publication-type="journal">R. C. Wang, Y. C. Lin, S. H. Wu, “A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries,” Hydrometallurgy, vol. 99, pp. 194-201, 2009.</mixed-citation>
                    </ref>
                                    <ref id="ref14">
                        <label>14</label>
                        <mixed-citation publication-type="journal">L. Li, R. Chen, F. Sun, F. Wu, J. Liu, “Preparation of LiCoO2 films from spent lithium-ion batteries by a combined recycling process,” Hydrometallurgy, vol. 108, pp. 220-225, 2011.</mixed-citation>
                    </ref>
                                    <ref id="ref15">
                        <label>15</label>
                        <mixed-citation publication-type="journal">D. A. Ferreira, L. M. Z. Prados, D. Majuste, M. B. Mansur, “Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries,” Journal of Power Sources, vol. 187, pp. 238-246, 2009.</mixed-citation>
                    </ref>
                                    <ref id="ref16">
                        <label>16</label>
                        <mixed-citation publication-type="journal">E. Gratz, Q. Sa, D. Apelian, Y. Wang, “A closed loop process for recycling spent lithium ion batteries,” Journal of Power Sources, vol. 262, pp. 255-262, 2014.</mixed-citation>
                    </ref>
                                    <ref id="ref17">
                        <label>17</label>
                        <mixed-citation publication-type="journal">Y. Guo, F. Li, H. Zhu, G. Li, J. Huang, W. He, “Leaching lithium from the anode electrode materials of spent lithium-ion batteries by hydrochloric acid (HCl),” Waste Management, vol. 51, pp. 227-233, 2016.)</mixed-citation>
                    </ref>
                                    <ref id="ref18">
                        <label>18</label>
                        <mixed-citation publication-type="journal">L. Li, W. Qu, X. Zhang, J. Lu, R. Chen, F. Wu, K. Amine, “Succinic acid-based leaching system: A sustainable process for recovery of valuable metals from spent Li-ion batteries,” Journal of Power Sources, vol. 282, pp. 544-551, 2015.</mixed-citation>
                    </ref>
                                    <ref id="ref19">
                        <label>19</label>
                        <mixed-citation publication-type="journal">Q. Sa, E. Gratz, M. He, W. Lu, D. Apelian, Y. Wang, “Synthesis of high performance LiNi1/3Mn1/3Co1/3O2 from lithium ion battery recovery stream,” Journal of Power Sources, vol. 282, pp. 140-154, 2015.</mixed-citation>
                    </ref>
                                    <ref id="ref20">
                        <label>20</label>
                        <mixed-citation publication-type="journal">L. Yao, Y. Feng, G. Xi, “A new method for the synthesis of LiNi1/3Co1/3Mn1/3O2 from waste lithium ion batteries,” RSC Advances, vol. 5, pp. 44107-44114, 2015.</mixed-citation>
                    </ref>
                                    <ref id="ref21">
                        <label>21</label>
                        <mixed-citation publication-type="journal">X. Zheng, Z. Zhu, X. Lin, Y. Zhang, Y. He, H. Cao, Z. Sun, “A Mini-Review on Metal Recycling from Spent Lithium Ion Batteries,” Engineering, vol. 4, pp. 361-370, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref22">
                        <label>22</label>
                        <mixed-citation publication-type="journal">L. Li, J. Ge, F. Wu, R. Chen, S. Chen, B. Wu, “Recovery of cobalt and lithium from spent lithium ion batteries using organic citric acid as leachant,” Journal of Hazardous Materials, vol. 176, pp. 288-293, 2010.</mixed-citation>
                    </ref>
                                    <ref id="ref23">
                        <label>23</label>
                        <mixed-citation publication-type="journal">P. Balaz, “Mechanical activation in hydrometallurgy,” International Journal of Mineral Processing, vol. 72, pp. 341-354, 2003.</mixed-citation>
                    </ref>
                                    <ref id="ref24">
                        <label>24</label>
                        <mixed-citation publication-type="journal">D. Tromans, J. A. Meech, “Enhanced Dissolution of Minerals: Stored Energy,” Amorphism and Mechanical Activation, vol. 14, no. 7, 1359-1377, 2001.</mixed-citation>
                    </ref>
                                    <ref id="ref25">
                        <label>25</label>
                        <mixed-citation publication-type="journal">X. Zeng, J. Li, N. Singh, “Recycling of spent lithium-ion battery: A critical review,” Critical Reviews in Environmental Science and Technology, vol. 44, pp. 1129-1165, 2014.</mixed-citation>
                    </ref>
                                    <ref id="ref26">
                        <label>26</label>
                        <mixed-citation publication-type="journal">J. Guan, H. Xiao, X. Lou, Y. Guo, X. Luo, Y. Li, C. Yan, X. Yan, G. Gao, H. Yuan, J. Dai, R. Su, W. Gu, Z. Guo, “Enhanced Hydrometallurgical Recovery of Valuable Metals from Spent Lithium-ion Batteries by Mechanical Activation Process,” ES Energy &amp; Environment, vol. 1, pp. 80-88, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref27">
                        <label>27</label>
                        <mixed-citation publication-type="journal">S. Zhang, C. Zhang, X. Zhang, E. Ma, “A mechanochemical method for one-step leaching of metals from spent LIBs,” Waste Management, vol. 161, pp. 245-253, 2023.</mixed-citation>
                    </ref>
                                    <ref id="ref28">
                        <label>28</label>
                        <mixed-citation publication-type="journal">Y. Yang, X. Zheng, H. Cao, C. Zhao, X. Lin, P. Ning, Y. Zhang, W. Jin, Z. Sun, “A Closed-Loop Process for Selective Metal Recovery from Spent Lithium Iron Phosphate Batteries through Mechanochemical Activation,” ACS Sustainable Chemistry &amp; Engineering, vol. 5, pp. 9972-9980, 2017.</mixed-citation>
                    </ref>
                                    <ref id="ref29">
                        <label>29</label>
                        <mixed-citation publication-type="journal">B. Musariri, G. Akdogan, C. Dorfling, S. Bradshaw, “Evaluating organic acids as alternative leaching reagents for metal recovery from lithium ion batteries,” Minerals Engineering, vol. 137, pp. 108-117, 2019.</mixed-citation>
                    </ref>
                                    <ref id="ref30">
                        <label>30</label>
                        <mixed-citation publication-type="journal">M. Wang, Q. Tan, J. Li, “Unveiling the Role and Mechanism of Mechanochemical Activation on Lithium Cobalt Oxide Powders from Spent Lithium-Ion Batteries,” Environmental Science and Technology, vol. 52, pp. 13136-13143, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref31">
                        <label>31</label>
                        <mixed-citation publication-type="journal">N. V. Kosova, V. F. Anufrienko, T. V. Larina, A. Rougier, L. Aymard, J. M. Tarascon, “Disordering and electronic state of cobalt ions in mechanochemically synthesized LiCoO2,” Journal of Solid State Chemistry, vol. 165, pp. 56-64, 2002.</mixed-citation>
                    </ref>
                                    <ref id="ref32">
                        <label>32</label>
                        <mixed-citation publication-type="journal">J. Guan, H. Xiao, X. Lou, Y. Guo, X. Luo, Y. Li, C. Yan, X. Yan, G. Gao, H. Yuan, J. Dai, R. Su, W. Gu, Z. Guo, “Enhanced Hydrometallurgical Recovery of Valuable Metals from Spent Lithium-ion Batteries by Mechanical Activation Process,” ES Energy &amp; Environment, vol. 1, 80-88, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref33">
                        <label>33</label>
                        <mixed-citation publication-type="journal">J. Guan, Y. Li, Y. Guo, R. Su, G. Gao, H. Song, H. Yuan, B. Liang, Z. Guo, “Mechanochemical Process Enhanced Cobalt and Lithium Recycling from Wasted Lithium-Ion Batteries,” ACS Sustainable Chemistry &amp; Engineering, vol. 5, pp. 1026-1032, 2017.</mixed-citation>
                    </ref>
                                    <ref id="ref34">
                        <label>34</label>
                        <mixed-citation publication-type="journal">L. Li, J. Ge, R. Chen, F. Wu, S. Chen, X. Zhang, “Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium-ion batteries,” Waste Management, vol. 30, pp. 2615-2621, 2010.</mixed-citation>
                    </ref>
                            </ref-list>
                    </back>
    </article>
