saujs

Sakarya University Journal of Science

2147-835X

Sakarya University

10.16984/saufenbilder.296995

Material Production Technologies

Malzeme Üretim Teknolojileri

The Production and characterization of tin (II) oxide composite anode electrodes for lithium ion batteries

Lityum iyon piller için kalay (II) oksit kompozit anot elektrotlarının üretimi ve karakterizasyonu

Güler

Mehmet Oğuz

04 01 2017

21 2 150 156 10 31 2016 11 16 2016

1997

Sakarya University Journal of Science

In this study, the core componentof the composite, tin (II) oxide powders synthesized through a facile chemicalreduction methods for Li-ion batteries. As the shell structure, surfaces of theas-synthesized tin (II) oxide particles were coated with carbon throughmicrowave assisted carburization process. The surface morphologies and phasecomponents of the as-synthesized tin (II) oxide/carbon composites wereinvestigated via scanning electron microscopy and X-ray diffraction methods,respectively. CR2016 type coin cells were prepared by using tin (II)oxide/carbon composite powders and electrochemical tests were performed at roomtemperature via 8-channel MTI BST8‒MA electrochemical test station between 10mV and 2.5 V potential range by applying fixed 1 C state of charge conditions.The results have shown that tin (II) oxide/carbon composite structure havesignificantly improved the specific capacities to 396 mAh g-1 after 100 cycles.

Bu çalışmada Li-iyon piller için uyumlu çekirdek olarak kalay (II) oksit anotlar kimyasal indirgeme yöntemi ile sentezlenmiştir. Karbon esaslı kabuk sentezi için mikrodalga destekli karbürizasyon yöntemi kullanılmış ve SnO tozlarının yüzeylerinde ince amorf bir karbon tabakası elde edilmiştir. Üretilen kalay (II) oksit/karbon kompozit elektrotların yüzey morfolojileri Taramalı Elektron Mikroskobu (SEM) ile analiz edilmiş ve yapıların faz bileşenleri X-Işınları Difraktometresi (XRD) ile karakterize edilmiştir. Üretilen kalay (II) oksit/karbon kompozit tozları kullanılarak hazırlanan elektrotlar ile CR2016 test hücreleri hazırlanmış ve elektrotların elektrokimyasal performansı MTI BST8‒MA 8 kanallı pil test ünitesinde, oda sıcaklığında 10 mV ve 2,5 V arasında sabit 1C şarj/deşarj şartlarında akım verilerek test edilmiştir. Sonuç olarak, kalay (II) oksit/karbon kompozit elektrot malzemeleri ile 100 çevrim sonrasında 396 mAh g-1 deşarj kapasitesi elde edilmiştir.

Tin (II) oxide core/shell chemical reduction microwave assisted carburization Li ion battery

Kalay (II) oksit çekirdek/kabuk kimyasal indirgeme mikrodalga destekli karbürizasyon Li iyon pil

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