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            <front>

                <journal-meta>
                                                                <journal-id>saujs</journal-id>
            <journal-title-group>
                                                                                    <journal-title>Sakarya University Journal of Science</journal-title>
            </journal-title-group>
                                        <issn pub-type="epub">2147-835X</issn>
                                                                                            <publisher>
                    <publisher-name>Sakarya University</publisher-name>
                </publisher>
                    </journal-meta>
                <article-meta>
                                        <article-id pub-id-type="doi">10.16984/saufenbilder.761756</article-id>
                                                                                                                                                                                            <title-group>
                                                                                                                        <article-title>The Role of Sodium Lauryl Sulfate on the Film Properties of Styrene-Butyl Acrylate-Acrylic Acid Copolymer Latex</article-title>
                                                                                                                                        </title-group>
            
                                                    <contrib-group content-type="authors">
                                                                        <contrib contrib-type="author">
                                                                    <contrib-id contrib-id-type="orcid">
                                        https://orcid.org/0000-0001-9775-9360</contrib-id>
                                                                <name>
                                    <surname>Eren</surname>
                                    <given-names>Bilge</given-names>
                                </name>
                                                                    <aff>BİLECİK ŞEYH EDEBALİ ÜNİVERSİTESİ</aff>
                                                            </contrib>
                                                    <contrib contrib-type="author">
                                                                    <contrib-id contrib-id-type="orcid">
                                        https://orcid.org/0000-0001-9585-9587</contrib-id>
                                                                <name>
                                    <surname>Solmaz</surname>
                                    <given-names>Yasemin</given-names>
                                </name>
                                                                    <aff>BILECIK SEYH EDEBALI UNIVERSITY</aff>
                                                            </contrib>
                                                                                </contrib-group>
                        
                                        <pub-date pub-type="pub" iso-8601-date="20201001">
                    <day>10</day>
                    <month>01</month>
                    <year>2020</year>
                </pub-date>
                                        <volume>24</volume>
                                        <issue>5</issue>
                                        <fpage>1074</fpage>
                                        <lpage>1080</lpage>
                        
                        <history>
                                    <date date-type="received" iso-8601-date="20200701">
                        <day>07</day>
                        <month>01</month>
                        <year>2020</year>
                    </date>
                                                    <date date-type="accepted" iso-8601-date="20200811">
                        <day>08</day>
                        <month>11</month>
                        <year>2020</year>
                    </date>
                            </history>
                                        <permissions>
                    <copyright-statement>Copyright © 1997, Sakarya University Journal of Science</copyright-statement>
                    <copyright-year>1997</copyright-year>
                    <copyright-holder>Sakarya University Journal of Science</copyright-holder>
                </permissions>
            
                                                                                                <abstract><p>In this study, the concentration effect of sodium lauryl sulfate (SLS) as a surfactant in the synthesis of styrene/acrylic acid/butyl acrylate copolymer (SAC) latex particles via seeded emulsion polymerization technique was investigated. Scanning electron microscopy (SEM), minimum film-forming temperature (MFFT), differential scanning calorimetry (DSC), dynamic light scattering (DLS), and thermal gravimetric analysis (TGA) techniques were used to explain the change on physicochemical properties and morphology. The main goal is to determine an optimal surfactant concentration to obtain latexes with low MFFT. DLS studies showed that the particle size decreases 118.30 to 75.18 nm with the increase of SLS concentration. MFFT of latexes decreased with increasing SLS concentration. From the TGA curves, it was found that all the SAC latex particles exhibit a three-step decomposition process. The observed single Tg values for SAC particles showed that the latexes were prepared successfully.</p></abstract>
                                                                                    
            
                                                            <kwd-group>
                                                    <kwd>latex</kwd>
                                                    <kwd>  Emulsion polymer</kwd>
                                                    <kwd>  Acrylate</kwd>
                                                    <kwd>  Styrene</kwd>
                                            </kwd-group>
                                                        
                                                                                                                                                <funding-group specific-use="FundRef">
                    <award-group>
                                                    <funding-source>
                                <named-content content-type="funder_name">Bilecik Şeyh Edebali University</named-content>
                            </funding-source>
                                                                            <award-id>2018-01.BŞEÜ.04-07</award-id>
                                            </award-group>
                </funding-group>
                                </article-meta>
    </front>
    <back>
                            <ref-list>
                                    <ref id="ref1">
                        <label>1</label>
                        <mixed-citation publication-type="journal">N. K. Ray and V. Gundabala, “Synthesis and characterization of titanium dioxide encapsulated poly (styrene-co-butyl acrylate-co-acrylic acid) nanocomposite latex,” Progress in Organic Coatings, vol. 111, pp. 93-98, 2017.</mixed-citation>
                    </ref>
                                    <ref id="ref2">
                        <label>2</label>
                        <mixed-citation publication-type="journal">T. Ramde, LG. Ecco and S. Rossi, “Visual appearance durability as function of natural and accelerated ageing of electrophoretic styrene-acrylic coatings: Influence of yellow pigment concentration,” Progress in Organic Coatings, vol. 103, pp. 23-32, 2017.</mixed-citation>
                    </ref>
                                    <ref id="ref3">
                        <label>3</label>
                        <mixed-citation publication-type="journal">W. J. Grigsby. “Photooxidative stability provided by condensed tannin additives in acrylic-based surface coatings on exterior exposure,” Journal of Coatings Technology and Research, vol. 15, pp. 1273-1282, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref4">
                        <label>4</label>
                        <mixed-citation publication-type="journal">M. Ataeefard, “Preparing nanosilver/styrene-butyl acrylate core-shell composite via eco-friendly emulsion aggregation method as a printing ink,” Colloid and Polymer Science, vol. 296, pp. 819-827, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref5">
                        <label>5</label>
                        <mixed-citation publication-type="journal">A. Rajaee and G. Farzi, “Encapsulation of paclitaxel in ultra-fine nanoparticles of acrylic/styrene terpolymer for controlled release,” Colloid and Polymer Science, vol. 294, pp. 95-105, 2016.</mixed-citation>
                    </ref>
                                    <ref id="ref6">
                        <label>6</label>
                        <mixed-citation publication-type="journal">E. Limousi, N. Ballard and J. M. Asua, “The influence of particle morphology on the structure and mechanical properties of films cast from hybrid latexes,” Progress in Organic Coatings, vol. 129, pp. 69-76, 2019.</mixed-citation>
                    </ref>
                                    <ref id="ref7">
                        <label>7</label>
                        <mixed-citation publication-type="journal">H. A. Abdel-Rahman, M.M. Younes and M.M. Khatta, “Effect of waste glass content on the physico-chemical and mechanical properties of styrene acrylic ester blended cement mortar composites,” Polymers and Polymer Composites, vol. 39, pp. 985-996, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref8">
                        <label>8</label>
                        <mixed-citation publication-type="journal">I. Barata, A. C. Fonseca, C. S. M. F. Costa, L. Ferreira, E. Julio and J. F. J. Coelho, “Insights into the thermo-mechanical properties of films cast from emulsion terpolymers,” Progress in Organic Coatings, vol. 77, pp. 790-797, 2014.</mixed-citation>
                    </ref>
                                    <ref id="ref9">
                        <label>9</label>
                        <mixed-citation publication-type="journal">O. F. Pacheco-Salazar, S. Wakayama, T. Sakai, C. R. Rios-Soberanis, J. V. Cauich-Rodriguez and J.M. Cervantes-Uc, “Damage accumulation studied by acoustic emission in bone cement prepared with core-shell nanoparticles under fatigue,” Journal of Materials Science, vol. 51, pp. 5635-5645, 2016.</mixed-citation>
                    </ref>
                                    <ref id="ref10">
                        <label>10</label>
                        <mixed-citation publication-type="journal">L. Shao-Jie, H. Qian-Qian, Z. Feng-Qing and C. Xiao-Menga, “Utilization of steel slag, iron tailings and fly ash as aggregates to prepare a polymer-modified waterproof mortar with a core shell styrene-acrylic copolymer as the modifier,” Construction and Building Materials, vol. 72, pp. 15-22, 2014.</mixed-citation>
                    </ref>
                                    <ref id="ref11">
                        <label>11</label>
                        <mixed-citation publication-type="journal">F. Z. Wang, Y. W. Luo, B. G. Li and S. P. Zhu, “Synthesis and Redispersibility of Poly, styrene-block n-butyl acrylate) Core-Shell Latexes by Emulsion Polymerization with RAFT Agent-Surfactant Design,” Macromolecules. vol. 48, pp. 1313-1319, 2015.</mixed-citation>
                    </ref>
                                    <ref id="ref12">
                        <label>12</label>
                        <mixed-citation publication-type="journal">K. K. Jaiswal, D. Manikandan, R. Murugan and A. P. Ramaswamy, “Microwave-assisted rapid synthesis of Fe3O4/poly, styrene-divinylbenzene-acrylic acid) polymeric magnetic composites and investigation of their structural and magnetic properties,” European Polymer Journal, vol. 98, pp. 177-190, 2018.</mixed-citation>
                    </ref>
                                    <ref id="ref13">
                        <label>13</label>
                        <mixed-citation publication-type="journal">P. A. Stewarda, J. U. Hearna and M. C. Wilkinson, “An overview of polymer latex film formation and properties,” Advances in Colloid and Interface Science, vol. 86, pp. 195-267, 2000.</mixed-citation>
                    </ref>
                                    <ref id="ref14">
                        <label>14</label>
                        <mixed-citation publication-type="journal">V. Kumthekar and S. Kolekar, “Attributes of the latex emulsion processing and its role in morphology and performance in paints,” Progress in Organic Coatings, vol. 72, pp. 380-386, 2011.</mixed-citation>
                    </ref>
                                    <ref id="ref15">
                        <label>15</label>
                        <mixed-citation publication-type="journal">H. Mori and A. H. E. Muller, “New polymeric architectures with (meth)acrylic acid segments,” Progress in Polymer Science, vol. 28, pp. 1403-1439, 2003.</mixed-citation>
                    </ref>
                                    <ref id="ref16">
                        <label>16</label>
                        <mixed-citation publication-type="journal">M. A. Trojer, L. Nordstierna, J. Bergek, H. Blanck, K. Holmberg and M. Nydéna, “Use of microcapsules as controlled release devices for coatings,” Journal of Colloid and Interface Science, vol. 222, pp. 18-43, 2015.</mixed-citation>
                    </ref>
                                    <ref id="ref17">
                        <label>17</label>
                        <mixed-citation publication-type="journal">S. Srivastava, “Co-polymerization of Acrylates,” Designed Monomers and Polymers, vol. 12, pp. 1-18, 2009.</mixed-citation>
                    </ref>
                                    <ref id="ref18">
                        <label>18</label>
                        <mixed-citation publication-type="journal">[Z. W. Wicks, D.A. Wicks and J. W. Rosthauser, “Two package waterborne urethane systems,” Progress in Organic Coatings, vol. 44, pp. 161-183, 2002.</mixed-citation>
                    </ref>
                                    <ref id="ref19">
                        <label>19</label>
                        <mixed-citation publication-type="journal">J. Huybrechts, P. Bruylants, A. Vaes and A. D. Marre, “Surfactant-free emulsions for waterborne, two-component polyurethane coatings,” Progress in Organic Coatings, vol. 38, pp. 67-77, 2000.</mixed-citation>
                    </ref>
                                    <ref id="ref20">
                        <label>20</label>
                        <mixed-citation publication-type="journal">C. H. Lee and R. G. Mallinson, “Surfactant effects in the emulsion polymerization of vinyl acetate,” Journal of Applied Polymer Science, vol. 39, pp. 2205-2218, 1990.</mixed-citation>
                    </ref>
                                    <ref id="ref21">
                        <label>21</label>
                        <mixed-citation publication-type="journal">L. M. Gan, K. C. Lee, C. H. Chew and S. C. Ng, “Effects of Surfactant Concentration on Polymerization of Methyl Methacrylate and Styrene in Emulsions and Microemulsions,” Langmuir. vol. 11, pp. 449-454, 1995.</mixed-citation>
                    </ref>
                                    <ref id="ref22">
                        <label>22</label>
                        <mixed-citation publication-type="journal">S. Feiz and A. H. Navarchian, “Emulsion polymerization of styrene: Simulation the effects of mixed ionic and non-ionic surfactant system in the presence of coagulation,” Chemical Engineering Science, vol. 69, pp. 431-439, 2012.</mixed-citation>
                    </ref>
                                    <ref id="ref23">
                        <label>23</label>
                        <mixed-citation publication-type="journal">F. A. Hassaroeieh, F. F. Tabrizi and H. Abedini, “Effect of Surfactant Concentration on the Dispersion Coefficient for the Comparison of Model and Experimental Results in Emulsion Polymerization of Butadiene,” Chemical Engineering Communications, vol. 203(5), pp. 609-618, 2016.</mixed-citation>
                    </ref>
                                    <ref id="ref24">
                        <label>24</label>
                        <mixed-citation publication-type="journal">J. I. Amalvy, “Colloidal and film properties of carboxylated acrylic latices ‐ effect of surfactant concentration,” Pigment &amp; Resin Technology, vol. 27, pp. 20-27, 1998.</mixed-citation>
                    </ref>
                                    <ref id="ref25">
                        <label>25</label>
                        <mixed-citation publication-type="journal">Z. Faai, Y. Wang, L. Yuan and C. Chai, “Synthesis of Acrylic Emulsion Containing High Hydroxyl Content,” Journal of Macromolecular Science, Part A, vol. A41, pp. 15-27, 2004.</mixed-citation>
                    </ref>
                                    <ref id="ref26">
                        <label>26</label>
                        <mixed-citation publication-type="journal">J. Chanra, E. Budianto and B. Soegijono, “The Role of SDS Surfactant in The Synthesis of Polymer Hybrid Latex Poly-(St-co-BA-co-MMA) with OMMT as Filler via Mini-Emulsion Polymerization,” IOP Conference Series: Materials Science and Engineering, vol. 515(1), 012059, 2019.</mixed-citation>
                    </ref>
                                    <ref id="ref27">
                        <label>27</label>
                        <mixed-citation publication-type="journal">B. Eren and Y. Solmaz, “Preparation and properties of negatively charged styrene acrylic latex particles cross-linked with divinylbenzene,” Journal of Thermal Analysis and Calorimetry, vol. 41, pp. 1331-1339, 2020.</mixed-citation>
                    </ref>
                                    <ref id="ref28">
                        <label>28</label>
                        <mixed-citation publication-type="journal">B. Podkościelna, M. Sobiesiak, Y. Zhao, B. Gawdzik and O. Sevastyanova, “Preparation of Lignin-containing Porous Microspheres through the Copolymerization of Lignin Acrylate Derivatives with Styrene and Divinylbenzene,” Holzforschung. vol. 69, pp. 769-776, 2015.</mixed-citation>
                    </ref>
                                    <ref id="ref29">
                        <label>29</label>
                        <mixed-citation publication-type="journal">H. J. Naghash, A. Karımzadeh, A. R. Momenı, A. R. Massah and H. Alıan, “Preparation and Properties of Triethoxyvinylsilane-Modified Styrene- Butyl Acrylate Emulsion Copolymers,” Turkish Journal of Chemistry, vol. 31, pp. 267-269, 2007.</mixed-citation>
                    </ref>
                                    <ref id="ref30">
                        <label>30</label>
                        <mixed-citation publication-type="journal">W. Yang, Y. Chen, D. Han and L. Zhu, “Synthesis and characterization of the fluorinated acrylic latex: Effect of fluorine-containing surfactant on properties of the latex film,” Journal of Fluorine Chemistry, vol. 149, pp. 8-12, 2013.</mixed-citation>
                    </ref>
                                    <ref id="ref31">
                        <label>31</label>
                        <mixed-citation publication-type="journal">N. Visaveliya, C. Hoffmann, A. Groß, E. Täuscher, U. Ritter and J. M. Koehler, “Micro-flow assisted synthesis of fluorescent polymer nanoparticles with tuned size and surface properties,” Nanotechnology Reviews, vol. 5(2), pp. 259-272, 2016.</mixed-citation>
                    </ref>
                            </ref-list>
                    </back>
    </article>
