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The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis

Year 2025, Volume: 29 Issue: 3, 250 - 257, 26.06.2025
https://doi.org/10.16984/saufenbilder.1603234

Abstract

This study investigated the phosphate phosphorus (PO4-P) removal potential of zinc oxysulfide (ZnOxSy) nanoparticles obtained by fifteen varying component ratios. The statistical meaning of the distinct synthesis compositions was evaluated by regression analysis based on the response of PO4-P removal efficiencies. The results indicated that ZnOxSy nanoparticles could remove PO4-P by 99.5% without optimization of the adsorption process (Initial PO4-P concentration: 15 mg/L, adsorbent dose: 1 g/L, pH: 4.31, contact time: 2 hr). However, the synthesis compositions of ZnOxSy nanoparticles strongly effect the PO4-P removal efficiency. The data could be interpreted by regression analysis with a high R2 of 89.61% and p value of 0.000. The main component that positively affect the PO4-P removal efficiency was hydrogen peroxide, whereas sodium sulfide component had a limited effect.

References

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  • Z. Li, R. S. Bowman, “Sorption of chromate and PCE by surfactant-modified clay minerals,” Environmental Engineering Science, vol. 15, no. 3, 1998.
  • U. Kafkafi, “Oxyanion Sorption on Soil Surfaces,” in Inorganic Contaminants in the Vadose Zone. Ecological Studies, vol. 74, B. Bar Yosef, N. J. Barrow, and J. Goldshmid, Eds., Springer, Berlin, Heidelberg, 1989.
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  • J. Suazo Hernández, P. Sepúlveda, L. Cáceres Jensen, J. Castro Rojas, P. Poblete Grant, N. Bolan, M. L. Mora, “nZVI-based nanomaterials used for phosphate removal from aquatic systems,” Nanomaterials, vol. 13, 2023.
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  • İ. Konuk Akça, R. Köklü, “Removal of paracetamol by powdered activated carbon synthesized from orange peels,” Sakarya University Journal of Science, vol. 27, no. 1, pp. 168–180, 2023.
  • F. Akti, “Effect of modifier agents on particle size and surface functional groups of calcined eggshell: Test in adsorption of remazol yellow,” Sakarya University Journal of Science, vol. 24, no. 1, pp. 272–280, 2020.
  • Y. Du, X. Wang, G. Nie, L. Xu, Y. Hu, “Enhanced phosphate removal by using La-Zr binary metal oxide nanoparticles confined in millimeter-sized anion exchanger,” Journal of Colloid and Interface Science, vol. 580, pp. 234–244, 2020.
  • Y. Wang, X. Xie, X. Chen, C. Huang, S. Yang, “Biochar-loaded Ce3+-enriched ultra-fine ceria nanoparticles for phosphate adsorption,” Journal of Hazardous Materials, vol. 396, p. 122626, 2020.
  • Y. Yu, L. Yu, K. Y. Koh, C. Wang, J. P. Chen, “Rare-earth metal based adsorbents for effective removal of arsenic from water: A critical review,” Critical Reviews in Environmental Science and Technology, vol. 48, no. 22–24, pp. 1127–1164, 2018.
  • I. Maamoun, R. Eljamal, O. Falyouna, K. Bensaida, Y. Sugihara, O. Eljamal, “Insights into kinetics, isotherms and thermodynamics of phosphorus sorption onto nanoscale zero-valent iron,” Journal of Molecular Liquids, vol. 328, 2021.
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  • W. Brontowiyono, I. Patra, S. A. Hussein, Alimuddin, A. B. Mahdi, S. E. Izzat, D. M. Al Dhalemi, A. K. O. Aldulaim, R. M. R. Parra, L. A. B. Arenas, Y. K. Mustafa, “Phosphate ion removal from synthetic and real wastewater using MnFe2O4 nanoparticles: A reusable adsorbent,” Acta Chimica Slovenica, vol. 69, pp. 681–693, 2022.
  • S. Rathod, S. Preetam, C. Pandey, S. P. Bera, “Exploring synthesis and applications of green nanoparticles and the role of nanotechnology in wastewater treatment,” Biotechnology Reports, vol. 41, p. e00830, 2024.
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  • P. Szczyglewska, A. Feliczak Guzik, I. Nowak, “Nanotechnology–general aspects: A chemical reduction approach to the synthesis of nanoparticles,” Molecules, vol. 28, p. 4932, 2023.
  • W. Nie, H. Cheng, Q. Sun, S. Liang, X. Lu, B. Lu, J. Zhou, “Design strategies toward high-performance Zn metal anode,” Small Methods, vol. 8, 2024.
  • A. Drenkova Tuhtan, M. Sihtmäe, K. Uke, H. Vija, M. Oppmann, J. Prieschl, K. Mandel, A. Kahru, “Synthesis and ecotoxicity screening of reusable, magnetically harvestable metal oxide/hydroxide nanocomposites for safe and sustainable removal and recovery of phosphorus from wastewater,” Journal of Cleaner Production, vol. 444, p. 141287, 2024.
  • M. Schneider, A. Drenkova Tuhtan, W. Szczerba, C. Gellermann, C. Meyer, H. Steinmetz, K. Mandel, G. Sextl, “Nanostructured ZnFeZr oxyhydroxide precipitate as efficient phosphate adsorber in waste water: understanding the role of different material-building-blocks,” Environmental Science: Nano, vol. 4, pp. 180–190, 2017.
  • H. Uppal, S. Chawla, A. G. Joshi, D. Haranath, N. Vijayan, N. Singh, “Facile chemical synthesis and novel application of zinc oxysulfide nanomaterial for instant and superior adsorption of arsenic from water,” Journal of Cleaner Production, vol. 208, pp. 458–469, 2019.
  • APHA, Standard Methods for the Examination of Water and Wastewater, 23rd ed. American Public Health Association (APHA), 2017.
  • H. Wang, X. Liang, Y. Liu, T. Li, K. Y. A. Lin, “Recycling spent iron-based disposable-chemical-warmer as adsorbent for As(V) removal from aqueous solution,” Resources, Conservation and Recycling, vol. 168, 2021.
  • S. Prasad, “Regression,” in Advanced Statistical Methods, Singapore: Springer Nature Singapore, 2024.
  • L. R. LaMotte, “A formula for Type III sums of squares,” Communications in Statistics- Theory and Methods, vol. 49, no. 13, pp. 3126–3136, 2020.
  • U. Knief, W. Forstmeier, “Violating the normality assumption may be the lesser of two evils,” Behavior Research Methods, vol. 53, pp. 2576–2590, 2021.
  • L. Jerome, “Multiple linear and non-linear regression in Minitab,” MSOR Connections, vol. 9, no. 3, 2009.
  • K. P. Burnham, D. R. Anderson, “Multimodel inference: Understanding AIC and BIC in model selection,” Sociological Methods and Research, vol. 33, no. 2, pp. 261–304, 2004.
Year 2025, Volume: 29 Issue: 3, 250 - 257, 26.06.2025
https://doi.org/10.16984/saufenbilder.1603234

Abstract

References

  • Y. Ren, W. Zheng, X. Duan, N. Goswami, Y. Liu, “Recent advances in electrochemical removal and recovery of phosphorus from water: A review,” Environmental Functional Materials, vol. 1, no. 1, pp. 10–20, 2022.
  • C. Korkmaz, G. D. Değermenci N. Değermenci, “Removal of phosphate from aqueous solution using anion exchange resin: Equilibrium, isotherms and kinetics,” Fibers and Polymers, vol. 24, pp. 3753–3760, 2023.
  • I. Haiduc, “Phosphorus–Nitrogen Compounds,” in Encyclopedia of Inorganic and Bioinorganic Chemistry, John Wiley & Sons, Ltd., 2006.
  • Z. Li, R. S. Bowman, “Sorption of chromate and PCE by surfactant-modified clay minerals,” Environmental Engineering Science, vol. 15, no. 3, 1998.
  • U. Kafkafi, “Oxyanion Sorption on Soil Surfaces,” in Inorganic Contaminants in the Vadose Zone. Ecological Studies, vol. 74, B. Bar Yosef, N. J. Barrow, and J. Goldshmid, Eds., Springer, Berlin, Heidelberg, 1989.
  • J. T. Bunce, E. Ndam, I. D. Ofiteru, A. Moore, D. W. Graham, “A review of phosphorus removal technologies and their applicability to small-scale domestic wastewater treatment systems,” Frontiers in Environmental Science, vol. 6, no. 8, 2018.
  • J. Suazo Hernández, P. Sepúlveda, L. Cáceres Jensen, J. Castro Rojas, P. Poblete Grant, N. Bolan, M. L. Mora, “nZVI-based nanomaterials used for phosphate removal from aquatic systems,” Nanomaterials, vol. 13, 2023.
  • C. Karaman, Z. Aksu, “Modelling of Remazol Black-B adsorption on chemically modified waste orange peel: pH shifting effect of acidic treatment,” Sakarya University Journal of Science, vol. 24, no. 5, pp. 1135–1150, 2020.
  • İ. Konuk Akça, R. Köklü, “Removal of paracetamol by powdered activated carbon synthesized from orange peels,” Sakarya University Journal of Science, vol. 27, no. 1, pp. 168–180, 2023.
  • F. Akti, “Effect of modifier agents on particle size and surface functional groups of calcined eggshell: Test in adsorption of remazol yellow,” Sakarya University Journal of Science, vol. 24, no. 1, pp. 272–280, 2020.
  • Y. Du, X. Wang, G. Nie, L. Xu, Y. Hu, “Enhanced phosphate removal by using La-Zr binary metal oxide nanoparticles confined in millimeter-sized anion exchanger,” Journal of Colloid and Interface Science, vol. 580, pp. 234–244, 2020.
  • Y. Wang, X. Xie, X. Chen, C. Huang, S. Yang, “Biochar-loaded Ce3+-enriched ultra-fine ceria nanoparticles for phosphate adsorption,” Journal of Hazardous Materials, vol. 396, p. 122626, 2020.
  • Y. Yu, L. Yu, K. Y. Koh, C. Wang, J. P. Chen, “Rare-earth metal based adsorbents for effective removal of arsenic from water: A critical review,” Critical Reviews in Environmental Science and Technology, vol. 48, no. 22–24, pp. 1127–1164, 2018.
  • I. Maamoun, R. Eljamal, O. Falyouna, K. Bensaida, Y. Sugihara, O. Eljamal, “Insights into kinetics, isotherms and thermodynamics of phosphorus sorption onto nanoscale zero-valent iron,” Journal of Molecular Liquids, vol. 328, 2021.
  • T. T. Nguyen, “Effective removal of phosphate from waste water based on silica nanoparticles,” Hindawi Journal of Chemistry, vol. 2022, 2022.
  • W. Brontowiyono, I. Patra, S. A. Hussein, Alimuddin, A. B. Mahdi, S. E. Izzat, D. M. Al Dhalemi, A. K. O. Aldulaim, R. M. R. Parra, L. A. B. Arenas, Y. K. Mustafa, “Phosphate ion removal from synthetic and real wastewater using MnFe2O4 nanoparticles: A reusable adsorbent,” Acta Chimica Slovenica, vol. 69, pp. 681–693, 2022.
  • S. Rathod, S. Preetam, C. Pandey, S. P. Bera, “Exploring synthesis and applications of green nanoparticles and the role of nanotechnology in wastewater treatment,” Biotechnology Reports, vol. 41, p. e00830, 2024.
  • C. Quintero Quiroz, N. Acevedo, J. Zapata Giraldo, L. E. Botero, J. Quintero, D. Zárate Trivinõ, J. Saldarriaga, V. Z. Pérez, “Optimization of silver nanoparticle synthesis by chemical reduction and evaluation of its antimicrobial and toxic activity,” Biomaterials Research, vol. 23, no. 27, 2019.
  • P. Szczyglewska, A. Feliczak Guzik, I. Nowak, “Nanotechnology–general aspects: A chemical reduction approach to the synthesis of nanoparticles,” Molecules, vol. 28, p. 4932, 2023.
  • W. Nie, H. Cheng, Q. Sun, S. Liang, X. Lu, B. Lu, J. Zhou, “Design strategies toward high-performance Zn metal anode,” Small Methods, vol. 8, 2024.
  • A. Drenkova Tuhtan, M. Sihtmäe, K. Uke, H. Vija, M. Oppmann, J. Prieschl, K. Mandel, A. Kahru, “Synthesis and ecotoxicity screening of reusable, magnetically harvestable metal oxide/hydroxide nanocomposites for safe and sustainable removal and recovery of phosphorus from wastewater,” Journal of Cleaner Production, vol. 444, p. 141287, 2024.
  • M. Schneider, A. Drenkova Tuhtan, W. Szczerba, C. Gellermann, C. Meyer, H. Steinmetz, K. Mandel, G. Sextl, “Nanostructured ZnFeZr oxyhydroxide precipitate as efficient phosphate adsorber in waste water: understanding the role of different material-building-blocks,” Environmental Science: Nano, vol. 4, pp. 180–190, 2017.
  • H. Uppal, S. Chawla, A. G. Joshi, D. Haranath, N. Vijayan, N. Singh, “Facile chemical synthesis and novel application of zinc oxysulfide nanomaterial for instant and superior adsorption of arsenic from water,” Journal of Cleaner Production, vol. 208, pp. 458–469, 2019.
  • APHA, Standard Methods for the Examination of Water and Wastewater, 23rd ed. American Public Health Association (APHA), 2017.
  • H. Wang, X. Liang, Y. Liu, T. Li, K. Y. A. Lin, “Recycling spent iron-based disposable-chemical-warmer as adsorbent for As(V) removal from aqueous solution,” Resources, Conservation and Recycling, vol. 168, 2021.
  • S. Prasad, “Regression,” in Advanced Statistical Methods, Singapore: Springer Nature Singapore, 2024.
  • L. R. LaMotte, “A formula for Type III sums of squares,” Communications in Statistics- Theory and Methods, vol. 49, no. 13, pp. 3126–3136, 2020.
  • U. Knief, W. Forstmeier, “Violating the normality assumption may be the lesser of two evils,” Behavior Research Methods, vol. 53, pp. 2576–2590, 2021.
  • L. Jerome, “Multiple linear and non-linear regression in Minitab,” MSOR Connections, vol. 9, no. 3, 2009.
  • K. P. Burnham, D. R. Anderson, “Multimodel inference: Understanding AIC and BIC in model selection,” Sociological Methods and Research, vol. 33, no. 2, pp. 261–304, 2004.
There are 30 citations in total.

Details

Primary Language English
Subjects Global Environmental Engineering
Journal Section Research Articles
Authors

Nilüfer Ülgüdür 0000-0003-3410-0598

Early Pub Date June 10, 2025
Publication Date June 26, 2025
Submission Date December 17, 2024
Acceptance Date May 8, 2025
Published in Issue Year 2025 Volume: 29 Issue: 3

Cite

APA Ülgüdür, N. (2025). The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis. Sakarya University Journal of Science, 29(3), 250-257. https://doi.org/10.16984/saufenbilder.1603234
AMA Ülgüdür N. The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis. SAUJS. June 2025;29(3):250-257. doi:10.16984/saufenbilder.1603234
Chicago Ülgüdür, Nilüfer. “The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis”. Sakarya University Journal of Science 29, no. 3 (June 2025): 250-57. https://doi.org/10.16984/saufenbilder.1603234.
EndNote Ülgüdür N (June 1, 2025) The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis. Sakarya University Journal of Science 29 3 250–257.
IEEE N. Ülgüdür, “The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis”, SAUJS, vol. 29, no. 3, pp. 250–257, 2025, doi: 10.16984/saufenbilder.1603234.
ISNAD Ülgüdür, Nilüfer. “The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis”. Sakarya University Journal of Science 29/3 (June 2025), 250-257. https://doi.org/10.16984/saufenbilder.1603234.
JAMA Ülgüdür N. The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis. SAUJS. 2025;29:250–257.
MLA Ülgüdür, Nilüfer. “The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis”. Sakarya University Journal of Science, vol. 29, no. 3, 2025, pp. 250-7, doi:10.16984/saufenbilder.1603234.
Vancouver Ülgüdür N. The Use of Synthesized Zinc Oxysulphide Nanoparticles in Phosphate Phosphorus Removal from Synthetic Wastewater and Statistical Analysis. SAUJS. 2025;29(3):250-7.


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