N2O2 Tipi Schiff Bazı Ligandı ile Sentezlenen Cu(II) Kompleksinin X-Işını Yapısı ve Termal Özelliği

Year 2013, Volume: 8 Issue: 2, 163 - 174, 16.04.2013

Ahmet Karahan Alper Yardan Yasemin Yahşi Hülya Kara Raif Kurtaran

Abstract

Cu(II) kompleksinin X-ışınları moleküler yapısı 293 K'de tayin edildi. Cu (II) kompleksi monoklinik yapıda ve uzay grubu P21/n a= 12.4007(14), b= 8.4476(9), c= 20.0286(12) Ã…, β= 97.291(7)°. Termal davranışları diferansiyel termal analiz ve termogravimetrik analiz ile incelendi. Ayrıca Schiff bazı ligandının karakterizasyonunda elementel analiz, IR, UV-vis spektroskopisi, termal analiz, 1H-NMR ve 13C-NMR yöntemlerinden faydalanıldı.

Anahtar kelimeler: Schiff bazı, Tek Kristal, X-ışınları analizi, Termal analiz

The X-Ray Molecular Structure and Thermal Behaviour of Cu (II) Complex, Synthesis With N2O2 Type Schiff Base Ligand

Abstract: The X-ray molecular structure of Cu (II) complex at 293 K has been determined. The Cu (II) complex, has been prepared and structurally and thermal characterized. The complex crystallizes in monoclinic space group P21/n with a= 12.407(14), b= 8.4476(9), c= 20.0286(12) Ã…, β= 97.291(7)°. The thermal behavior of the compound was investigated by differential thermal analysis and thermogravimetry. Additionally, Schiff base ligand also characterized by elemental analysis, IR, UV-vis spectroscopy, thermal analysis, 1H-NMR and 13C-NMR.

Key words: Schiff base, Single crystal, X-ray analysis, Thermal analysis

Keywords

Schiff bazı, Tek Kristal, X-ışınları analizi, Termal analiz

References

• Abbo H.S., Titinchi S.J.J., Prasad R., Chand S., 2005. Synthesis, characterization and study of polymeric iron(III) complexes with bidentate p-hydroxy Schiff bases as heterogeneous catalysts, Journal Molecular Catalys A: Chemistry, 225, 225-232.
• Reddy K.H., Lingappa Y., 1994. Synthesis and characterization of copper (II) complexes of physiologically active tridentate Schifd bases, Indian Journal of Chemistry Section A, 33, 919- 923.
• Kuduk J., Trynda L. 1994. Impact of KPtClon the structure of human serum albumın and its binding 2 6 ability of heme and bilirubin, Journal of Inorgic Biochemistry, 53 (4): 249-260.
• Salman S.R., Farrant, R.D., Lindon, J.C., 1991. Studies of tautomerism in 2-hydroxy naphtaldehyde Schiff bases by multinuclear magnetic resonance, Spectroscopy Letters, 24 (9): 1071-1078.
• Gaber M., Issaf R.M., Aly A., Ayad M.I., 1989. Studies of Ti(IV) and Zr(IV) chelates with NO; 22 schiff bases of 2-hydroxy-1-naphthaldehyde with aromatic diamines, Thermochimica Acta, 155, 309-316.
• Thangadurai T.D., Gowr, M., Natarajan K. 2002. Synthesıs and Characterısatıon of Ruthenıum(III) Complexes Contaınıng Monobasıc Bıdentate Schiff Bases and Their Bıologıcal Actıvıtıes, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 32, 329-343.
• Ramesh R., Sivagamasundari M. 2003. Synthesis, Spectral and Antifungal Activity of Ru(II) Mixed-­‐Ligand Complexes, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano- Metal Chemistry, 33, 899-910.
• Soliman A.A., Linert W., 1999. Investigations on new transition metal chelates of the 3-methoxy- salicylidene-2-aminothiophenol Schiff base, Thermochimica. Acta, 338, 67–75.
• Soliman A.A., 2001.Thermogravimetric and Spectroscopic Studies on Cadmium Complexes With Two Salicylidene Thiophenol Schiff Bases, Journal of Thermal Analysis and Calorimetry, 63, 221–231.
• Garg B.S., Kumar D.N., 2003. Spectral studies of complexes of nickel(II) with tetradentate schiff bases having N2O2 donor groups, Spectrochimica Acta Part A, 59, 229–234.
• Anthonysamy A., Balasubramanian S., 2005. Synthesis, spectral, thermal and electrochemical studies of nickel (II) complexes with N2O2 donor ligands, Inorganic Chemistry Communications, 8, 908–911.
• Durmuş S., 2001. Heterotrinükleer geçiş metalleri komplekslerinin hazırlanması ve yapılarının incelenmesi, Doktora Tezi, Fen Bilimleri Enstitüsü, Ankara Üniversitesi, Ankara, 139 sayfa.
• Zhang Q., Zhu B., Lindoy L., Wei G., 2008. Dinuclear nickel(II) complex of a N2O3-donor Schiff base derived from acetylacetone and 1,3-diamino-2-hydroxypropane, Inorganic Chemistry Communications, 11, 678-680.
• Balcı M., 2004. Nükleer Manyetik Rezonans Spektroskopisi, ODTÜ Yayıncılık, Türkiye, 452 sayfa.
• Djebar-Sid S., Benali-Baitich O., Deloume J.P., 2001. Synthesis, characterization and electrochemical behaviour of cobalt(II) and cobalt(III):O2− complexes, respectively, with linear and tripodal tetradentate ligands derived from Schiff bases, Journal of Molecular. Structure, 569, 121-128.
• Alper Yardan e-posta: [e-mail]
• Yasemin Yahşi e-posta: [e-mail]
• Hülya Kara e-posta: [e-mail]
• Raif Kurtaran e-posta: [e-mail]