Year 2020, Volume 15 , Issue 1, Pages 63 - 72 2020-05-31

Trisübstitüe Hetarilazo İndol Boyalarının Sentezi ve Absorpsiyon Özelliklerinin İncelenmesi
Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes

Mehmet ULUTÜRK [1] , Tahir TİLKİ [2]


Bu çalışmada, çeşitli aromatik aminler ile hazırlanan diazonyum tuzlarının, 2-(4-metilfenil)-1H-indol ve 2-(4-klorfenil)-1H-indol bileşikleri ile azo kenetlenmesi sonucu, bir dizi yeni hetarilazo indol boyası sentezlendi. Hazırlanan boyarmaddelerin, Mitsunobu reaksiyonu ile N-pozisyonundan izopropil alkol ile alkillenmesi sonucu N-sübstitue indol türevlerinin sentezi gerçekleştirildi. Sentezlenen bileşiklerin kimyasal yapıları, NMR, FT-IR, UV-vis, kütle spektrometresi ve elementel analiz ile aydınlatıldı. Elde edilen boyarmaddelerin fotofiziksel özelliklerini belirlemek için, farklı polariteye sahip çözücüler içerisinde görünür bölge absorpsiyon spektrumları incelendi. Ek olarak, asit ve baz ilavesinin absorpsiyon maksimumları üzerine etkileri ayrıntılı olarak incelendi.

In this study, as a result of azo coupling of diazonium salts prepared with various aromatic amines with 2-(4-methylphenyl)-1H-indole and 2-(4-chlorophenyl)-1H-indole compounds, a series of new hetarylazo indole dyes were synthesized. N-substituted indole derivatives were synthesized by alkylation of the prepared dyes with the isopropyl alcohol from the N-position by Mitsunobu reaction. The chemical structures of the synthesized compounds were determined by NMR, FT-IR, UV-vis, mass spectrometry and elemental analysis. In order to determine the photophysical properties of the dyes obtained, visible region absorption spectra were examined in solvents of different polarity. In addition, the behavior of acid and base addition on absorption maxima were examined in detail.
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Primary Language en
Subjects Engineering, Chemical
Journal Section Makaleler
Authors

Orcid: 0000-0003-3931-5328
Author: Mehmet ULUTÜRK (Primary Author)
Institution: SULEYMAN DEMIREL UNIVERSITY, FACULTY OF SCIENCE AND LETTERS, DEPARTMENT OF CHEMISTRY
Country: Turkey


Orcid: 0000-0002-1040-2375
Author: Tahir TİLKİ
Institution: SULEYMAN DEMIREL UNIVERSITY, FACULTY OF SCIENCE AND LETTERS, DEPARTMENT OF CHEMISTRY
Country: Turkey


Supporting Institution SDU-BAP
Project Number 3497-D1-13
Thanks The authors are grateful to SDU-BAP (Project No: 3497-D1-13) for their financial support.
Dates

Publication Date : May 31, 2020

Bibtex @research article { sdufeffd649535, journal = {Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi}, issn = {}, eissn = {1306-7575}, address = {}, publisher = {Süleyman Demirel University}, year = {2020}, volume = {15}, pages = {63 - 72}, doi = {10.29233/sdufeffd.649535}, title = {Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes}, key = {cite}, author = {Ulutürk, Mehmet and Ti̇lki̇, Tahir} }
APA Ulutürk, M , Ti̇lki̇, T . (2020). Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes . Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi , 15 (1) , 63-72 . DOI: 10.29233/sdufeffd.649535
MLA Ulutürk, M , Ti̇lki̇, T . "Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes" . Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 15 (2020 ): 63-72 <https://dergipark.org.tr/en/pub/sdufeffd/issue/54573/649535>
Chicago Ulutürk, M , Ti̇lki̇, T . "Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 15 (2020 ): 63-72
RIS TY - JOUR T1 - Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes AU - Mehmet Ulutürk , Tahir Ti̇lki̇ Y1 - 2020 PY - 2020 N1 - doi: 10.29233/sdufeffd.649535 DO - 10.29233/sdufeffd.649535 T2 - Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi JF - Journal JO - JOR SP - 63 EP - 72 VL - 15 IS - 1 SN - -1306-7575 M3 - doi: 10.29233/sdufeffd.649535 UR - https://doi.org/10.29233/sdufeffd.649535 Y2 - 2020 ER -
EndNote %0 Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes %A Mehmet Ulutürk , Tahir Ti̇lki̇ %T Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes %D 2020 %J Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi %P -1306-7575 %V 15 %N 1 %R doi: 10.29233/sdufeffd.649535 %U 10.29233/sdufeffd.649535
ISNAD Ulutürk, Mehmet , Ti̇lki̇, Tahir . "Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 15 / 1 (May 2020): 63-72 . https://doi.org/10.29233/sdufeffd.649535
AMA Ulutürk M , Ti̇lki̇ T . Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes. SDÜFEFFD. 2020; 15(1): 63-72.
Vancouver Ulutürk M , Ti̇lki̇ T . Synthesis and Absorption Properties of Trisubstituted Hetarylazo Indole Dyes. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi. 2020; 15(1): 63-72.