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Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması

Year 2010, Volume: 14 Issue: 1, 95 - 103, 27.02.2014

Şule Uğur Merih Sarıışık Ahmet Aktaş

Abstract

Çok tabakalı kaplama yöntemi ile katyonik dokuma pamuklu kumaşların yüzeyinde ZnO nanopartikül içeren çok tabakalı nanokompozit filmler oluşturulmuştur. Katyonik yüzey yükü oluşturabilmek için pamuklu kumaşlar, 2,3- epoksipropiltrimetilamonyum klorür (EP3MAC) ile emdirme-bekletme (pad-batch) yöntemi kullanılarak muamele edilmiştir. Nano PU/ZnO, PSS/ZnO ve ZnO/PDDA nanokompozit 10 ve 16 tabakalı filmler pamuk lifleri üzerinde çok tabakalı kaplama yöntemi ile oluşturulmuştur. Çok tabakalı filmlerin varlığını kanıtlamak amacıyla FTIR-ATR ve SEM analizleri yapılmıştır. Çok tabakalı kaplama yöntemi ile elde edilen bütün çok tabakalı film kaplanan pamuklu kumaşlar Staphylococcus aureus bakterisine karşı iyi derecede antibakteriyel etki göstermiştir. Ayrıca çok tabakalı kaplama yönteminin pamuklu kumaşa etkisini belirlemek amacıyla, ZnO nanopartikül, Nano PU, PSS ve PDDA içeren filmlerin kaplama önce ve sonrasında hava geçirgenliği ve beyazlık dereceleri tespit edilmiştir. Pamuklu kumaşlarda kendiliğinden düzenlenen çok tabakalı filmlerin antibakteriyel aktivite özelliklerinin devamlılığı 10 ve 20 yıkama işleminden sonra tekrar test edilmiştir. Anahtar Kelimeler: Çok Tabakalı Kaplama Yöntemi, Katyonizasyon, ZnO Nanopartikül, Antibakteriyel Etki

Keywords

Çok Tabakalı Kaplama Yöntemi Katyonizasyon ZnO Nanopartikül Antibakteriyel Etki

References

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  • Chunder, A., Sarkar, S., Yu, Y., Zhai, L. 2007. Fabrication of Ultrathin Polyelectrolyte Fibers and Their Controlled Release Properties. Colloids and Surfaces B: Biointerfaces, 58, 172-179. Decher, G. 1997.
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  • Dubas, S.T., Limsavarn, L., Iamsamai, C., Potiyaraj, P. 2006. Assembly of Polyelectrolyte Multilayers on Nylon Fibers. Journal of Applied Polymer Science, 101, 3286-3290.
  • Dubas, S.T., Chutchawalkulchai, E., Egkasit, S., Iamsamai, C., Potiyaraj, P. 2007. Deposition of Polyelectrolyte Multilayers to Improve the Color Fastness of Silk. Textile Research Journal, 77, 437-441.
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  • Kim, S.H., Shin, C-J., Keum, S-R., Koh, K. 2007. Layer- by-Layer Self-Assembled Multilayer of Cationic Spiroxazine and Polystyrenesulfonate. Dyes and Pigments, 72, 378-382.
  • Lee, D., Rubner, M.F., Cohen, R.E. 2006. All- Nanoparticle Thin-Film Coatings. Nano Letters, 6, 2305-2312.
  • Lee, D., Omolade, D., Cohen, R.E., Rubner, M.F. 2007. pH-Dependent TiO2/SiO2 Nanoparticle Multilayer Thin Films. Chem. Mater, 19, 1427-1433. Properties of
  • Li, J.H., Hong, R.Y., Li, M.Y., Zi, H.Z., Zheng, Y., Ding, J. 2009. Effects of ZnO Nanoparticles on the Mechanical and Antibacterial Properties of Polyurethane Coatings. Organic Coatings, 64, 504- 509.
  • Liu, X., Wang, J., Zhang, J., Liu, B., Zhou, J., Yang, S. 2007. Fabrication Ag/Polymer Layer-by-Layer Self-Assembly Technique. Thin Solid Films, 515, 7870-7875. Films Nanocomposite Through
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  • Polowinski, S. 2007. Deposition of Polymer Complex Layers onto Nonwoven Textiles. Journal of Applied Polymer Science, 103, 1700-1705.
  • Takenaka, S., Maehara, Y., Imai, H., Yoshikawa, M., Shiratori, S. 2003. Layer-by-Layer Self-Assembly Replication Photoelectrode of Dye-Sensitized Solar Cell. Thin Solid Films, 438 –439, 346-351. to
  • Uğur, Ş.S., Sarıışık, M., Aktaş, H. 2009. Layer-by-Layer Deposition of ZnO Nanoparticles on Cotton Fabrics. International Symposium on Engineering And Architectural Sciences of Balkan, Caucasus and Turkic Republics, 22-24 Ekim, Isparta, Proceedings Volume II, 259-265.
  • Vigneshwaran, N., Kumar, S., Kathe, A.A., Varadarajan, P.V., Prasad, V. 2006. Functional Finishing of Cotton Fabrics Using Zinc Oxide–Soluble Starch Nanocomposites. Nanotechnology, 17, 5087-5095.
  • Ying, K.L., Hsieh, T.E., Hsieh, Y.F. 2009. Colloidal Dispersion of Nano-Scale ZnO Powders Using Amphibious Ceramics International, 35, 1165-1171. Polyelectrolytes.
  • Zohdy, M.H., Karem, H.A., El-Naggar, A.M., Hassan, M.S. Morphology, and Thermal Stability of Cotton and Cotton/Polyester Antimicrobial Formulations by a Radiation Method. Journal of Applied Polymer Science, 89, 2604-2610. Detection, Surface Fabrics Treated with

Year 2010, Volume: 14 Issue: 1, 95 - 103, 27.02.2014

Şule Uğur Merih Sarıışık Ahmet Aktaş

Abstract

References

  • Bertrand, P., Jonas, A., Laschewsky, A., Legras, R. 2000. Ultrathin Polymer Coatings by Complexation of Polyelectrolytes at Interfaces: Suitable Materials, Structure and Properties. Macromolecular Rapid Communications, 21, 319-348.
  • Cant, N.E., Zhang, H., Critchley, K., Mykhalyk, T.A., Davies, G.R., Evans, S.D. 2003. Fabrication and Characterization Nanoparticle/Polyelectrolyte Multilayer Films. J. Phys. Chem. B., 107, 13557-13562.
  • Chunder, A., Sarkar, S., Yu, Y., Zhai, L. 2007. Fabrication of Ultrathin Polyelectrolyte Fibers and Their Controlled Release Properties. Colloids and Surfaces B: Biointerfaces, 58, 172-179. Decher, G. 1997.
  • Multicomposites Fuzzy
  • Nanoassemblies: Toward Layered Polymeric.
  • Science, 277, 1232-1237.
  • Ding, B., Kim, J., Kimura, E., Shiratori, S. 2004. Layer- by-Layer Structured Films of TiO2 Nanoparticles and Poly(acrylic acid) on Electrospun Nanofibres. Nanotechnology, 15, 913-917.
  • Dubas, S.T., Limsavarn, L., Iamsamai, C., Potiyaraj, P. 2006. Assembly of Polyelectrolyte Multilayers on Nylon Fibers. Journal of Applied Polymer Science, 101, 3286-3290.
  • Dubas, S.T., Chutchawalkulchai, E., Egkasit, S., Iamsamai, C., Potiyaraj, P. 2007. Deposition of Polyelectrolyte Multilayers to Improve the Color Fastness of Silk. Textile Research Journal, 77, 437-441.
  • Hauser, P.J., Tabba, A.H. 2001. Improving the Environmental and Economic Aspects of Cotton Dyeing Using a Cationised Cotton. Coloration Technology, 117, 282-288.
  • Hyde, K., Rusa, M., Hinestroza, J. 2005. Layer-by-Layer Deposition of Polyelectrolyte Nanolayers on Natural Fibres: Cotton. Institute of Physics Publishing, Nanotechnology, 16, 422-428.
  • Jantas, R., Polowinski, S. 2007. Modifying of Polyester Fabric Surface with Polyelectrolyte Nanolayers Using the Layer-by-Layer Deposition Technique. Fibres & Textiles in Eastern Europe, 15-61, 97-99.
  • Kathirvelu, S., D’Souza, L., Dhurai, B. 2009. A Study on Functional Finishing of Cotton Fabrics Using Nano-particles of Zinc Oxide. Materials Science, 15, 75-79.
  • Kim, S.H., Shin, C-J., Keum, S-R., Koh, K. 2007. Layer- by-Layer Self-Assembled Multilayer of Cationic Spiroxazine and Polystyrenesulfonate. Dyes and Pigments, 72, 378-382.
  • Lee, D., Rubner, M.F., Cohen, R.E. 2006. All- Nanoparticle Thin-Film Coatings. Nano Letters, 6, 2305-2312.
  • Lee, D., Omolade, D., Cohen, R.E., Rubner, M.F. 2007. pH-Dependent TiO2/SiO2 Nanoparticle Multilayer Thin Films. Chem. Mater, 19, 1427-1433. Properties of
  • Li, J.H., Hong, R.Y., Li, M.Y., Zi, H.Z., Zheng, Y., Ding, J. 2009. Effects of ZnO Nanoparticles on the Mechanical and Antibacterial Properties of Polyurethane Coatings. Organic Coatings, 64, 504- 509.
  • Liu, X., Wang, J., Zhang, J., Liu, B., Zhou, J., Yang, S. 2007. Fabrication Ag/Polymer Layer-by-Layer Self-Assembly Technique. Thin Solid Films, 515, 7870-7875. Films Nanocomposite Through
  • Nanofabrication via Layer-by-Layer
  • Ma, M., Hill, R.M. 2006. Superhydrophobic Surfaces. Current Opinion in Colloid & Interface Science, 11, 193-202.
  • Ou, R., Zhang, J., Deng, Y., Ragauskas, A.J. 2007. Polymer Clay Self-Assembly Complexes on Paper. Journal of Applied Polymer Science, 102, 1987- 1992.
  • Perelshtein, I., Applerot, G., Perkas, N., Wehrschetz-Sigl, E., Hasmann, A., Guebitz, G.M., Gedanken, A. 2009. Antibacterial Properties of an In Situ Generated Nanocrystalline ZnO on Fabrics. ACS Applied Materials & Interfaces, 1, 361-366. Deposited
  • Polowinski, S. 2007. Deposition of Polymer Complex Layers onto Nonwoven Textiles. Journal of Applied Polymer Science, 103, 1700-1705.
  • Takenaka, S., Maehara, Y., Imai, H., Yoshikawa, M., Shiratori, S. 2003. Layer-by-Layer Self-Assembly Replication Photoelectrode of Dye-Sensitized Solar Cell. Thin Solid Films, 438 –439, 346-351. to
  • Uğur, Ş.S., Sarıışık, M., Aktaş, H. 2009. Layer-by-Layer Deposition of ZnO Nanoparticles on Cotton Fabrics. International Symposium on Engineering And Architectural Sciences of Balkan, Caucasus and Turkic Republics, 22-24 Ekim, Isparta, Proceedings Volume II, 259-265.
  • Vigneshwaran, N., Kumar, S., Kathe, A.A., Varadarajan, P.V., Prasad, V. 2006. Functional Finishing of Cotton Fabrics Using Zinc Oxide–Soluble Starch Nanocomposites. Nanotechnology, 17, 5087-5095.
  • Ying, K.L., Hsieh, T.E., Hsieh, Y.F. 2009. Colloidal Dispersion of Nano-Scale ZnO Powders Using Amphibious Ceramics International, 35, 1165-1171. Polyelectrolytes.
  • Zohdy, M.H., Karem, H.A., El-Naggar, A.M., Hassan, M.S. Morphology, and Thermal Stability of Cotton and Cotton/Polyester Antimicrobial Formulations by a Radiation Method. Journal of Applied Polymer Science, 89, 2604-2610. Detection, Surface Fabrics Treated with
There are 28 citations in total.

Details

Primary Language English
Journal Section MÜHENDİSLİK ve MİMARLIK BİLİMLERİ
Authors

Şule Uğur This is me

Merih Sarıışık This is me

Ahmet Aktaş This is me

Publication Date February 27, 2014
Published in Issue Year 2010 Volume: 14 Issue: 1

Cite

APA Uğur, Ş., Sarıışık, M., & Aktaş, A. (2014). Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 14(1), 95-103. https://doi.org/10.19113/sdufbed.53640
AMA Uğur Ş, Sarıışık M, Aktaş A. Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması. J. Nat. Appl. Sci. February 2014;14(1):95-103. doi:10.19113/sdufbed.53640
Chicago Uğur, Şule, Merih Sarıışık, and Ahmet Aktaş. “Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14, no. 1 (February 2014): 95-103. https://doi.org/10.19113/sdufbed.53640.
EndNote Uğur Ş, Sarıışık M, Aktaş A (February 1, 2014) Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14 1 95–103.
IEEE Ş. Uğur, M. Sarıışık, and A. Aktaş, “Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması”, J. Nat. Appl. Sci., vol. 14, no. 1, pp. 95–103, 2014, doi: 10.19113/sdufbed.53640.
ISNAD Uğur, Şule et al. “Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14/1 (February 2014), 95-103. https://doi.org/10.19113/sdufbed.53640.
JAMA Uğur Ş, Sarıışık M, Aktaş A. Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması. J. Nat. Appl. Sci. 2014;14:95–103.
MLA Uğur, Şule et al. “Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 14, no. 1, 2014, pp. 95-103, doi:10.19113/sdufbed.53640.
Vancouver Uğur Ş, Sarıışık M, Aktaş A. Pamuklu Kumaşlarda Antibakteriyel Amaçlı ZnO Nanopartikül İçeren İnce Filmlerin Oluşturulması. J. Nat. Appl. Sci. 2014;14(1):95-103.

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