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Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4

Year 2013, Volume: 17 Issue: 3, 42 - 45, 11.07.2014

İsrafil Şabikoğlu

Abstract

In the family of borate and phosphate, orthoborate lutetium (LuBO3), and lanthanum gadolinium phosphate (LaGdPO4) materials are the new generation materials in optoelectronic devices due to their superior luminescence properties. Some physical and chemical differences occur in nanostructures synthesized by hydrothermal method according to micro-sized structure. Optical properties of nano-sized structures can be changed owing to different doping with rare earth element in to the host material. The hydrothermal synthesis method is a type of synthesis that allowing the production of nano-sized single crystal in high purity under low temperature and high pressure. In this study, radiolumnescence and XRD properties of LuBO3:REE and La,GdPO4: REE (REE: Eu, Tb) materials are investigated. It is observed that typical electronic transition for Eu and Tb

Keywords

Radioluminescence LuBO3 LaGdPO4 XRD HydrothermalSynthesis

References

  • Balcerzyk M, Gontarz Z, Moszynski M, Kapusta M (2000) Future hosts for fast and high light output cerium doped scintillator, J. Lumin., 87–89, 963–966. Bessie`re A, Benhamou RA, Wallez G, Lecointre A, Viana B (2012) Site occupancy and mechanisms of thermally stimulated luminescence in Ca9Ln(PO4)7, ActaMaterialia 60, 6641–6649.
  • Dwivedi Y and Zilio SC (2013) Infrared cascade and cooperative multicolor upconversion emissions in YV2O:Eu:Yb nanophosphors, Optic Express 21-4, 4717.
  • John B. Gruber et.al (2011) Spectroscopic analysis of Eu3+ in single-crystal hexagonal phase AlN J. Applied Physics 110, 023104.
  • Kim KN, Jung HK, Park HD (2002) Synthesis and characterization of red phosphor (Y,Gd)BO3:Eu by the coprecipitation method, J. Mater. Res., 17, 907.
  • Li ZH, Zeng JH, Chen C, Li YD (2006) Synthesis and characterization of red phosphor (Y,Gd)BO3:Eu by the coprecipitation method, J. Cryst. Growth, 286, 487.
  • Şabikoğlu İ (2011) Katkılandırılmış Lityum Silikat camsı seramiklerin sentezlenmesi ve lüminesans özelliklerinin incelenmesi, Doctorate Thesis, Celal Bayar University, Institute of Science 178p.
  • Taikar DR, Joshi CP, Moharil SV, Muthal PL, Dhopte SM (2012) Synthesis and luminescence of La2BaZnO5 phosphors J.of Lumin 11022.
  • Wu C, Wang Y (2007) Hydrothermal synthesis and luminescent properties of (La,Gd)PO4:Tb phosphors under VUV excitation, Materials Letters 61, 2416– 2418.
  • Wu X et.al (2002) Vacuum ultraviolet optical properties of (La,Gd)PO4:RE3+ (RE=Eu, Tb), Mater.Res.Bull. 37, 1531-1538.
  • Yang J, Zhang C, Wang L, Hou Z, Huang S, Lian H, Lin J (2008) Hydrothermal synthesis and luminescent properties of LuBO3: Tb3+microflowers, J.SolidSt.Che., 181, 2672.
  • Zhang L et.al. (1999) Fast fluorescence and scintillation properties of cerium and praseodymium doped lutetium orthoborates, Radiat. Eff. Defects Solids, 150, 47.

Eu veTb Katkılandırılmış LuBO3 ve LaGdPO4 'ın Radyolüminesans Özelliklerinin Araştırılması

Year 2013, Volume: 17 Issue: 3, 42 - 45, 11.07.2014

İsrafil Şabikoğlu

Abstract

Lütesyum ortoborat (LuBO3) ve lantan, gadolinyum fosfat (LaGdPO4) malzemeleri, borat ve fosfat bileşikleri arasından, sergiledikleri üstün lüminesans özelliklerinden dolayı, optoelektronik cihazlarda kullanılabilecek yeni nesil ev sahibi malzemelerdir. Hidrotermal yöntem ile sentezlenen nano yapılarda, mikro boyuta göre, fiziksel ve kimyasal farklılıklar meydana gelmektedir. Farklı nadir toprak elementleri ile katkılandırılarak yapılan nano yapıların optik özellikleri de değiştirilebilmektedir. Hidrotermal sentez yöntemi, düşük sıcaklık ve yüksek basınç altında, yüksek saflıkta ve nano boyutlarda tek kristal üretimini sağlayan bir sentezleme türüdür. Bu çalışmada, LuBO3:NTE ve La,GdPO4: NTE (NTE:Eu, Tb) örneklerinin X-ışını kırınımı (XRD) ve radyolüminesans (RL) özellikleri incelenmiştir. Eu ve Tb için tipik elektronik geçişleri gözlenmiştir.

Keywords

Radyolüminesans LuBO3 LaGdPO4 XRD Hidrotermal sentez

References

  • Balcerzyk M, Gontarz Z, Moszynski M, Kapusta M (2000) Future hosts for fast and high light output cerium doped scintillator, J. Lumin., 87–89, 963–966. Bessie`re A, Benhamou RA, Wallez G, Lecointre A, Viana B (2012) Site occupancy and mechanisms of thermally stimulated luminescence in Ca9Ln(PO4)7, ActaMaterialia 60, 6641–6649.
  • Dwivedi Y and Zilio SC (2013) Infrared cascade and cooperative multicolor upconversion emissions in YV2O:Eu:Yb nanophosphors, Optic Express 21-4, 4717.
  • John B. Gruber et.al (2011) Spectroscopic analysis of Eu3+ in single-crystal hexagonal phase AlN J. Applied Physics 110, 023104.
  • Kim KN, Jung HK, Park HD (2002) Synthesis and characterization of red phosphor (Y,Gd)BO3:Eu by the coprecipitation method, J. Mater. Res., 17, 907.
  • Li ZH, Zeng JH, Chen C, Li YD (2006) Synthesis and characterization of red phosphor (Y,Gd)BO3:Eu by the coprecipitation method, J. Cryst. Growth, 286, 487.
  • Şabikoğlu İ (2011) Katkılandırılmış Lityum Silikat camsı seramiklerin sentezlenmesi ve lüminesans özelliklerinin incelenmesi, Doctorate Thesis, Celal Bayar University, Institute of Science 178p.
  • Taikar DR, Joshi CP, Moharil SV, Muthal PL, Dhopte SM (2012) Synthesis and luminescence of La2BaZnO5 phosphors J.of Lumin 11022.
  • Wu C, Wang Y (2007) Hydrothermal synthesis and luminescent properties of (La,Gd)PO4:Tb phosphors under VUV excitation, Materials Letters 61, 2416– 2418.
  • Wu X et.al (2002) Vacuum ultraviolet optical properties of (La,Gd)PO4:RE3+ (RE=Eu, Tb), Mater.Res.Bull. 37, 1531-1538.
  • Yang J, Zhang C, Wang L, Hou Z, Huang S, Lian H, Lin J (2008) Hydrothermal synthesis and luminescent properties of LuBO3: Tb3+microflowers, J.SolidSt.Che., 181, 2672.
  • Zhang L et.al. (1999) Fast fluorescence and scintillation properties of cerium and praseodymium doped lutetium orthoborates, Radiat. Eff. Defects Solids, 150, 47.
There are 11 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Özel Sayı
Authors

İsrafil Şabikoğlu This is me

Publication Date July 11, 2014
Published in Issue Year 2013 Volume: 17 Issue: 3

Cite

APA Şabikoğlu, İ. (2014). Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 17(3), 42-45.
AMA Şabikoğlu İ. Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4. SDÜ Fen Bil Enst Der. March 2014;17(3):42-45.
Chicago Şabikoğlu, İsrafil. “Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 17, no. 3 (March 2014): 42-45.
EndNote Şabikoğlu İ (March 1, 2014) Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 17 3 42–45.
IEEE İ. Şabikoğlu, “Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4”, SDÜ Fen Bil Enst Der, vol. 17, no. 3, pp. 42–45, 2014.
ISNAD Şabikoğlu, İsrafil. “Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 17/3 (March 2014), 42-45.
JAMA Şabikoğlu İ. Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4. SDÜ Fen Bil Enst Der. 2014;17:42–45.
MLA Şabikoğlu, İsrafil. “Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 17, no. 3, 2014, pp. 42-45.
Vancouver Şabikoğlu İ. Investigation of Radioluminescence Properties of Eu and Tb Doped LuBO3 and LaGdPO4. SDÜ Fen Bil Enst Der. 2014;17(3):42-5.

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