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THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE

Year 2023, Volume: 2 Issue: 36, 1 - 12, 31.12.2023
https://doi.org/10.47118/somatbd.1403544

Abstract

Clay is mainly composed of illite, kaolinite, montmorillonite groups. Although it is abundant in nature, it is very difficult to find pure clay. The substances that make up clay are hydrous aluminum silicates. Each clay group contains different metal oxides or organic compounds. These impurities contained in minerals constitute an interesting field in luminescence and optical studies.
Although there are many studies on clay minerals, each sample shows its own unique characteristics. In this study, clay samples taken from Edirne-Keşan-Erikli Beach, located on the coast of Saros Gulf, were studied. Its crystallographic structure was determined by XRD analysis, its rheological properties and the elements it contained were determined by SEM-EDX analysis, and its structural properties were examined by FT-IR analysis. In optical absorption analysis, strong absorption bands were observed in the UV and Vis regions. In radioluminescence (RL) analysis, the emission spectrum formed by X-ray excitation are discussed. Likewise, in the thermoluminescence (TL) analysis using X-ray as primary excitation, peaks were observed in shallow and deep traps.

References

  • [1] Sam Boggs, S.B.J., Principles Of Sedimentology And Stratigraphy, Pearson Prentice Hall.
  • [2] Division, C., et al., Nanoclays For Polymer Nanocomposites , Paints , Inks , Greases And Cosmetics Formulations , Drug Delivery Vehicle And Waste Water Treatment, 29 (2006), 2, pp. 133-145
  • [3] Faïza Bergaya, B. K. G. Theng, G.L., Handbook Of Clay Science, Elsevier Ltd, 2006
  • [4] Dubey, V., et al., Thermoluminescence Study, Including The Effect Of Heating Rate, And Chemical Characterization Of Amarnath Stone Collected From Amarnath Holy Cave, Res. Chem. Intermed., 40 (2014), 2, pp. 531-536
  • [5] Yüksel, M., et al., Thermoluminescence Properties Of Annealed Natural Quartz After Beta Irradiation, Luminescence, 31 (2016), 8, pp. 1513-1518
  • [6] Jose, M.T., et al., Determination Of Thermoluminescence Kinetic Parameters Of Thulium Doped Lithium Calcium Borate, Radiat. Meas., 46 (2011), 10, pp. 1026-1032
  • [7] da Silva, R.S., et al., Thermoluminescence Kinetic Parameters Of Bi4Ge3O12 Single Crystals, Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. with Mater. Atoms, 250 (2006), 1-2, pp. 390-395
  • [8] Arslanlar Tuncer Y., Kibar R., Çetin A., Canımoğlu A., A.T.Y., Radioluminescence Properties Of Copper- And Terbium-Implanted Strontium Titanate Radioluminescence Properties Of Copper- And Terbium-Implanted Strontium Titanate, Lett. Spectrosc., (2013), July, pp. 364-366
  • [9] Rodríguez-Lazcano, Y., et al., Thermo- And Cathodoluminescence Properties Of Lepidolite, Spectrochim. Acta Part A Mol. Biomol. Spectrosc., 113 (2013), pp. 281-285
  • [10] İlhan, M., et al., NIR Photoluminescence And Radioluminescence Characteristics Of Nd 3+ Doped BaTa 2 O 6 Phosphor, Int. J. Appl. Ceram. Technol., 15 (2018), 6, pp. 1594-1601
  • [11] Keskin, İ.Ç., İlhan, M., Thermoluminescence Kinetic Parameters And Radioluminescence Of RE3+ (RE = Pr, Sm, Tb, Ho, Er)-Doped Barium Tantalate Phosphors, J. Electron. Mater., 52 (2023), 8, pp. 5614-5630
  • [12] Keskin, İ.Ç., et al., X-Ray Irradiated Thermo- And Radioluminescence, Structural And Thermal Characterization Of Septarian (Powder&Bulk) From Madagascar, Opt. Mater. (Amst)., 83 (2018), pp. 176-181
  • [13] Jozanikohan, G., Nosrati, M., The Fourier Transform Infrared Spectroscopy ( FTIR ) Analysis For The Clay Mineralogy Studies In A Clastic Reservoir, J. Pet. Explor. Prod. Technol., 12 (2022), 8, pp. 2093-2106
  • [14] Ullah, R., et al., Synthesis And Characterization Of Silica Coated Iron-Oxide Composites Of Different Ratios, Int. J. Compos. Mater., 4 (2014), 2, pp. 135-145
  • [15] Ramasamy, V., et al., Depth Wise Analysis Of Recently Excavated Vellar River Sediments Through FTIR And XRD Studies, Indian J. Phys., 83 (2009), 9, pp. 1295-1308
  • [16] Keskı̇n, İ.Ç., Radioluminescence Results, Thermoluminescence Analysis And Kinetic Parameters Of Y2O3:Ln3+ (Ln: Dy, Nd, Sm) Nanophosphors Obtained By Sol-Gel Method, Ceram. Int., 48 (2022), 14, pp. 20579-20590
  • [17] Keskin, İ.Ç., et al., Detailed Luminescence (RL, PL, CL, TL) Behaviors Of Tb3+ And Dy3+ Doped LiMgPO4 Synthesized By Sol-Gel Method, J. Lumin., 225 (2020), pp. 117276
  • [18] Striganov, A.R., Sventitskii, N.S., Tables Of Spectral Lines Of Neutral And Ionized Atoms, Springer US, Boston, MA, 1968
  • [19] Bayraktar, N.Ş., Krizopnas ve Rodonit ’ in Termolüminesans, MSc Thesis, Erzincan Üniversitesi Fen, 2010

SAROS KÖRFEZİ KİL ÖRNEĞİNİN YAPISAL KARAKTERİZASYONU, TERMO VE X-IŞINI İLE UYARTMALI LUMİNESANS ÖZELLİKLERİNİN İNCELENMESİ

Year 2023, Volume: 2 Issue: 36, 1 - 12, 31.12.2023
https://doi.org/10.47118/somatbd.1403544

Abstract

Kil, temel olarak illit, kaolinit, montmorillonit grupları olarak adlandırılmaktadır. Doğada bol miktarda bulunmakla birlikte saf kil bulmak oldukça zordur. Kili meydana getiren maddeler sulu alüminyum silikatlerdir. Her kil grubu içerisinde farklı metal oksitler veya organik bileşikler barındırmaktadır. Minerallerin barındırdığı bu safsızlıklar lüminesans ve optik çalışmalarında ilgi çekici bir alan oluşturmaktadır.
Kil mineralleri üzerine pek çok çalışma bulunmakla birlikte herbir örnek kendine özgü özellikler göstermektedir. Bu çalışmada Saros Körfezine kıyısı bulunan Edirne-Keşan-Erikli Sahilinden alınan kil örnekleri ile çalışılmıştır. XRD analizi ile krsitalografik yapısı belirlenmiş, reolojik özellikleri ve içerdiği elementler SEM-EDX analizi ile tespit edilmiş, FT-IR analizi ile yapısal özellikleri incelenmiştir. Optik absorbsiyon analizinde UV ve Vis bölgede güçlü soğurma bandları gözlenmiştir. Radyolüminesans (RL) analizinde X ışını uyartımı ile oluşan ışıma bandları tartışılmıştır. Yine birincil uyartım olarak X ışını kullanılarak alınan termolüminesans (TL) analizinde sığ ve derin tuzaklara pikler görülmüştür.
Optik absorbsiyon analizinde UV bölgede ve 273, 330, 465, 510 nm’de güçlü soğurma bandları gözlenmiştir. RL analizinde yaklaşık 550, 610, 720 ve 850 nm'de geniş emisyonlar gözlenmiştir. Alınan ölçümlerde 250 oC’deki ana pikin yanı sıra yaklaşık 100 ve 340 oC civarında TL pikleri görülmüştür.

References

  • [1] Sam Boggs, S.B.J., Principles Of Sedimentology And Stratigraphy, Pearson Prentice Hall.
  • [2] Division, C., et al., Nanoclays For Polymer Nanocomposites , Paints , Inks , Greases And Cosmetics Formulations , Drug Delivery Vehicle And Waste Water Treatment, 29 (2006), 2, pp. 133-145
  • [3] Faïza Bergaya, B. K. G. Theng, G.L., Handbook Of Clay Science, Elsevier Ltd, 2006
  • [4] Dubey, V., et al., Thermoluminescence Study, Including The Effect Of Heating Rate, And Chemical Characterization Of Amarnath Stone Collected From Amarnath Holy Cave, Res. Chem. Intermed., 40 (2014), 2, pp. 531-536
  • [5] Yüksel, M., et al., Thermoluminescence Properties Of Annealed Natural Quartz After Beta Irradiation, Luminescence, 31 (2016), 8, pp. 1513-1518
  • [6] Jose, M.T., et al., Determination Of Thermoluminescence Kinetic Parameters Of Thulium Doped Lithium Calcium Borate, Radiat. Meas., 46 (2011), 10, pp. 1026-1032
  • [7] da Silva, R.S., et al., Thermoluminescence Kinetic Parameters Of Bi4Ge3O12 Single Crystals, Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. with Mater. Atoms, 250 (2006), 1-2, pp. 390-395
  • [8] Arslanlar Tuncer Y., Kibar R., Çetin A., Canımoğlu A., A.T.Y., Radioluminescence Properties Of Copper- And Terbium-Implanted Strontium Titanate Radioluminescence Properties Of Copper- And Terbium-Implanted Strontium Titanate, Lett. Spectrosc., (2013), July, pp. 364-366
  • [9] Rodríguez-Lazcano, Y., et al., Thermo- And Cathodoluminescence Properties Of Lepidolite, Spectrochim. Acta Part A Mol. Biomol. Spectrosc., 113 (2013), pp. 281-285
  • [10] İlhan, M., et al., NIR Photoluminescence And Radioluminescence Characteristics Of Nd 3+ Doped BaTa 2 O 6 Phosphor, Int. J. Appl. Ceram. Technol., 15 (2018), 6, pp. 1594-1601
  • [11] Keskin, İ.Ç., İlhan, M., Thermoluminescence Kinetic Parameters And Radioluminescence Of RE3+ (RE = Pr, Sm, Tb, Ho, Er)-Doped Barium Tantalate Phosphors, J. Electron. Mater., 52 (2023), 8, pp. 5614-5630
  • [12] Keskin, İ.Ç., et al., X-Ray Irradiated Thermo- And Radioluminescence, Structural And Thermal Characterization Of Septarian (Powder&Bulk) From Madagascar, Opt. Mater. (Amst)., 83 (2018), pp. 176-181
  • [13] Jozanikohan, G., Nosrati, M., The Fourier Transform Infrared Spectroscopy ( FTIR ) Analysis For The Clay Mineralogy Studies In A Clastic Reservoir, J. Pet. Explor. Prod. Technol., 12 (2022), 8, pp. 2093-2106
  • [14] Ullah, R., et al., Synthesis And Characterization Of Silica Coated Iron-Oxide Composites Of Different Ratios, Int. J. Compos. Mater., 4 (2014), 2, pp. 135-145
  • [15] Ramasamy, V., et al., Depth Wise Analysis Of Recently Excavated Vellar River Sediments Through FTIR And XRD Studies, Indian J. Phys., 83 (2009), 9, pp. 1295-1308
  • [16] Keskı̇n, İ.Ç., Radioluminescence Results, Thermoluminescence Analysis And Kinetic Parameters Of Y2O3:Ln3+ (Ln: Dy, Nd, Sm) Nanophosphors Obtained By Sol-Gel Method, Ceram. Int., 48 (2022), 14, pp. 20579-20590
  • [17] Keskin, İ.Ç., et al., Detailed Luminescence (RL, PL, CL, TL) Behaviors Of Tb3+ And Dy3+ Doped LiMgPO4 Synthesized By Sol-Gel Method, J. Lumin., 225 (2020), pp. 117276
  • [18] Striganov, A.R., Sventitskii, N.S., Tables Of Spectral Lines Of Neutral And Ionized Atoms, Springer US, Boston, MA, 1968
  • [19] Bayraktar, N.Ş., Krizopnas ve Rodonit ’ in Termolüminesans, MSc Thesis, Erzincan Üniversitesi Fen, 2010
There are 19 citations in total.

Details

Primary Language English
Subjects Material Characterization
Journal Section Issue 36, Volume II
Authors

İlker Çetin Keskin 0000-0003-2743-766X

Publication Date December 31, 2023
Submission Date December 11, 2023
Acceptance Date December 24, 2023
Published in Issue Year 2023 Volume: 2 Issue: 36

Cite

APA Keskin, İ. Ç. (2023). THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE. Soma Meslek Yüksekokulu Teknik Bilimler Dergisi, 2(36), 1-12. https://doi.org/10.47118/somatbd.1403544
AMA Keskin İÇ. THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE. Soma MYO Teknik Bilimler Dergisi. December 2023;2(36):1-12. doi:10.47118/somatbd.1403544
Chicago Keskin, İlker Çetin. “THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE”. Soma Meslek Yüksekokulu Teknik Bilimler Dergisi 2, no. 36 (December 2023): 1-12. https://doi.org/10.47118/somatbd.1403544.
EndNote Keskin İÇ (December 1, 2023) THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE. Soma Meslek Yüksekokulu Teknik Bilimler Dergisi 2 36 1–12.
IEEE İ. Ç. Keskin, “THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE”, Soma MYO Teknik Bilimler Dergisi, vol. 2, no. 36, pp. 1–12, 2023, doi: 10.47118/somatbd.1403544.
ISNAD Keskin, İlker Çetin. “THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE”. Soma Meslek Yüksekokulu Teknik Bilimler Dergisi 2/36 (December 2023), 1-12. https://doi.org/10.47118/somatbd.1403544.
JAMA Keskin İÇ. THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE. Soma MYO Teknik Bilimler Dergisi. 2023;2:1–12.
MLA Keskin, İlker Çetin. “THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE”. Soma Meslek Yüksekokulu Teknik Bilimler Dergisi, vol. 2, no. 36, 2023, pp. 1-12, doi:10.47118/somatbd.1403544.
Vancouver Keskin İÇ. THE STRUCTURAL CHARACTERIZATION, INVESTIGATION VIA THERMO AND X-RAY STIMULATED LUMINESCENCE PROPERTIES OF SAROS GULF CLAY SAMPLE. Soma MYO Teknik Bilimler Dergisi. 2023;2(36):1-12.