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TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ

Year 2015, Issue: 41, 97 - 103, 01.12.2015

Abstract

Bu çalışmada çıkış maddesi olarak siyanür klorür kullanıldı. Siyanür klorür, literatürde verilen metodlardan faydalanılarak asetonlu ortamda üç klor ucundan 5-hidroksiizoftalik asit kullanılarak 100 oC’de üç yönlü (tripodal) 2,4,6-tris(3,5-dikarboksifenoksi)-s-triazin bileşikleri sentezlendi. Çok yönlü s-triazinlerin sentezi için, 5-hidroksiizoftalik asit, literatürde verilen metotlardan faydalanılarak hidroksil ucundan kenetleme reaksiyonu yapılarak tripodal-s-triazinler sentezlendi. Etanollü ortamda çözülmüş, 2,4,6-tris(3,5-dikarboksifen oksi)-s-triazin ligandlarına etanolde çözülmüş ligand kompleksleri [Fe(salen/saloph)]2O, [Cr(salen/ saloph)]2O ilave edilerek çift oksijenle koordine olmuş tripodal komplekslerinin sentezi gerçekleştirildi. Sonuç olarak, tripodal-s-triazin ligandı ve bu ligandın Fe(III), Cr(III) kompleksleri izole edilerek, elemental analizleri, FT-IR, 1H-NMR, manyetik süsseptibilite spektrumları alınarak yapıları aydınlatıldı.

References

  • Candlın, JP, Taylor, KA and Thompson DT (1968). Reactions of Transition Metal Complexes, Elsevier, Amsterdam, 87.
  • Çelik C, Tümer M and Serin S (2002). Complexes of tetradentate schiff base ligands with divalent transition metals, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 1839.
  • Kandil SS, El-Dissouky A and Ali GY (2004). Cobalt(II) and copper(II) complexes of (2-Acetylpyridine)-(5,6Diphenyl-[1,2,4]Triazin-3-yl) hydrazone, Journal of Coordination Chemistry, 57, 105-113
  • Karataş İ. and Uçan Hİ (1998). The synthesis of biphenylglyoxime and bis(phenyloxime) and their complexes with Cu(II), Ni(II) and Co(II), Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 28, 383.
  • Karipcin F, Karatas I, Ucan HI (2002). Binuclear and mononuclear cobalt(II), nickel(II) and copper(II) complexes of 4,4’-bis(alkylaminoisonitrosoacetyl)-diphenylmethane derivatives, Transition Metal Chemistry, 27, 813.
  • Koç ZE (2011). Complexes of iron(III) and chromium(III) salen and salophen Schiff Bases with bridging 1,3,5Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry 48, 747–990.
  • Koç ZE, S. Uysal (2010). Synthesis and characterization of dendrimeric bridged salen/saloph complexes and investigation of their magnetic and thermal behaviors, Helvetica Chimica Acta, 93, 910-919.
  • Koç ZE, Uçan Hİ (2007). Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazin and 2,4,6-tris(4-carboxyphenylimino-4’formylphenoxy)-1,3,5-triazin, Transition Metal Chemistry, 32, 597-602.
  • Kopel E (1998). Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23, 139.
  • Sasaki T and Tahmassebi DC (1994). Synthesis of a new trialdehyde template for molecular imprinting, Journal of Organic Chemistry, 59, 679.
  • Tahmassebi DC and Sasaki T (1998). Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63, 728-731.
  • Tan N and Bekaroğlu Ö (1983). Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione dioxime and comparison with B Model Compounds, Synthesis and Reactivity in Inorganic, MetalOrganic, and Nano-Metal Chemistry, 13, 667-682.

THE SYNTHESIS OF TRIPODAL S-TRIAZINE LIGAND AND INVESTIGATION OF TRANSITION METAL COMPLEXES

Year 2015, Issue: 41, 97 - 103, 01.12.2015

Abstract

In this study, cyanuric chloride was used as a starting material. Cyanuric chloride, given in the literature making use of methods in acetone end of the 5-hydroxyisophtalic acid chloride using 100 oC (tripodal) 2,4,6-tris(3,5- dicarboxyphenoxy)-s-triazine compounds were synthesized. Very versatile for the synthesis of striazines, 5-hydroxyisophtalic acid, hydroxyl end of the coupling reaction done by making use of the methods given in the literature s-triazines were synthesized multipodal. Dissolved in ethanol 2,4,6-tris(3,5- dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with tripodal was performed in conclusion, three different ligands and this ligands of Fe(III), Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.

References

  • Candlın, JP, Taylor, KA and Thompson DT (1968). Reactions of Transition Metal Complexes, Elsevier, Amsterdam, 87.
  • Çelik C, Tümer M and Serin S (2002). Complexes of tetradentate schiff base ligands with divalent transition metals, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 1839.
  • Kandil SS, El-Dissouky A and Ali GY (2004). Cobalt(II) and copper(II) complexes of (2-Acetylpyridine)-(5,6Diphenyl-[1,2,4]Triazin-3-yl) hydrazone, Journal of Coordination Chemistry, 57, 105-113
  • Karataş İ. and Uçan Hİ (1998). The synthesis of biphenylglyoxime and bis(phenyloxime) and their complexes with Cu(II), Ni(II) and Co(II), Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 28, 383.
  • Karipcin F, Karatas I, Ucan HI (2002). Binuclear and mononuclear cobalt(II), nickel(II) and copper(II) complexes of 4,4’-bis(alkylaminoisonitrosoacetyl)-diphenylmethane derivatives, Transition Metal Chemistry, 27, 813.
  • Koç ZE (2011). Complexes of iron(III) and chromium(III) salen and salophen Schiff Bases with bridging 1,3,5Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry 48, 747–990.
  • Koç ZE, S. Uysal (2010). Synthesis and characterization of dendrimeric bridged salen/saloph complexes and investigation of their magnetic and thermal behaviors, Helvetica Chimica Acta, 93, 910-919.
  • Koç ZE, Uçan Hİ (2007). Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazin and 2,4,6-tris(4-carboxyphenylimino-4’formylphenoxy)-1,3,5-triazin, Transition Metal Chemistry, 32, 597-602.
  • Kopel E (1998). Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23, 139.
  • Sasaki T and Tahmassebi DC (1994). Synthesis of a new trialdehyde template for molecular imprinting, Journal of Organic Chemistry, 59, 679.
  • Tahmassebi DC and Sasaki T (1998). Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63, 728-731.
  • Tan N and Bekaroğlu Ö (1983). Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione dioxime and comparison with B Model Compounds, Synthesis and Reactivity in Inorganic, MetalOrganic, and Nano-Metal Chemistry, 13, 667-682.
There are 12 citations in total.

Details

Other ID JA57YS78PC
Journal Section Research Articles
Authors

Ziya Erdem Koç This is me

Publication Date December 1, 2015
Submission Date December 1, 2015
Published in Issue Year 2015 Issue: 41

Cite

APA Koç, Z. E. (2015). TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi(41), 97-103.
AMA Koç ZE. TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ. sufefd. December 2015;(41):97-103.
Chicago Koç, Ziya Erdem. “TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, no. 41 (December 2015): 97-103.
EndNote Koç ZE (December 1, 2015) TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 41 97–103.
IEEE Z. E. Koç, “TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ”, sufefd, no. 41, pp. 97–103, December 2015.
ISNAD Koç, Ziya Erdem. “TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 41 (December 2015), 97-103.
JAMA Koç ZE. TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ. sufefd. 2015;:97–103.
MLA Koç, Ziya Erdem. “TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, no. 41, 2015, pp. 97-103.
Vancouver Koç ZE. TRİPODAL S-TRİAZİN LİGANDININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ. sufefd. 2015(41):97-103.

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Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.

It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
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