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s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi

Year 2017, Volume: 43 Issue: 2, 149 - 162, 31.10.2017

Abstract

Bu çalışmada çıkış maddesi
olarak asetoguanamin (6-metil-2,4-diamino-1,3,5-triazin) [AG] kullanıldı.
6-Metil-2,4-diamino-1,3,5-triazin literatürden yararlanarak elde edilen azo
boyar madde özelliği gösteren 2-hidroksi-5-[(E)-(arildiazenil)]benzaldehit [1],
(2,4-dimetilfenil)diazenil)-2-hidroksibenzaldehit [2],
5-(2,5-dimetilfenil)diazenil)-2-hidroksibenzaldehit’in [3] kondenzasyon
reaksiyonu ile elde edilen s-triazin merkezli azo boyar Schiff bazlarına susuz FeCl3
ve CrCl3.6H2O bileşikleri ilave edilerek kompleks
yapıları sentezlendi. Sonuç olarak, elde edilen ligandların FT-IR, 1H
NMR, elementel analizi ve TGA ile yapısı aydınlatıldı. Elde edilen üç farklı
s-triazin merkezli azo boyar Schiff baz komplekslerin FT-IR, TGA ve manyetik
süsseptibiliteleri alınarak yapıları aydınlatıldı.

References

  • Koç ZE, Uçan Hİ (2007). Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5-dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazin and 2,4,6-tris(4-carboxyphenylimino-4’-formylphenoxy)-1,3,5-triazin, Transition Metal Chemistry, 32, 597-602

The Synthesis of s-Triazine Dyes and Investigation of Some of Their Metal Complexes

Year 2017, Volume: 43 Issue: 2, 149 - 162, 31.10.2017

Abstract

In this work, acetoguanamine (6-methyl-2,4-diamino-1,3,5-triazine) [AG]
was used as the starting material. 6-Methyl-2,4-diamino-1,3,5-triazine was
obtained from the literature and the s-triazine-based azo dye Schiff bases
obtained by the condensation reaction of
2-hydroxy-5-[(E)-(aryldiazenyl)]benzaldehyde [1],
(2,4-dimethylphenyl)diazenyl)-2-hydroxybenzaldehyde [2],
5-(2,5-dimethylphenyl)diazenyl)-2-hydroxybenzaldehyde [3] complexes were
synthesized by adding anhydrous FeCl3 and CrCl3.6H2O
compounds. As a result, the structure of the resulting ligands was clarified by
FT-IR, 1H NMR, elemental analysis and TGA. FT-IR, TGA and magnetic
susceptibility properties of three different s-triazin-centered azo-dye Schiff
base complexes were investigated.

References

  • Koç ZE, Uçan Hİ (2007). Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5-dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazin and 2,4,6-tris(4-carboxyphenylimino-4’-formylphenoxy)-1,3,5-triazin, Transition Metal Chemistry, 32, 597-602
There are 1 citations in total.

Details

Journal Section Research Articles
Authors

Ziya Erdem Koç

Publication Date October 31, 2017
Submission Date May 30, 2017
Published in Issue Year 2017 Volume: 43 Issue: 2

Cite

APA Koç, Z. E. (2017). s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, 43(2), 149-162.
AMA Koç ZE. s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi. sufefd. October 2017;43(2):149-162.
Chicago Koç, Ziya Erdem. “S-Triazin Boyar Maddelerinin Sentezi Ve Onların Bazı Metal Komplekslerinin İncelenmesi”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 43, no. 2 (October 2017): 149-62.
EndNote Koç ZE (October 1, 2017) s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 43 2 149–162.
IEEE Z. E. Koç, “s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi”, sufefd, vol. 43, no. 2, pp. 149–162, 2017.
ISNAD Koç, Ziya Erdem. “S-Triazin Boyar Maddelerinin Sentezi Ve Onların Bazı Metal Komplekslerinin İncelenmesi”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 43/2 (October 2017), 149-162.
JAMA Koç ZE. s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi. sufefd. 2017;43:149–162.
MLA Koç, Ziya Erdem. “S-Triazin Boyar Maddelerinin Sentezi Ve Onların Bazı Metal Komplekslerinin İncelenmesi”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, vol. 43, no. 2, 2017, pp. 149-62.
Vancouver Koç ZE. s-Triazin Boyar Maddelerinin Sentezi ve Onların Bazı Metal Komplekslerinin İncelenmesi. sufefd. 2017;43(2):149-62.

Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Hüseyin YILMAZ
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.

It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
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