Preparation of Metal-Thin Film-Metal Device Structure for Pyroelectric Heat Sensor Measurement
Year 2023,
Volume: 2 Issue: 1, 29 - 35, 21.05.2023
Rıfat Çapan
Zikriye Özbek
Abstract
In this study, the pyroelectric properties of organic Langmuir-Blodgett (LB) thin film material produced
at the nanometer scale were investigated. LB thin films obtained by transferring organic molecules floating on the water
surface to the solid surface were produced in an unsymmetrical structure. Steric acid and eicosylamine molecules were
selected to fabricate unsymmetrical LB film structure. This structure was used to investigate the pyroelectric and
electrical (C-f and C-tan δ) measurements. The pyroelectric figure of merit (FOM) was determined using pyroelectric
constant, the dielectric constant value and dielectric loss. The value of FOM for the stearic acid/eicosylamine LB film
was determined as 0.530 Cm-2K-1
.
References
- [1] R. Çapan, “Organic pyroelectric materials for
device applications,” Balıkesir University
Journal of Science (BAÜ FBE Dergisi), vol. 12,
no. 1, pp. 75-90, 2010.
- [2] Zhuo Han, Sana Ullah, Guangping Zheng, Hua
bing Yin, Jinlin Zhao, Shiduo Cheng, Xianying
Wang, Junhe Yang, “The thermal-to-electrical
energy conversion in
(Bi0.5Na0.5)0.94Ba0.06TiO3/graphene oxide
heterogeneous structures,” Ceramics
International, vol. 45, no. 18, pp.24493-24499,
2019.
- [3] M. B. Biddle, S. E. Rickert, “Opportunities for
Langmuir-Blodgett-films in piezoelectric and
pyroelectric devices,” Ferroelectrics, vol. 76, no.
1-2, 133, 1987.
- [4] S. G. Porter, “A brief guide to pyroelectric
detectors,” Ferroelectrics, vol. 33, no. 1-4, pp.
193-206, 1981.
- [5] H. Huang, Z. Tianshu, J. T. Oh, P. Hing, “Effect
of a-site substitution of calcium on Zr-rich lead
zirconate titanate,” Ferroelectrics, vol. 274, pp.
55–65, 2002.
- [6] B. Ploss, B. Ploss, F. G. Shin, H. L. W. Chan, and
C. L. Choy, “Pyroelectric or piezoelectric
compensated ferroelectric composites,”
Applied Physics Letters, vol. 76, no. 19, pp.
2776-2778, 2000.
- [7] D. Lacey, S. Holder, W H A. Majid, R. Capan, T.
Richardson, “High Pyroelectric Sensitivity in
Alternate Layer LangmuirBlodgett Superlatices,” Materials Science &
Engineering C, vol. 3, pp. 197-203, 1995.
- [8] R. Capan, S.V. Batty, T. Richardson, D. Lacey, S,
J. Holder, “Optimisation of The Pyroelectric
Figure of Merit of Polysiloxane/amine
Superlattices,” Thin Solid Films, vol. 284-285,
pp. 915-918, 1996.
- [9] R. Çapan, A.K. Ray, T. H. Richardson, A.K.
Hassan and F. Davis,
“Pyroelectric and Conduction Properties of Ztype Calix [4] acid Langmuir-Blodgett Films,”
J. of Nanoscience and Nanotechnology, vol: 5,
no: 11, pp. 1910-1914, 2005.
- [10]R. Capan, T. Richardson, J. Tsibouklis, “A
Study of Pyroelectric and Dielectric
Characterisation Using Alternate Layer
Langmuir-Blodgett Films,” Colloids & Surfaces
A, vol. 198-200, pp. 835-841, 2002.
- [11]P. Oliviere, J. Yarwood, T. H. Richardson,
“Pyroelectric Activity in Calix[8]arene/Amine
Langmuir Blodgett Films: New Insights into
the Mechanism of Polarization Variation with
Temperature,” Langmuir, vol. 19, no. 1, pp. 63-
71, 2003.
- [12]D. Lacey, T. Richardson, F. Davis, and
R. Capan, “Pyroelectric Superlattices Based
on Polysiloxane / Calix[n]arene Alternate LB
Films,” Materials Science & Engineering C, vol.
8-9 pp. 377-384, 1999.
- [13]R. Çapan, T. Richardson and D. Lacey,
“Pyroelectric Figure of Merit for a
Heterogeneous Alternate Layer LangmuirBlodgett Film System,” Thin Solid Films, vol.
415, no. 1-2, pp. 236-241, 2002.
- [14]R. Çapan, “Langmuir-Blodgett (LB) Film
Technique in Nanotechnology,”
Süleyman Demirel University Journal of
Science, vol. 8, no. 2, pp. 17-22, 2004.
- [15]L. Tian, J. Sun, Y. Li, X. Hua Zhang,
“Pyroelectric response in the Langmuir–
Blodgett fabricated artificial polymer
multilayers,” Modern Physics Letters B, vol. 33,
no. 11, pp. 1950137, 2019.
- [16]A. Kausar, “Survey on Langmuir–Blodgett
Films of Polymer and Polymeric Composite,”
vol. 56, no. 9, pp. 932-945, 2017.
- [17]R. Çapan, İ. Başaran, T.H. Richardson, D.
Lacey, “A Theoretical Model for The
Pyroelectric Response in Langmuir-Blodgett
Films,” Materials Science & Engineering C, vol.
22, no. 2, pp. 245-249, 2002.
- [18]R. Çapan, İ. Alp, T. H. Richardson, F. Davis,”
Pyroelectric Figure of Merit for a calix [4] acid/amine alternate layer LangmuirBlodgett Film,”, Materials Letters, vol.59, pp.
1945-1948, 2005.
- [19]R. Çapan, T. H. Richardson, “Pyroelectric effect
in a mixed polysiloxane/eicosylamine
Langmuir-Blodgett Thin Film,” Materials
Letters, vol. 25, pp. 3131-3135, 2004.
- [20]D. Lacey, T. Richardson, F. Davis, and
R. Capan, “Pyroelectric Superlattices Based
on Polysiloxane / Calix[n]arene Alternate LB
Films,” Materials Science & Engineering C, vol.
8-9 pp. 377-384, 1999.
- [21]R. Çapan, “Pyroelectric and Dielectric
Characterisation of Alternate Layer LangmuirBlodgett Films Incorporating Ions,” Materials
Letters, vol. 61, no. 4-5, pp. 1231-1234, 2007.
- [22]R. Çapan, T. H. Richardson, D. Lacey,
“Pyroelectric Effect in Langmuir-Blodgett Films
Incorporating Ions,” Thin Solid Films, vol. 468,
no. 1-2, pp. 262-267, 2004.
- [23]R. Capan, T. Richardson, D. Lacey, “Cd 2+ and
Mn 2+ Incorporation in
Copolysiloxane/Eicosylamine Alternate Layer
LB Films:Influence on Pyroelectric Activity,”
Thin Solid Films, vol: 327-329, pp. 369-372, 1998.
Pyroelektrik Isı Sensörü Ölçümü İçin Metal-İnce Film-Metal Cihaz Yapısının Hazırlanması
Year 2023,
Volume: 2 Issue: 1, 29 - 35, 21.05.2023
Rıfat Çapan
Zikriye Özbek
Abstract
Bu çalışmada, nanometre ölçeğinde üretilen organik Langmuir-Blodgett (LB) ince film malzemesinin piroelektrik
özellikleri incelenmiştir. Su yüzeyinde yüzen organik moleküllerin katı yüzeye aktarılmasıyla elde edilen LB ince
filmler simetrik olmayan bir yapıda üretilmiştir. Simetrik olmayan LB film yapısını imal etmek için sterik asit ve
eikosilamin molekülleri seçildi. Bu yapı, piroelektrik ve elektriksel (C-f ve C-tan δ) ölçümlerini araştırmak için
kullanıldı. Piroelektrik figüre of merit (FOM) değeri piroelektrik sabiti, dielektrik sabiti değeri ve dielektrik kaybı
kullanılarak hesaplandı. Sterik asit/eikosilamin LB filmi için FOM değeri 0.530 Cm-2K-1 olarak elde edilmiştir.
.
References
- [1] R. Çapan, “Organic pyroelectric materials for
device applications,” Balıkesir University
Journal of Science (BAÜ FBE Dergisi), vol. 12,
no. 1, pp. 75-90, 2010.
- [2] Zhuo Han, Sana Ullah, Guangping Zheng, Hua
bing Yin, Jinlin Zhao, Shiduo Cheng, Xianying
Wang, Junhe Yang, “The thermal-to-electrical
energy conversion in
(Bi0.5Na0.5)0.94Ba0.06TiO3/graphene oxide
heterogeneous structures,” Ceramics
International, vol. 45, no. 18, pp.24493-24499,
2019.
- [3] M. B. Biddle, S. E. Rickert, “Opportunities for
Langmuir-Blodgett-films in piezoelectric and
pyroelectric devices,” Ferroelectrics, vol. 76, no.
1-2, 133, 1987.
- [4] S. G. Porter, “A brief guide to pyroelectric
detectors,” Ferroelectrics, vol. 33, no. 1-4, pp.
193-206, 1981.
- [5] H. Huang, Z. Tianshu, J. T. Oh, P. Hing, “Effect
of a-site substitution of calcium on Zr-rich lead
zirconate titanate,” Ferroelectrics, vol. 274, pp.
55–65, 2002.
- [6] B. Ploss, B. Ploss, F. G. Shin, H. L. W. Chan, and
C. L. Choy, “Pyroelectric or piezoelectric
compensated ferroelectric composites,”
Applied Physics Letters, vol. 76, no. 19, pp.
2776-2778, 2000.
- [7] D. Lacey, S. Holder, W H A. Majid, R. Capan, T.
Richardson, “High Pyroelectric Sensitivity in
Alternate Layer LangmuirBlodgett Superlatices,” Materials Science &
Engineering C, vol. 3, pp. 197-203, 1995.
- [8] R. Capan, S.V. Batty, T. Richardson, D. Lacey, S,
J. Holder, “Optimisation of The Pyroelectric
Figure of Merit of Polysiloxane/amine
Superlattices,” Thin Solid Films, vol. 284-285,
pp. 915-918, 1996.
- [9] R. Çapan, A.K. Ray, T. H. Richardson, A.K.
Hassan and F. Davis,
“Pyroelectric and Conduction Properties of Ztype Calix [4] acid Langmuir-Blodgett Films,”
J. of Nanoscience and Nanotechnology, vol: 5,
no: 11, pp. 1910-1914, 2005.
- [10]R. Capan, T. Richardson, J. Tsibouklis, “A
Study of Pyroelectric and Dielectric
Characterisation Using Alternate Layer
Langmuir-Blodgett Films,” Colloids & Surfaces
A, vol. 198-200, pp. 835-841, 2002.
- [11]P. Oliviere, J. Yarwood, T. H. Richardson,
“Pyroelectric Activity in Calix[8]arene/Amine
Langmuir Blodgett Films: New Insights into
the Mechanism of Polarization Variation with
Temperature,” Langmuir, vol. 19, no. 1, pp. 63-
71, 2003.
- [12]D. Lacey, T. Richardson, F. Davis, and
R. Capan, “Pyroelectric Superlattices Based
on Polysiloxane / Calix[n]arene Alternate LB
Films,” Materials Science & Engineering C, vol.
8-9 pp. 377-384, 1999.
- [13]R. Çapan, T. Richardson and D. Lacey,
“Pyroelectric Figure of Merit for a
Heterogeneous Alternate Layer LangmuirBlodgett Film System,” Thin Solid Films, vol.
415, no. 1-2, pp. 236-241, 2002.
- [14]R. Çapan, “Langmuir-Blodgett (LB) Film
Technique in Nanotechnology,”
Süleyman Demirel University Journal of
Science, vol. 8, no. 2, pp. 17-22, 2004.
- [15]L. Tian, J. Sun, Y. Li, X. Hua Zhang,
“Pyroelectric response in the Langmuir–
Blodgett fabricated artificial polymer
multilayers,” Modern Physics Letters B, vol. 33,
no. 11, pp. 1950137, 2019.
- [16]A. Kausar, “Survey on Langmuir–Blodgett
Films of Polymer and Polymeric Composite,”
vol. 56, no. 9, pp. 932-945, 2017.
- [17]R. Çapan, İ. Başaran, T.H. Richardson, D.
Lacey, “A Theoretical Model for The
Pyroelectric Response in Langmuir-Blodgett
Films,” Materials Science & Engineering C, vol.
22, no. 2, pp. 245-249, 2002.
- [18]R. Çapan, İ. Alp, T. H. Richardson, F. Davis,”
Pyroelectric Figure of Merit for a calix [4] acid/amine alternate layer LangmuirBlodgett Film,”, Materials Letters, vol.59, pp.
1945-1948, 2005.
- [19]R. Çapan, T. H. Richardson, “Pyroelectric effect
in a mixed polysiloxane/eicosylamine
Langmuir-Blodgett Thin Film,” Materials
Letters, vol. 25, pp. 3131-3135, 2004.
- [20]D. Lacey, T. Richardson, F. Davis, and
R. Capan, “Pyroelectric Superlattices Based
on Polysiloxane / Calix[n]arene Alternate LB
Films,” Materials Science & Engineering C, vol.
8-9 pp. 377-384, 1999.
- [21]R. Çapan, “Pyroelectric and Dielectric
Characterisation of Alternate Layer LangmuirBlodgett Films Incorporating Ions,” Materials
Letters, vol. 61, no. 4-5, pp. 1231-1234, 2007.
- [22]R. Çapan, T. H. Richardson, D. Lacey,
“Pyroelectric Effect in Langmuir-Blodgett Films
Incorporating Ions,” Thin Solid Films, vol. 468,
no. 1-2, pp. 262-267, 2004.
- [23]R. Capan, T. Richardson, D. Lacey, “Cd 2+ and
Mn 2+ Incorporation in
Copolysiloxane/Eicosylamine Alternate Layer
LB Films:Influence on Pyroelectric Activity,”
Thin Solid Films, vol: 327-329, pp. 369-372, 1998.