trakya univ j nat sci

Trakya University Journal of Natural Sciences

2528-9691

Trakya University

10.23902/trkjnat.284521

SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI

SYNTHESIS AND ANTIMICROBIAL ACTIVITY OF IRON CYCLOHEXANEDICARBOXYLIC ACID AND EXAMINATION OF pH EFFECT ON EXTRACTION IN WATER AND ORGANIC PHASES

Becenen

Nilgün

Uluçam

Gühergül

Altun

Özlen

03 10 2017

18 1 1 7 01 06 2017 02 06 2017

2000

Trakya University Journal of Natural Sciences

Buçalışmada, reflux şartlarında demir siklohekzandikarboksilli asitsentezlenmiştir. Kompleksin yapısı fizikokimyasal ve spektroskopik metodlarlakarakterize edilmiştir. Daha sonra reaksiyon sırasında pH’ın su ve organikfazlardaki paylaşma sabitleri () ve ekstraksiyon yüzdelerine (%E) etkisiekstraksiyon metodu ile incelenmiştir. Deney sonucunda, su fazındaki Fe2+iyonlarının çoğu pH=7.5’ta organik faza geçmiştir. Bu pH’tan sonra ekstraksiyonyüzdesi su fazından organik faza geçiş yüzünden azalmıştır. Demir siklohekzandikarboksilliasit eter, petrol eteri, benzol ve karbon tetra klorür ile sulu çözeltilerindenekstre edilmiş, ilave olarak kompleksin mikrobiyal aktiviteleri çalışılmıştır.Aktivite sonuçları, demir siklohekzandikarboksilli asitin önemli antibakteriyalve antifungal aktiviteye sahip olduğunu göstermiştir.

In this study, iron cyclohexanedicarboxylic acid wassynthesized under refluxing conditions. The structural characterization of thecomplex was performed by using physico-chemical and spectroscopic methods. Theeffect of pH on division constant (µ) and extraction percentages (% E) in water andorganic phase wasinvestigated with the extraction method. At the end of the experiment,most of the Fe2+ ions in the water phase at pH=7.5 passed into theorganic phase. Above this pH, the extraction percentage decreased because ofthe transition from water phase to organic phase. Iron cyclohexanedicarboxylic acidwas extracted with ether, petroleum ether, benzole and carbon tetrachloride from aqueous solution and microbial activitiesof the complex were studied. The activity data showed that iron cyclohexanedicarboxylicacid has an important antibacterial and antifungal activities.

Fe (II) cyclohexanedicarboxylic acid synthesis extraction

Fe (II) siklohekzandikarboksilli asit sentez ekstraksiyon

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