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Year 2017, Volume: 9 Issue: 3, 155 - 161, 26.12.2017
https://doi.org/10.29137/umagd.347702

Abstract

References

  • [1] T. Komoda, N. Ide, J. Kido, J.,”High Efficient OLEDs and Their Application to Lighting”, Light Vis. Environ. 32, 75., 2008. [2] T.M. Brown, R.H. Friend, I.S. Millard, D.J. Lacey, J.H. Burroughes, F. Cacialli, “Efficient electron injection in blue-emitting polymer light-emitting diodes with LiF/Ca/Al cathodes”, Appl. Phys. Lett. 79,174, 2001. [3] F. Laquai, G. Wegner, H. Bässler, Phil., “What determines the mobility of charge carriers in conjugated polymers?”,Trans. R. Soc. A 365,1473, 2007. [4] H.J. Bolink, E. Coronado, D. Repetto, M. Sessolo, Hybrid organic-inorganic light emitting diodes: effect of the metal oxide, Appl. Phys. Lett. 91,223501, 2007. 223501. [5] S.A. Haque, S. Koops, N. Tokmoldin, J.R. Durrant, J.S. Huang, D.D.C. Bradley, E. Palomares, “A Multilayered Polymer Light-Emitting Diode Using a Nanocrystalline Metal-Oxide Film as a Charge-Injection Electrode”, Adv. Mater. 19, 683, 2007. [6] N. Tokmoldin, N. Griffiths, D.D.C. Bradley, S.A. Haque, “A Hybrid Inorganic–Organic Semiconductor Light-Emitting Diode Using ZrO2 as an Electron-Injection Layer”, Adv. Mater. 21,1, 2009. [7] L. Wang, B. Liang, F. Huang, J. Peng, Y. Cao, “Utilization of water/alcohol-soluble polyelectrolyte as an electron injection layer for fabrication of high-efficiency multilayer saturated red-phosphorescence polymer light-emitting diodes by solution processing”, Appl. Phys. Lett. 89, 151115, 2006. [8] Y. Jin, G.C. Bazan, A.J. Heeger, J.Y. Kim, K. Lee, “Improved electron injection in polymer light-emitting diodes using anionic conjugated polyelectrolyte”, Appl. Phys. Lett. 93, 123304, 2008. [9] N. Glezos, P. Argitis, D. Velessiotis, C.D. Diakoumakos, “Tunneling transport in polyoxometalate based composite Materials”, Appl. Phys. Lett., 83, 488 ,2003. [10] M.T. Pope, A. Muller, “Polyoxometalates: From Platonic Solids To Anti-Retroviral Activity”, Angew. Chem., Int. Ed. Engl. 30,34, 1991. [11] A.M. Douvas, E. Makarona, N. Glezos, P. Argitis, J.A. Mielczarski, E. Mielczarski, “Polyoxometalate-based layered structures for charge transport control in molecular devices”, ACS Nano 2, 733, 2008. [12]R. Contant, “Relation entre les tungstophophates apparentés à l’anion PW12O403‐. Synthèse et propriétés d’un nouveau polyoxotungstophosphate lacunaire K10P2W20O70∙24H20”, Can. J. Chem., 65, 568‐573., 1987.

Organometallic compound derivates as a novel efficient electron injection layer for hybrid light-emitting diodes

Year 2017, Volume: 9 Issue: 3, 155 - 161, 26.12.2017
https://doi.org/10.29137/umagd.347702

Abstract

In this
study we have presented the use of a organometallic compounds derivates (Keggin
type polyoxometalates) for the production of powerful electron injection layer
between the emissive polymer layer (PFO) and cathode layer (Al) .
Electron transport studies
in
organometallic compounds layers showed efficient
electron transport in very thin structures.
High
efficiency solution-processed organic light emitting diodes (OLEDs) are
achieved by organometallic compounds 
such as Keggin type polyoxometalates used as electron injection or
transport layers with superb electron mobilities and hole blocking capacities.
These results indicate the potential for organometallic compounds derivates as
a variable, emerging new class of efficient electron injection/transport
molecular materials for high performance air-stable HyLEDs. The Keggin
type  polyoxometalates show unique
features such as superior ionization energy and 
low electron affinity which conversion them as efficient electron
injection/hole blocking layers and, immensely high electron mobility.

References

  • [1] T. Komoda, N. Ide, J. Kido, J.,”High Efficient OLEDs and Their Application to Lighting”, Light Vis. Environ. 32, 75., 2008. [2] T.M. Brown, R.H. Friend, I.S. Millard, D.J. Lacey, J.H. Burroughes, F. Cacialli, “Efficient electron injection in blue-emitting polymer light-emitting diodes with LiF/Ca/Al cathodes”, Appl. Phys. Lett. 79,174, 2001. [3] F. Laquai, G. Wegner, H. Bässler, Phil., “What determines the mobility of charge carriers in conjugated polymers?”,Trans. R. Soc. A 365,1473, 2007. [4] H.J. Bolink, E. Coronado, D. Repetto, M. Sessolo, Hybrid organic-inorganic light emitting diodes: effect of the metal oxide, Appl. Phys. Lett. 91,223501, 2007. 223501. [5] S.A. Haque, S. Koops, N. Tokmoldin, J.R. Durrant, J.S. Huang, D.D.C. Bradley, E. Palomares, “A Multilayered Polymer Light-Emitting Diode Using a Nanocrystalline Metal-Oxide Film as a Charge-Injection Electrode”, Adv. Mater. 19, 683, 2007. [6] N. Tokmoldin, N. Griffiths, D.D.C. Bradley, S.A. Haque, “A Hybrid Inorganic–Organic Semiconductor Light-Emitting Diode Using ZrO2 as an Electron-Injection Layer”, Adv. Mater. 21,1, 2009. [7] L. Wang, B. Liang, F. Huang, J. Peng, Y. Cao, “Utilization of water/alcohol-soluble polyelectrolyte as an electron injection layer for fabrication of high-efficiency multilayer saturated red-phosphorescence polymer light-emitting diodes by solution processing”, Appl. Phys. Lett. 89, 151115, 2006. [8] Y. Jin, G.C. Bazan, A.J. Heeger, J.Y. Kim, K. Lee, “Improved electron injection in polymer light-emitting diodes using anionic conjugated polyelectrolyte”, Appl. Phys. Lett. 93, 123304, 2008. [9] N. Glezos, P. Argitis, D. Velessiotis, C.D. Diakoumakos, “Tunneling transport in polyoxometalate based composite Materials”, Appl. Phys. Lett., 83, 488 ,2003. [10] M.T. Pope, A. Muller, “Polyoxometalates: From Platonic Solids To Anti-Retroviral Activity”, Angew. Chem., Int. Ed. Engl. 30,34, 1991. [11] A.M. Douvas, E. Makarona, N. Glezos, P. Argitis, J.A. Mielczarski, E. Mielczarski, “Polyoxometalate-based layered structures for charge transport control in molecular devices”, ACS Nano 2, 733, 2008. [12]R. Contant, “Relation entre les tungstophophates apparentés à l’anion PW12O403‐. Synthèse et propriétés d’un nouveau polyoxotungstophosphate lacunaire K10P2W20O70∙24H20”, Can. J. Chem., 65, 568‐573., 1987.
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Details

Journal Section Articles
Authors

Yasemin Torlak

Publication Date December 26, 2017
Submission Date October 8, 2017
Published in Issue Year 2017 Volume: 9 Issue: 3

Cite

APA Torlak, Y. (2017). Organometallic compound derivates as a novel efficient electron injection layer for hybrid light-emitting diodes. International Journal of Engineering Research and Development, 9(3), 155-161. https://doi.org/10.29137/umagd.347702

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