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Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic

Yıl 2018, Cilt: 46 Sayı: 2, 159 - 167, 03.06.2018

Öz

I
n this work, platinum (Pt), titanium (Ti) and silver (Ag) doped graphene oxide (GO) nanostructures were
synthesized by using sonochemical technique, a relatively new technique in nanomaterial synthesis, and
characterized in detail. The synthesized nanomaterials were characterized utilizing transmission electron
microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). TEM images and XPS spectras showed that
the dopping process was successful. In addition, a multilayer graphene oxide-silver nanoparticles (M-GOAgNPs)
nano-structure was synthesized in this study for the first time, and it’s electrochemical performance
was compared with GO-AgNPs. As a result of electrochemical study, the rate constants of the GO-AgNPs and
M-GO-AgNPs modified electrodes were found as ksanodic= 6.62 s-1 and ksanodic= 6.78 s-1, respectively. Finally, the
M-GO-AgNPs nano-structure obtained by sonochemical technique, a green chemistry synthesis technique, has
been found to be suitable for use as an electrochemical sensor matrix.

Kaynakça

  • J. Liu, X. Bo, Z. Zhao, L. Guo, Highly exposed Pt nanoparticles supported on porous graphene for electrochemical detection of hydrogen peroxide in living cells, Biosens. Bioelectron., 74 (2015) 71-77.
  • Z. Liu, Y. Guo, C. Dong, A high performance nonenzymatic electrochemical glucose sensor based on polyvinylpyrrolidone–graphene nanosheets–nickel nanoparticles–chitosan nanocomposite, Talanta, 137 (2015) 87-93.
  • G. Giovannetti, P.A. Khomyakov, G. Brocks, V.M. Karpan, J. van den Brink, and P.J. Kelly, Doping Graphene With Metal Contacts, Phys. Rev. Let., 101 (2008) 268031-268034.
  • B. Uchoa, C.Y. Lin, and A.H. Castro Neto, Tailoring graphene with metals on top, Phys. Rev. B, 77 (2008) 035421-035425.
  • G.M. Scheuermann, L. Rumi, P. Steurer, W. Bannwarth, R. Mulhaupt, Palladium nanoparticles on graphite oxide and its functionalized graphene derivatives as highly active catalysts for the Suzuki−Miyaura coupling reaction, J. Am. Chem. Soc., 131, 2009, 8262- 8270.
  • Y. Li, L. Tang, J. Li, Preparation and electrochemical performance for methanol oxidation of pt/graphene nanocomposites, Electrochem. Commun., 11 (2009) 846–849.
  • T. Maiyalagan, X. Dong, P. Chen, X. Wang, Electrodeposited Pt on three-dimensional interconnected graphene as a free-standing electrode for fuel cell application, J. Mater. Chem., 22 (2012) 5286-5290.
  • K.S. Suslick, Ultrasound: Its chemical, physical and biological effects, VCH Verlagsgesellschaft, Weinheim, Germany, 1988.
  • B. Neppolian, C. Wang, Muthupandian Ashokkumar. Sonochemically synthesized mono and bimetallic Au– Ag reduced graphene oxide based nanocomposites with enhanced catalytic activity, Ultrason. Sonochem., 21 (2014) 1948-1953.
  • B. Neppolian, A. Bruno, C.L. Bianchi, M. Ashokkumar, Graphene oxide based Pt–TiO2 photocatalyst: Ultrasound assisted synthesis, characterization and catalytic efficiency, Ultrason. Sonochem., 19 (2012) 9-15.
  • S. Zhu, J. Guo, J. Dong, Zn Cui, T. Lu, C. Zhu, D. Zhang, J. Ma, Sonochemical fabrication of Fe3O4 nanoparticles on reduced graphene oxide for biosensors, Ultrason. Sonochem., 20 (2013) 872-880.
  • L. Zhu, J.D. Chung, W.C. Oh, Rapid sonochemical synthesis of novel PbSe–graphene–TiO2 composite sonocatalysts with enhanced on decolorization performance and generation of ROS, Ultrason. Sonochem., 27 (2015) 252-261.
  • M. Giovanni, H.L. Poh, A. Ambrosi, G. Zhao, Z. Sofer, F. Sanek, B. Khezri, R.D. Webster and M. Pumera, Noble metal (Pd, Ru, Rh, Pt, Au, Ag) doped graphene hybrids for electrocatalysis, Nanoscale, 4 (2012) 5002.
  • E. Laviron, General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems, J. Electroanal. Chem. 101 (1979) 19-28.
  • H.L. Wang, L.F. Cui, Y.A. Yang, H.S. Casalongue, J.T. Robinson, Y.Y. Liang, Y. Cui, H.J. Dai, J. Am. Chem. Soc., 132 (2010) 13978-13980.
  • G. Jiang, Z. Lin, C. Chen, L. Zhu, Q. Chang, N. Wang, W. Wei, H. Tang, TiO2 nanoparticles assembled on graphene oxide nanosheets with high photocatalytic activity for removal of pollutants, Carbon, 49 (2011) 2693-2701.
  • J. Guo, S. Zhu, Z. Chen, Y. Li, Z. Yu, Q. Liu, J. Li, C. Feng, D. Zhang, Sonochemical synthesis of TiO2 nanoparticles on graphene for use as photocatalyst, Ultrason. Sonochem., 18 (2011) 1082-1090.
  • E. Sumesh, M.S. Bootharaju, A.T. Pradeep, A practical silver nanoparticle-based adsorbent for the removal of Hg2+ from water, J. Hazard. Mater. 189 (2011) 450.
  • C. Gunawan, W.Y. Teoh, C.P. Marquis, J. Lifia and R. Amal, Reversible antimicrobial photoswitching in nanosilver, Small, 5 (2009) 341-344.
  • P. Prieto, V. Nistor, K. Nouneh, M. Oyama, M.A. Lefdil, R. Díaz, XPS study of silver, nickel and bimetallic silver– nickel nanoparticles prepared by seed-mediated growth, Appl. Surf. Sci., 258 (2012) 8807.
Yıl 2018, Cilt: 46 Sayı: 2, 159 - 167, 03.06.2018

Öz

Kaynakça

  • J. Liu, X. Bo, Z. Zhao, L. Guo, Highly exposed Pt nanoparticles supported on porous graphene for electrochemical detection of hydrogen peroxide in living cells, Biosens. Bioelectron., 74 (2015) 71-77.
  • Z. Liu, Y. Guo, C. Dong, A high performance nonenzymatic electrochemical glucose sensor based on polyvinylpyrrolidone–graphene nanosheets–nickel nanoparticles–chitosan nanocomposite, Talanta, 137 (2015) 87-93.
  • G. Giovannetti, P.A. Khomyakov, G. Brocks, V.M. Karpan, J. van den Brink, and P.J. Kelly, Doping Graphene With Metal Contacts, Phys. Rev. Let., 101 (2008) 268031-268034.
  • B. Uchoa, C.Y. Lin, and A.H. Castro Neto, Tailoring graphene with metals on top, Phys. Rev. B, 77 (2008) 035421-035425.
  • G.M. Scheuermann, L. Rumi, P. Steurer, W. Bannwarth, R. Mulhaupt, Palladium nanoparticles on graphite oxide and its functionalized graphene derivatives as highly active catalysts for the Suzuki−Miyaura coupling reaction, J. Am. Chem. Soc., 131, 2009, 8262- 8270.
  • Y. Li, L. Tang, J. Li, Preparation and electrochemical performance for methanol oxidation of pt/graphene nanocomposites, Electrochem. Commun., 11 (2009) 846–849.
  • T. Maiyalagan, X. Dong, P. Chen, X. Wang, Electrodeposited Pt on three-dimensional interconnected graphene as a free-standing electrode for fuel cell application, J. Mater. Chem., 22 (2012) 5286-5290.
  • K.S. Suslick, Ultrasound: Its chemical, physical and biological effects, VCH Verlagsgesellschaft, Weinheim, Germany, 1988.
  • B. Neppolian, C. Wang, Muthupandian Ashokkumar. Sonochemically synthesized mono and bimetallic Au– Ag reduced graphene oxide based nanocomposites with enhanced catalytic activity, Ultrason. Sonochem., 21 (2014) 1948-1953.
  • B. Neppolian, A. Bruno, C.L. Bianchi, M. Ashokkumar, Graphene oxide based Pt–TiO2 photocatalyst: Ultrasound assisted synthesis, characterization and catalytic efficiency, Ultrason. Sonochem., 19 (2012) 9-15.
  • S. Zhu, J. Guo, J. Dong, Zn Cui, T. Lu, C. Zhu, D. Zhang, J. Ma, Sonochemical fabrication of Fe3O4 nanoparticles on reduced graphene oxide for biosensors, Ultrason. Sonochem., 20 (2013) 872-880.
  • L. Zhu, J.D. Chung, W.C. Oh, Rapid sonochemical synthesis of novel PbSe–graphene–TiO2 composite sonocatalysts with enhanced on decolorization performance and generation of ROS, Ultrason. Sonochem., 27 (2015) 252-261.
  • M. Giovanni, H.L. Poh, A. Ambrosi, G. Zhao, Z. Sofer, F. Sanek, B. Khezri, R.D. Webster and M. Pumera, Noble metal (Pd, Ru, Rh, Pt, Au, Ag) doped graphene hybrids for electrocatalysis, Nanoscale, 4 (2012) 5002.
  • E. Laviron, General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems, J. Electroanal. Chem. 101 (1979) 19-28.
  • H.L. Wang, L.F. Cui, Y.A. Yang, H.S. Casalongue, J.T. Robinson, Y.Y. Liang, Y. Cui, H.J. Dai, J. Am. Chem. Soc., 132 (2010) 13978-13980.
  • G. Jiang, Z. Lin, C. Chen, L. Zhu, Q. Chang, N. Wang, W. Wei, H. Tang, TiO2 nanoparticles assembled on graphene oxide nanosheets with high photocatalytic activity for removal of pollutants, Carbon, 49 (2011) 2693-2701.
  • J. Guo, S. Zhu, Z. Chen, Y. Li, Z. Yu, Q. Liu, J. Li, C. Feng, D. Zhang, Sonochemical synthesis of TiO2 nanoparticles on graphene for use as photocatalyst, Ultrason. Sonochem., 18 (2011) 1082-1090.
  • E. Sumesh, M.S. Bootharaju, A.T. Pradeep, A practical silver nanoparticle-based adsorbent for the removal of Hg2+ from water, J. Hazard. Mater. 189 (2011) 450.
  • C. Gunawan, W.Y. Teoh, C.P. Marquis, J. Lifia and R. Amal, Reversible antimicrobial photoswitching in nanosilver, Small, 5 (2009) 341-344.
  • P. Prieto, V. Nistor, K. Nouneh, M. Oyama, M.A. Lefdil, R. Díaz, XPS study of silver, nickel and bimetallic silver– nickel nanoparticles prepared by seed-mediated growth, Appl. Surf. Sci., 258 (2012) 8807.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Articles
Yazarlar

Burak Derkus

Pınar Acar Bozkurt Bu kişi benim

Yayımlanma Tarihi 3 Haziran 2018
Kabul Tarihi 26 Mart 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 46 Sayı: 2

Kaynak Göster

APA Derkus, B., & Bozkurt, P. A. (2018). Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic. Hacettepe Journal of Biology and Chemistry, 46(2), 159-167.
AMA Derkus B, Bozkurt PA. Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic. HJBC. Haziran 2018;46(2):159-167.
Chicago Derkus, Burak, ve Pınar Acar Bozkurt. “Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure As Efficient Peroxidase Mimic”. Hacettepe Journal of Biology and Chemistry 46, sy. 2 (Haziran 2018): 159-67.
EndNote Derkus B, Bozkurt PA (01 Haziran 2018) Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic. Hacettepe Journal of Biology and Chemistry 46 2 159–167.
IEEE B. Derkus ve P. A. Bozkurt, “Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic”, HJBC, c. 46, sy. 2, ss. 159–167, 2018.
ISNAD Derkus, Burak - Bozkurt, Pınar Acar. “Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure As Efficient Peroxidase Mimic”. Hacettepe Journal of Biology and Chemistry 46/2 (Haziran 2018), 159-167.
JAMA Derkus B, Bozkurt PA. Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic. HJBC. 2018;46:159–167.
MLA Derkus, Burak ve Pınar Acar Bozkurt. “Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure As Efficient Peroxidase Mimic”. Hacettepe Journal of Biology and Chemistry, c. 46, sy. 2, 2018, ss. 159-67.
Vancouver Derkus B, Bozkurt PA. Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic. HJBC. 2018;46(2):159-67.

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