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Photochemical Reaction of Metal Carbonyls [M(CO)6 (M=Cr,Mo,W)] with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone

Yıl 2019, Cilt: 2 Sayı: 1, 27 - 31, 30.06.2019
https://doi.org/10.38061/idunas.463196

Öz



The new complexes, [M(CO)5(msh4)]
(Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of
metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes
has been investigated by using elemental analyses; FT-IR; EI-MS and 1H
NMR spectrometric methods. According to all spectroscopic data, msh4 is
monodaentate and coordinate via thiophene ring sulfur.



Kaynakça

  • G.Domagk, Deut. Med. Wochenschr. 61(1935) 250.
  • G.I.Mandell, W.A.Petri, J.G.Hardman, L.E.Limbird, P.B.Molinoff, R.W.Ruddon, A.G.Gilman, Goodman’s the Pharmacological Basis of Therapeutics, 9th ed.,McGraw-Hill, New York, 1996.
  • N.R.Lomax , LV.L.Narayanan, Chemical Structures of Interest to the Division of Cancer Treatment, Vol. VI, Developmental Therapeutics Program, National Cancer Institue, Bethesda,MD, p.32(1988).
  • P.B.Jensen, B.S.Soerensen, J.F.E.Demant, M.Sehested, P.S.Jensen, L.H.Vindeloey, H.H.Hansen, Cancer Res., 50, 3311(1990).
  • G.J.Finlay, B.C.Baguley, K.Snow, W.Judd, J.NATL.Cancer Inst., 82, 662(1990).
  • S.Topiol, M.Sabio, P.W.Erhardt, J.Chem.Soc., Perkin Trans., 2, 437(1998).
  • H.Rutner, N.Lewin, E.C.Woodbury, T.J.McBride, K.V.Rao. Cancer Chemother.Rep., Part 1,58, 803 (1974).
  • A.Lenco, C.Mealli, P.Paoli, N.Dodoff, Z.Kantarcı, N.Karacan, New J. Chem.,23, 1253(1999).
  • M.A. Reynolds, A.A. Guzei, B.C. Logsdon, L.M. Thomas, R.A. Jacobson, R.J. Angelici. Organometallics, 18, 4075 (1999).
  • G.Orhan, O.S.Şentürk, Ü.Ö.Özmen, S.Sert, E.Subaşı, J.of Coor. Chem., 64, 19 (2014).
  • D.D.Perrin, W.F.F.Armarego, D.R.Perrin, Purification of Laboratory Chemicals, Pergamon Press, Oxford (1980).
  • N.I.Dodoff, Ü.Özdemir, N.Karacan, M.Georgieva, S.M.Konstantinov, M.E.Stefanova, Z.Naturforsch, 54b, 1553(1999).
  • K. Hanai, T. Okuda, T. Uno, K. Machida. Spectrochim. Acta, 31, 1217 (1975).
  • A.R. Katritzky, R.A. Jones. J. Chem. Soc., 4497 (1960).
  • N. Bacon, A.J. Boulton, R.T.C. Brownlee, A.R. Katritzky, R.D. Topsom. J. Chem. Soc., 5230 (1965).
  • Y. Tanaka, Y. Tanaka. Chem. Pharm. Bull., 13, 858 (1965).
  • K. Hanai, A. Noguchi, T. Okuda. Spectrochim. Acta, 34, 771 (1978).
  • Ü. Özdemir, O.S. Sentürk, S. Sert, N. Karacan, F. Uğur. Transit. Met. Chem., 28, 443 (2003).
  • Ü.Ö. Özdemir, N. Akkaya, N. Özbek. Inorg. Chim. Acta, 400, 13 (2013).
  • R.J.W. Cremlyn, D.N. Waters. J. Chem Soc., suppl. 2, 6243 (1964).
  • R.D. McLachlan, V.B. Carter. Spectrochim. Acta, 26, 1121 (1970).
  • T. Uno, K. Machida, K. Hanai. Spectrochim. Acta, 27, 107 (1971).
  • G. Geiseler, G. Hanschmann. J. Mol. Struct., 8, 293 (1971).
  • G. Chassaing, J. Corset, J. Limouzi. Spectrochim Acta, 37, 721 (1981).
  • P. Teyssie, J.J. Charette. Spectrochim. Acta, 19, 1407 (1963).
  • J.A. Faniran, K.S. Patel, J.C. Bailar Jr. J. Inorg. Nucl. Chem., 36, 1547 (1974).
  • L.I. Kozhevina, E.B. Prokopenko, V.I. Rybachenko, E.V. Titov. Zh. Prikl. Spektrosk., 59, 440 (1993).
  • V.I. Tsapkov, N.M. Samus’. Zh. Obshch. Khim., 67, 1422 (1997).
  • P. Mills, S. Korlann, M.E. Bussell, M.A. Reynolds, M.V. Ovchinnikov, R.J. Angelici, C. Stinner, T. Weber, R. Prins. J. Phys. Chem. A, 105, 4418 (2001).
  • C.Kumar, C.Parlak, H.Fun, M.Tursun, G.Keşan, S.Chandraju, C.K.Quah, Spectrochim.Acta Part A:Molecular and Biomolecular Spectroscopy 127,67 (2014).
  • P. Mills, S. Korlann, M.E. Bussell, M.A. Reynolds, M.V. Ovchinnikov, R.J. Angelici, C. Stinner, T. Weber, R. Prins. J. Phys. Chem., 105, 4418 (2001).
  • C. Spinu, A. Kriza. Acta Chim. Slov., 47, 179 (2000).
  • F. Sarıkahya, O.S. Şentürk. Syn. React. Inorg. Met., 31, 1843 (2001).

Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone

Yıl 2019, Cilt: 2 Sayı: 1, 27 - 31, 30.06.2019
https://doi.org/10.38061/idunas.463196

Öz

The new complexes, [M(CO)5(msh4)] (Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur.

Kaynakça

  • G.Domagk, Deut. Med. Wochenschr. 61(1935) 250.
  • G.I.Mandell, W.A.Petri, J.G.Hardman, L.E.Limbird, P.B.Molinoff, R.W.Ruddon, A.G.Gilman, Goodman’s the Pharmacological Basis of Therapeutics, 9th ed.,McGraw-Hill, New York, 1996.
  • N.R.Lomax , LV.L.Narayanan, Chemical Structures of Interest to the Division of Cancer Treatment, Vol. VI, Developmental Therapeutics Program, National Cancer Institue, Bethesda,MD, p.32(1988).
  • P.B.Jensen, B.S.Soerensen, J.F.E.Demant, M.Sehested, P.S.Jensen, L.H.Vindeloey, H.H.Hansen, Cancer Res., 50, 3311(1990).
  • G.J.Finlay, B.C.Baguley, K.Snow, W.Judd, J.NATL.Cancer Inst., 82, 662(1990).
  • S.Topiol, M.Sabio, P.W.Erhardt, J.Chem.Soc., Perkin Trans., 2, 437(1998).
  • H.Rutner, N.Lewin, E.C.Woodbury, T.J.McBride, K.V.Rao. Cancer Chemother.Rep., Part 1,58, 803 (1974).
  • A.Lenco, C.Mealli, P.Paoli, N.Dodoff, Z.Kantarcı, N.Karacan, New J. Chem.,23, 1253(1999).
  • M.A. Reynolds, A.A. Guzei, B.C. Logsdon, L.M. Thomas, R.A. Jacobson, R.J. Angelici. Organometallics, 18, 4075 (1999).
  • G.Orhan, O.S.Şentürk, Ü.Ö.Özmen, S.Sert, E.Subaşı, J.of Coor. Chem., 64, 19 (2014).
  • D.D.Perrin, W.F.F.Armarego, D.R.Perrin, Purification of Laboratory Chemicals, Pergamon Press, Oxford (1980).
  • N.I.Dodoff, Ü.Özdemir, N.Karacan, M.Georgieva, S.M.Konstantinov, M.E.Stefanova, Z.Naturforsch, 54b, 1553(1999).
  • K. Hanai, T. Okuda, T. Uno, K. Machida. Spectrochim. Acta, 31, 1217 (1975).
  • A.R. Katritzky, R.A. Jones. J. Chem. Soc., 4497 (1960).
  • N. Bacon, A.J. Boulton, R.T.C. Brownlee, A.R. Katritzky, R.D. Topsom. J. Chem. Soc., 5230 (1965).
  • Y. Tanaka, Y. Tanaka. Chem. Pharm. Bull., 13, 858 (1965).
  • K. Hanai, A. Noguchi, T. Okuda. Spectrochim. Acta, 34, 771 (1978).
  • Ü. Özdemir, O.S. Sentürk, S. Sert, N. Karacan, F. Uğur. Transit. Met. Chem., 28, 443 (2003).
  • Ü.Ö. Özdemir, N. Akkaya, N. Özbek. Inorg. Chim. Acta, 400, 13 (2013).
  • R.J.W. Cremlyn, D.N. Waters. J. Chem Soc., suppl. 2, 6243 (1964).
  • R.D. McLachlan, V.B. Carter. Spectrochim. Acta, 26, 1121 (1970).
  • T. Uno, K. Machida, K. Hanai. Spectrochim. Acta, 27, 107 (1971).
  • G. Geiseler, G. Hanschmann. J. Mol. Struct., 8, 293 (1971).
  • G. Chassaing, J. Corset, J. Limouzi. Spectrochim Acta, 37, 721 (1981).
  • P. Teyssie, J.J. Charette. Spectrochim. Acta, 19, 1407 (1963).
  • J.A. Faniran, K.S. Patel, J.C. Bailar Jr. J. Inorg. Nucl. Chem., 36, 1547 (1974).
  • L.I. Kozhevina, E.B. Prokopenko, V.I. Rybachenko, E.V. Titov. Zh. Prikl. Spektrosk., 59, 440 (1993).
  • V.I. Tsapkov, N.M. Samus’. Zh. Obshch. Khim., 67, 1422 (1997).
  • P. Mills, S. Korlann, M.E. Bussell, M.A. Reynolds, M.V. Ovchinnikov, R.J. Angelici, C. Stinner, T. Weber, R. Prins. J. Phys. Chem. A, 105, 4418 (2001).
  • C.Kumar, C.Parlak, H.Fun, M.Tursun, G.Keşan, S.Chandraju, C.K.Quah, Spectrochim.Acta Part A:Molecular and Biomolecular Spectroscopy 127,67 (2014).
  • P. Mills, S. Korlann, M.E. Bussell, M.A. Reynolds, M.V. Ovchinnikov, R.J. Angelici, C. Stinner, T. Weber, R. Prins. J. Phys. Chem., 105, 4418 (2001).
  • C. Spinu, A. Kriza. Acta Chim. Slov., 47, 179 (2000).
  • F. Sarıkahya, O.S. Şentürk. Syn. React. Inorg. Met., 31, 1843 (2001).
Toplam 33 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya Mühendisliği
Bölüm Makaleler
Yazarlar

Sema Sert

Yayımlanma Tarihi 30 Haziran 2019
Kabul Tarihi 28 Kasım 2018
Yayımlandığı Sayı Yıl 2019 Cilt: 2 Sayı: 1

Kaynak Göster

APA Sert, S. (2019). Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone. Natural and Applied Sciences Journal, 2(1), 27-31. https://doi.org/10.38061/idunas.463196