Year 2016, Volume 19, Issue 4, Pages 244 - 250 2016-12-01

Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA)

Miguel Iglesias [1] , Carolina Ravazzano [2] , Karine Lima [3] , Rebecca S. Andrade [4]

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Ionic liquids are being studied extensively in the last few years, due to their amazing properties and potential industrial applications. Despite this effort, a considerable gap of knowledge is noted in terms of thermodynamic information related to the temperature effect on mixing trend. In this work, a binary mixture of protic ionic liquids comprising formate and acetate anions and 2-hydroxy ethyl ammonium and 2-hydroxy diethyl ammonium cations have been studied in terms of volumetric and acoustic properties as a function of temperature. The measured properties (density and ultrasonic velocity) were correlated to polynomial expansions. The corresponding derived properties (excess molar volumes and change of isentropic compressibilities) have been computed from the experimental data and fitted to a Redlich-Kister temperature dependent expression. The new experimental data were used to test the prediction capability of different procedures for density (Mchaweh-Nasrifar-Moshfeghian (MNM) model) and ultrasonic velocity (Collision Factor Theory (CFT)).
Derived magnitudes, Protic ionic liquid; Theoretical models; Temperature.
Journal Section Regular Original Research Article
Authors

Author: Miguel Iglesias

Author: Carolina Ravazzano

Author: Karine Lima

Author: Rebecca S. Andrade

Dates

Publication Date: December 1, 2016

Bibtex @ { ijot277775, journal = {International Journal of Thermodynamics}, issn = {1301-9724}, eissn = {2146-1511}, address = {Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi}, year = {2016}, volume = {19}, pages = {244 - 250}, doi = {10.5541/eoguijt.277775}, title = {Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA)}, key = {cite}, author = {Iglesias, Miguel and Ravazzano, Carolina and Lima, Karine and Andrade, Rebecca S.} }
APA Iglesias, M , Ravazzano, C , Lima, K , Andrade, R . (2016). Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA). International Journal of Thermodynamics, 19 (4), 244-250. Retrieved from http://dergipark.org.tr/ijot/issue/26363/277775
MLA Iglesias, M , Ravazzano, C , Lima, K , Andrade, R . "Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA)". International Journal of Thermodynamics 19 (2016): 244-250 <http://dergipark.org.tr/ijot/issue/26363/277775>
Chicago Iglesias, M , Ravazzano, C , Lima, K , Andrade, R . "Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA)". International Journal of Thermodynamics 19 (2016): 244-250
RIS TY - JOUR T1 - Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA) AU - Miguel Iglesias , Carolina Ravazzano , Karine Lima , Rebecca S. Andrade Y1 - 2016 PY - 2016 N1 - DO - T2 - International Journal of Thermodynamics JF - Journal JO - JOR SP - 244 EP - 250 VL - 19 IS - 4 SN - 1301-9724-2146-1511 M3 - UR - Y2 - 2019 ER -
EndNote %0 International Journal of Thermodynamics Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA) %A Miguel Iglesias , Carolina Ravazzano , Karine Lima , Rebecca S. Andrade %T Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA) %D 2016 %J International Journal of Thermodynamics %P 1301-9724-2146-1511 %V 19 %N 4 %R %U
ISNAD Iglesias, Miguel , Ravazzano, Carolina , Lima, Karine , Andrade, Rebecca S. . "Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA)". International Journal of Thermodynamics 19 / 4 (December 2016): 244-250.
AMA Iglesias M , Ravazzano C , Lima K , Andrade R . Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA). International Journal of Thermodynamics. 2016; 19(4): 244-250.
Vancouver Iglesias M , Ravazzano C , Lima K , Andrade R . Thermodynamic Study of a Short Protic Ionic Liquids Binary Mixture: 2-Hydroxy Ethyl Ammonium Formate (2-HEAF) + 2-Hydroxy Diethyl Ammonium Acetate (2-HDEAA). International Journal of Thermodynamics. 2016; 19(4): 250-244.