Year 2016, Volume 3, Issue 2, Pages 183 - 205 2016-06-29

STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES

Mehtap Şafak Boroğlu [1]

837 617

In this study, the preparation of polyetherimide (PEI-Ultem1000)/ZIF-11 mixed matrix membranes was studied in various ZIF-11 nanoparticles loadings (0, 10, 15, 20, and 30 wt.%). The newly synthesized ZIF-11 nanoparticles with an average particle size of ~280 nm were integrated in PEI membranes as novel mixed matrix membranes (MMMs). The effect of ZIF-11 loading was scrutinised for H2, CO2, and CH4 gas separation performance at 35 °C and 4 bar. The incorporation of ZIF-11 nanoparticles improved the gas permeation properties of the MMMs with an increase in ZIF-11 loading. As the ZIF-11 loading increased up to 20 wt.%, the permeability of H2 and CO2 increased to four times higher than that of the pure polymer. Moderate increase of CH4 permeability was also recorded. At higher loadings above 20 wt.%, the permeability decreased for all gases and the CO2/CH4, and H2/CH4 selectivities increased consistent with the ZIF-11 loading.

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Journal Section Articles
Authors

Author: Mehtap Şafak Boroğlu

Dates

Publication Date: June 29, 2016

Bibtex @ { jotcsa260525, journal = {Journal of the Turkish Chemical Society Section A: Chemistry}, issn = {}, eissn = {2149-0120}, address = {Turkish Chemical Society}, year = {2016}, volume = {3}, pages = {183 - 205}, doi = {10.18596/jotcsa.62047}, title = {STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES}, key = {cite}, author = {Şafak Boroğlu, Mehtap} }
APA Şafak Boroğlu, M . (2016). STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES. Journal of the Turkish Chemical Society Section A: Chemistry, 3 (2), 183-205. DOI: 10.18596/jotcsa.62047
MLA Şafak Boroğlu, M . "STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES". Journal of the Turkish Chemical Society Section A: Chemistry 3 (2016): 183-205 <http://dergipark.org.tr/jotcsa/issue/24619/260525?publisher=turchemsoc?publisher=turchemsoc>
Chicago Şafak Boroğlu, M . "STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES". Journal of the Turkish Chemical Society Section A: Chemistry 3 (2016): 183-205
RIS TY - JOUR T1 - STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES AU - Mehtap Şafak Boroğlu Y1 - 2016 PY - 2016 N1 - doi: 10.18596/jotcsa.62047 DO - 10.18596/jotcsa.62047 T2 - Journal of the Turkish Chemical Society Section A: Chemistry JF - Journal JO - JOR SP - 183 EP - 205 VL - 3 IS - 2 SN - -2149-0120 M3 - doi: 10.18596/jotcsa.62047 UR - https://doi.org/10.18596/jotcsa.62047 Y2 - 2019 ER -
EndNote %0 Journal of the Turkish Chemical Society Section A: Chemistry STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES %A Mehtap Şafak Boroğlu %T STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES %D 2016 %J Journal of the Turkish Chemical Society Section A: Chemistry %P -2149-0120 %V 3 %N 2 %R doi: 10.18596/jotcsa.62047 %U 10.18596/jotcsa.62047
ISNAD Şafak Boroğlu, Mehtap . "STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES". Journal of the Turkish Chemical Society Section A: Chemistry 3 / 2 (June 2016): 183-205. https://doi.org/10.18596/jotcsa.62047
AMA Şafak Boroğlu M . STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES. JOTCSA. 2016; 3(2): 183-205.
Vancouver Şafak Boroğlu M . STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI)/ZEOLITIC IMIDAZOLATE (ZIF-11) MIXED MATRIX MEMBRANES. Journal of the Turkish Chemical Society Section A: Chemistry. 2016; 3(2): 205-183.