Volatile Constituents of Three Stachys L. Species from Turkey

Abstract

Volatile compounds of three Stachys species; Stachys macrantha

(C. Koch) Stearn, Stachys sylvatica L. and Stachys annua ssp.

annua var. annua L. were analyzed by a solid phase micro

extraction (SPME) method coupled with gas chromatographyflame

ionization detector (GC–FID) and gas chromatographymass

spectrometry (GC-MS). A total of 38 (99.2%), 39 (99.0%)

and 33 (98.8%) volatile compounds were identified from S.

annua ssp. annua var. annua, S. sylvatica and S. macrantha

respectively. The major volatile constituents of the investigated

three Stachys species were; α-pinene (11.2%), p-cymene (18.2%),

and carvacrol (28.8%) in S. macrantha, γ-muurolene (10.2%),

α-cedrene (11.2%), and limonene (37.0%) in S. sylvatica and

α-pinene (11,4%), β-pinene (23.1%), and (Z)-β-ocimene

(24.8%) in S. annua ssp. annua var. annua. Comparison of

volatile organic compounds of all three species showed that

monoterpene hydrocarbons were the major constituents in S.

annua ssp. annua var. annua and S. sylvatica (65.8% and 49.8%

respectively), whereas oxygenated monoterpenes were the main

components (42.1%) of S. macrantha.

Keywords

• Stachys macrantha,Stachys sylvatica,Stachys annua ssp. annua var. annua,Lamiaceae,volatile compounds,SPME

Türkiye’den Üç Stachys L. Türünün Uçucu Bileşenleri

Abstract

Stachys macrantha (C. Koch) Stearn, Stachys sylvatica L. ve

Stachys annua ssp. annua var. annua L. türlerine ait uçucu

bileşenler Katı Faz Mikro Ekstraksiyon (SPME) metoduna

ek olarak Alev İyonizasyon Dedektörü (GC-FID) ve Gaz

Kromotografisi-Kütle Spektrometresi (GC-MS) ile analiz edildi.

S. annua ssp. annua var. annua, S. sylvatica ve S. macrantha

türlerinde sırasıyla toplam 38 (%99.2), 39 (%99.0) ve 33 (%98.8)

uçucu bileşen tanımlandı. İncelenen bu üç türdeki major uçucu

bileşenler S. macrantha türünde α-pinen (%11.2), p-simen

(%18.2) ve karvakrol (%28.8), S. sylvatica’da γ-muurolen

(%10.2), α-sedren (%11.2) ve limonen (%37.0) ve S. annua

ssp. annua var. annua’da α-pinen (%11.4), β-pinen (%23.1)

ve (Z)-β-osimen (%24.8) olarak bulundu. Türler üzerinde

yapılan karşılaştırma çalışması S. annua ssp. annua var.

annua ve S. sylvatica türlerinin ana monoterpen hidrokarbon

yapısında olduğunu bileşenlerinin (sırasıyla %65.8 ve %49.8)

ve S. macrantha’nın ana bileşenlerinin ise oksijenlenmiş

monoterpenler (%42.1) olduğunu gösterdi.

Keywords

• Stachys macrantha,Stachys sylvatica,Stachys annua ssp. annua var. annua,Lamiaceae,uçucu bileşikler,SPME

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