EQUILIBRIUM STUDIES ON Ni(II) and Cu(II) COMPLEXES with 4,7- DIMETHYL-1,10-PHENANTHROLINE and ACIDIC AMINO ACIDS in AQUEOUS SOLUTION

Duygu İnci

doi:10.18596/jotcsa.757923

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Kaynak Göster

EQUILIBRIUM STUDIES ON Ni(II) and Cu(II) COMPLEXES with 4,7- DIMETHYL-1,10-PHENANTHROLINE and ACIDIC AMINO ACIDS in AQUEOUS SOLUTION

Yıl 2020, Cilt: 7 Sayı: 3, 775 - 788, 30.10.2020

Duygu İnci

https://doi.org/10.18596/jotcsa.757923

Cited By: 1

Öz

The aim of this studies are to determine protonation constants of selected ligands {4,7-dimethyl-1,10-phenanthroline (4,7-dmphen), aspartic acid (asp) and glutamic acid (glu)} and their stability constants of (1:1) and (1:1:1) complexes with Ni(II) and Cu(II) ion were determined I = 0.1 M KCl and T = 298.15 K. The protonation constants of the 4,7-dmphen, asp and glu and their stability constants of the (1:1) and (1:1:1) Ni(II) and Cu(II) complexes were computed performing BEST program. Moreover, SPE program was used to determine the distribution of the species occured in aqueous solution medium. The stability constants of the (1:1:1) Ni(II) and Cu(II) complexes are compared with those of the corresponding the stability of the (1:1) Ni(II) and Cu(II) complexes with regard to Δlog K values.

Anahtar Kelimeler

Nickel(II), copper(II), 4.7-dimethyl-1.10-phenanthroline, acidic amino acids, stability constants, potentiometric methods

Teşekkür

The author would like to thank Prof. Dr. Rahmiye AYDIN for allowing me to use the facilities at the Inorganic Chemistry Laboratory to conduct in this study.

Kaynakça

1. Nair MS, Neelakantan MA, Sunu SS. Potentiometric stugy of the multiple equilibria in nickel (II) and copper (II) mixed ligand complexes containing nicotinic acid and imidazoles. IJC-A Vol38A(12) [December 1999] [Internet]. Available: http://nopr.niscair.res.in/handle/123456789/16138
2. Nakon R, Rechani PR, Angelici RJ. Copper(II) complex catalysis of amino acid ester hydrolysis. A correlation with complex stability. J Am Chem Soc. 1974;96(7):2117-20.
3. Ullah MR, Bhattacharya PK. Study of the effect of nature of ligand on reproportionation constants of ternary complexes. Proc Indian Acad Sci Chem Sci. 1990:102(4):513-19.
4. Reddy PR, Rao KS. Ternary nickel(II) complexes as hydrolytic DNA-cleavage agents. Chem Biodivers. 2006;3(2):231-44.
5. Wyatt KS, Harrison KN, Jensen CM. Release of platinum from cysteine residues induced by N,S-donor chelation. Inorg Chem. 1992;31(18):3867-8.
6. İnci D, Aydın R. Structures, hydrolysis, stabilities of palladium(II) complexes containing biologically active ligands and species distribution in aqueous solution. Journal of Molecular Structure. 2019;1187:23-37.
7. İnci D, Aydın R. Stabilities of the Ternary Complexes of Copper(II) with Substituted 1,10-Phenanthrolines and Some Amino Acids in Aqueous Solution. J Solution Chem. 2014;43(4):711-26.
8. İnci D, Aydın R. Potentiometric Studies on Complexation of Cu(II) Ion with Methyl/Nitro-Substituted 1,10-Phenanthrolines and Selected Amino Acids. J Solution Chem. 2017;46(1):124-38.
9. Şenel P, Inci D, Aydın R. Temperature and methyl substitution effect on copper(II) complexes with biorelevant ligands and species distribution in aqueous solution. Physics and Chemistry of Liquids. 2019;1-15.
10. Kiraz S, İnci D, Aydın R, Vatan Ö, Zorlu Y, Cavaş T. Antiproliferative activity of copper(II) glutamine complexes with N,N-donor ligands: Synthesis, characterization, potentiometric studies and DNA/BSA interactions. Journal of Molecular Structure. 2019;1194:245-55.
11. Aydin R, Yirikogullari A. Potentiometric Study on Complexation of Divalent Transition Metal Ions with Amino Acids and Adenosine 5′-Triphosphate. J Chem Eng Data. 2010;55(11):4794-800.
12. Martell AE, 1916-, Motekaitis RJ. Determination and use of stability constants [Internet]. VCH Publishers; 1992. Available: https://agris.fao.org/agris-search/search.do?recordID=US201300727267
13. Brisbin DA, Mcbryde WAE. THE stability of metallic complexes of two dimethylphenanthrolines. Can J Chem. 1963;41(5):1135-41.
14. Yasuda M, Sone K, Yamasaki K. Stability of Zinc and Cadmium Complexes with Some Methyl Derivatives of 1,10-Phenanthroline and 2,2′-Bipyridine. J Phys Chem. 1956;60(12):1667-8.
15. Makar GKR, Touche MLD, Williams DR. Thermodynamic considerations in co-ordination. Part XXIII. Formation constants for complexes of protons, zinc(II), and acid anions and their use in computer evaluation of a better zinc therapeutical. J Chem Soc, Dalton Trans. 1976;(11):1016-9.
16. Boraei AAA, Ibrahim SA, Mohamed AH. Solution Equilibria of Binary and Ternary Systems Involving Transition Metal Ions, Adenosine 5‘-Triphosphate, and Amino Acids. J Chem Eng Data. 1999;44(5):907-11.
17. Erçag A, Sismanoglu T, Pura S. Thermodynamics of binary and ternary complexes of 3-amino-1, 2, 4-triazole and aminoacids with Ni(II) and Co(II) metal ions. Journal of the Serbian Chemical Society. 2005;70(8-9):1057-66.
18. Shoukry MM, Shehata MR, Mohamed MMA. Binary and ternary complexes of Cd(II) involving triethylenetetramine and selected amino acids and DNA units. Mikrochim Acta. 1998;129(1):107-13.
19. Abdel Gaber AA, Farghaly OA, Ghandour MA, El-Said HS. Potentiometric Studies on SomeCephalosporin Complexes. Monatshefte für Chemie. 2000;131(10):1031-8.
20. Chikira M, Tomizawa Y, Fukita D, Sugizaki T, Sugawara N, Yamazaki T, vd. DNA-fiber EPR study of the orientation of Cu(II) complexes of 1,10-phenanthroline and its derivatives bound to DNA: mono(phenanthroline)-copper(II) and its ternary complexes with amino acids. Journal of Inorganic Biochemistry. 2002;89(3):163-73.
21. Su C-C, Tai T-Y, Wu S-P, Wang S-L, Liao F-L. Spectroscopic and electronic properties of mixed ligand aminoacidatocopper(II) complexes: Molecular structure of [Cu(4,7-dimethyl-1,10-phenanthroline)(l-phenylalaninato)](ClO4). Polyhedron. 1999;18(18):2361-8.
22. Kamecka A, Kurzak B. Review: Solution equilibria of ternary complexes formed from copper(II), aliphatic amines, and bioligands. Journal of Coordination Chemistry. 2014;67(15):2497-529.

Yıl 2020, Cilt: 7 Sayı: 3, 775 - 788, 30.10.2020

Duygu İnci

https://doi.org/10.18596/jotcsa.757923

Cited By: 1

Öz

Kaynakça

1. Nair MS, Neelakantan MA, Sunu SS. Potentiometric stugy of the multiple equilibria in nickel (II) and copper (II) mixed ligand complexes containing nicotinic acid and imidazoles. IJC-A Vol38A(12) [December 1999] [Internet]. Available: http://nopr.niscair.res.in/handle/123456789/16138
2. Nakon R, Rechani PR, Angelici RJ. Copper(II) complex catalysis of amino acid ester hydrolysis. A correlation with complex stability. J Am Chem Soc. 1974;96(7):2117-20.
3. Ullah MR, Bhattacharya PK. Study of the effect of nature of ligand on reproportionation constants of ternary complexes. Proc Indian Acad Sci Chem Sci. 1990:102(4):513-19.
4. Reddy PR, Rao KS. Ternary nickel(II) complexes as hydrolytic DNA-cleavage agents. Chem Biodivers. 2006;3(2):231-44.
5. Wyatt KS, Harrison KN, Jensen CM. Release of platinum from cysteine residues induced by N,S-donor chelation. Inorg Chem. 1992;31(18):3867-8.
6. İnci D, Aydın R. Structures, hydrolysis, stabilities of palladium(II) complexes containing biologically active ligands and species distribution in aqueous solution. Journal of Molecular Structure. 2019;1187:23-37.
7. İnci D, Aydın R. Stabilities of the Ternary Complexes of Copper(II) with Substituted 1,10-Phenanthrolines and Some Amino Acids in Aqueous Solution. J Solution Chem. 2014;43(4):711-26.
8. İnci D, Aydın R. Potentiometric Studies on Complexation of Cu(II) Ion with Methyl/Nitro-Substituted 1,10-Phenanthrolines and Selected Amino Acids. J Solution Chem. 2017;46(1):124-38.
9. Şenel P, Inci D, Aydın R. Temperature and methyl substitution effect on copper(II) complexes with biorelevant ligands and species distribution in aqueous solution. Physics and Chemistry of Liquids. 2019;1-15.
10. Kiraz S, İnci D, Aydın R, Vatan Ö, Zorlu Y, Cavaş T. Antiproliferative activity of copper(II) glutamine complexes with N,N-donor ligands: Synthesis, characterization, potentiometric studies and DNA/BSA interactions. Journal of Molecular Structure. 2019;1194:245-55.
11. Aydin R, Yirikogullari A. Potentiometric Study on Complexation of Divalent Transition Metal Ions with Amino Acids and Adenosine 5′-Triphosphate. J Chem Eng Data. 2010;55(11):4794-800.
12. Martell AE, 1916-, Motekaitis RJ. Determination and use of stability constants [Internet]. VCH Publishers; 1992. Available: https://agris.fao.org/agris-search/search.do?recordID=US201300727267
13. Brisbin DA, Mcbryde WAE. THE stability of metallic complexes of two dimethylphenanthrolines. Can J Chem. 1963;41(5):1135-41.
14. Yasuda M, Sone K, Yamasaki K. Stability of Zinc and Cadmium Complexes with Some Methyl Derivatives of 1,10-Phenanthroline and 2,2′-Bipyridine. J Phys Chem. 1956;60(12):1667-8.
15. Makar GKR, Touche MLD, Williams DR. Thermodynamic considerations in co-ordination. Part XXIII. Formation constants for complexes of protons, zinc(II), and acid anions and their use in computer evaluation of a better zinc therapeutical. J Chem Soc, Dalton Trans. 1976;(11):1016-9.
16. Boraei AAA, Ibrahim SA, Mohamed AH. Solution Equilibria of Binary and Ternary Systems Involving Transition Metal Ions, Adenosine 5‘-Triphosphate, and Amino Acids. J Chem Eng Data. 1999;44(5):907-11.
17. Erçag A, Sismanoglu T, Pura S. Thermodynamics of binary and ternary complexes of 3-amino-1, 2, 4-triazole and aminoacids with Ni(II) and Co(II) metal ions. Journal of the Serbian Chemical Society. 2005;70(8-9):1057-66.
18. Shoukry MM, Shehata MR, Mohamed MMA. Binary and ternary complexes of Cd(II) involving triethylenetetramine and selected amino acids and DNA units. Mikrochim Acta. 1998;129(1):107-13.
19. Abdel Gaber AA, Farghaly OA, Ghandour MA, El-Said HS. Potentiometric Studies on SomeCephalosporin Complexes. Monatshefte für Chemie. 2000;131(10):1031-8.
20. Chikira M, Tomizawa Y, Fukita D, Sugizaki T, Sugawara N, Yamazaki T, vd. DNA-fiber EPR study of the orientation of Cu(II) complexes of 1,10-phenanthroline and its derivatives bound to DNA: mono(phenanthroline)-copper(II) and its ternary complexes with amino acids. Journal of Inorganic Biochemistry. 2002;89(3):163-73.
21. Su C-C, Tai T-Y, Wu S-P, Wang S-L, Liao F-L. Spectroscopic and electronic properties of mixed ligand aminoacidatocopper(II) complexes: Molecular structure of [Cu(4,7-dimethyl-1,10-phenanthroline)(l-phenylalaninato)](ClO4). Polyhedron. 1999;18(18):2361-8.
22. Kamecka A, Kurzak B. Review: Solution equilibria of ternary complexes formed from copper(II), aliphatic amines, and bioligands. Journal of Coordination Chemistry. 2014;67(15):2497-529.

Toplam 22 adet kaynakça vardır.

Ayrıntılar

Birincil Dil	İngilizce
Konular	İnorganik Kimya
Bölüm	Makaleler
Yazarlar	Duygu İnci 0000-0002-0483-9642
Yayımlanma Tarihi	30 Ekim 2020
Gönderilme Tarihi	25 Haziran 2020
Kabul Tarihi	25 Ağustos 2020
Yayımlandığı Sayı	Yıl 2020 Cilt: 7 Sayı: 3

Kaynak Göster

Vancouver	İnci D. EQUILIBRIUM STUDIES ON Ni(II) and Cu(II) COMPLEXES with 4,7- DIMETHYL-1,10-PHENANTHROLINE and ACIDIC AMINO ACIDS in AQUEOUS SOLUTION. JOTCSA. 2020;7(3):775-88.

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Synthesis and Determination of Acid Dissociation Constants of Bis-Acyl Thiourea Derivatives

Journal of the Turkish Chemical Society Section A: Chemistry

https://doi.org/10.18596/jotcsa.1269213

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