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B4C takviyeli alüminyum matris kompozitlerin farklı çözeltilerdeki korozyon davranışları

Yıl 2020, Cilt: 5 Sayı: 1, 23 - 28, 29.03.2020

İjlal Şimşek Doğan Şimşek Dursun Özyürek

https://doi.org/10.30728/boron.659969

Öz

Bu çalışmada mekanik alaşımlama yöntemi ile üretilen %12 B4C takviyeli Al %2 grafit matrisli kompozit malzemenin farklı çözeltilerdeki korozyon davranışı incelenmiştir. Hazırlanan tozlar planeter tip alaşımlama cihazında mekanik alaşımlanmıştır. Mekanik alaşımlanan tozlar, hidrolik preste 750 MPa basınç altında soğuk preslenerek ham numuneler üretilmiştir. Üretilen ham numuneler 600°C sıcaklıkta 2 saat sinterlenmiştir. Korozyon testleri iki farklı çözeltide (%3,5 NaCl ve 0,1 M H2SO4) potansiyodinamik polarizasyon yöntemi ile yapılmıştır. Korozyon testleri sonucunda, NaCl çözeltisinde H2SO4 çözeltisine göre düşük akım yoğunluğu elde edilmiştir. Ayrıca elektrokimyasal empedans ölçümlerinde H2SO4 çözeltisi içerisinde, Nyquist eğrisinin daha düşük bir yarım daire çapına ve düşük frekanslarda endüktif bir döngüye sahip olduğu görülmüştür.

Anahtar Kelimeler

Al kompozit B4C Empedans Korozyon

Kaynakça

  • [1] Nie J., Wang F., Chen Y., Mao Q., Yang H., Song Z., Liu X., Zhao Y., Microstructure and corrosion behavior of Al-TiB2/TiC composites processed by hot rolling, Results in Phys., 14, 1-7, 2019.
  • [2] Alaneme K. K., Adewale T.M., Olubambi P. A., Corrosion and wear behaviour of Al–Mg–Si alloy matrix hybrid composites reinforced with rice husk ash and silicon carbide, J. Mater. Res. Technol., 3 (1), 9-16, 2014.
  • [3] Fattah-alhosseini A., Naser M., Alemi M. H., Corrosion behavior assessment of finely dispersed and highly uniform Al/B4C/SiC hybrid composite fabricated via accumulative roll bonding process, J. Manuf. Processes, 22, 120-126, 2016.
  • [4] Özyürek D., Tekeli S., An investigation on wear resistance of SiCp-reinforced aluminium composites produced by mechanical alloying method, Sci. Eng. Compos. Mater., 17 (1), 31-38, 2010.
  • [5] Şimşek İ., Şimşek D., Özyürek D., Production and characterization of Al-SiC composites prepared by mechanical milling and pressureless sintering, BEU Journal of Science, 8 (1), 227-233, 2019.
  • [6] Darmiani E., Danaee I., Golozar M. A., Toroghinejad M. R., Corrosion investigation of Al–SiC nano-composite fabricated by accumulative roll bonding (ARB) process, J. Alloys Compd., 552, 31-39, 2013.
  • [7] Gupta R. K., Mehrotra S. P., Gupta S. P., Evaluation and optimization of metal matrix composite strip produced by single roll continuous strip casting method, Mater. Sci. Eng. A, 465, 116-23, 2007.
  • [8] Simsek I., Ozyurek D., Investigation of the wear and corrosion behaviors of Ti5Al2.5Fe and Ti6Al4V alloys produced by mechanical alloying method in simulated body fluid environment, Mater. Sci. Eng. C, 94, 357-363, 2019.
  • [9] Hemanth J., Tribological behavior of cryogenically treated B4Cp/Al–12% Si composites, Wear, 258, 1732-1744, 2005.
  • [10] Şimşek İ., Yıldırım M., Tunçay T., Özyürek D., Şimşek D., Mekanik alaşımlama/öğütme yöntemi ile üretilen Al-SiC kompozitlerin incelenmesi, Technological Applied Sciences, 13 (2), 165-171, 2018.
  • [11] Şimşek İ., The effect of B4C amount on wear behaviors of Al-Graphite/B4C hybrid composites produced by mechanical alloying, BORON, 4(2), 100-106, 2019.
  • [12] Şimşek İ., Mekanik alaşımlama yöntemi ile üretilen farklı miktarlarda ZrO2 takviyeli Al-2Gr matrisli kompozit malzemelerin aşınma performanslarının incelenmesi, El-Cezeri F. Müh. Der., 6 (3), 594-605, (2019).
  • [13] Erek H. B., Ozyurek D., Asan A., Electrical conductivity and corrosion performances of ın situ and ex situ AA7075 aluminum composites, Acta Phys. Pol. A, 131 (1), 153-155, 2017.
  • [14] Bobıć B., Mıtrovıć S., Babıć M., Bobıć I., Corrosion of metal-matrix composites with aluminium alloy substrate, Tribol. Ind., 32 (1), 3-11, 2010.
  • [15] Han Y. M., Grant-Chen X., Electrochemical behavior of Al-B4C metal matrix composites in NaCl solution, Materials, 8, 6455-6470, 2015.
  • [16] Katkar V.A., Gunasekaran G, Rao A.G., Koli P. M., Effect of the reinforced boron carbide particulate content of AA6061 alloy on formation of the passive film in seawater, Corros. Sci., 53, 2700-2712, 2011.
  • [17] Bostan B., Ozdemir A. T., Kalkanli A., Microstructure characteristics in Al–C system after mechanical alloying and high temperature treatment, Powd. Metal., 47 (1), 37-42, 2004.
  • [18] Durai T. G., Das K., Das S., Corrosion behavior of Al–Zn/Al2O3 and Al–Zn–X/Al2O3 (X = Cu, Mn) composites synthesized by mechanical–thermal treatment, J. Alloys Compd., 462, 410-415, 2008.
  • [19] Dobrzanski L. A., Włodarczyk A., Adamiak M., Structure, properties and corrosion resistance of PM composite materials based on EN AW-2124 aluminum alloy reinforced with the Al2O3 ceramic particles, J. Mater. Process. Technol., 162-163, 27-32, 2005.
  • [20] Yerlikaya G., Ahmad A., Farsak M., Kardaş G., Yumuşak çeliğin asit ortamındaki korozyonuna thiadiazole türevi inhibitörün etkisi, XVth International Corrosion Symposium, Hatay-Türkiye, September 26–28, 2018.
  • [21] Huanhuan S., Hui W., Fanling M., Study of corrosion protection of the composite films on A356 aluminum alloy, J. Rare Earths, 29 (10), 991-996, 2011.
  • [22] Feng Z., Lin C., Pitting behavior of SiCp/2024 Al metal matrix composites, J. Mater. Sci. 33, 5637–5642, 1998.
  • [23] Kiourtsidis G.E., Skolianos S.M., Pitting corrosion of artificially aged T6 AA2024/SiCp composites in 3.5 wt% NaCl aqueous solution, Corros. Sci. 49, 2711–2725, 2007.
  • [24] Ahmad Z., Paulette P.T., Aleem B.J.A., Mechanism of localized corrosion of aluminum–silicon carbide composites in a chloride containing environment, J. Mater. Sci. 35, 2573–2579, 2000.
  • [25] Aballe A., Bethencourt M., Botana F. J., Cano M. J., Marcos M., Influence of the cathodic intermetallics distribution on the reproducibility of the electrochemical measurements on AA5083 alloy in NaCl solutions, Corros. Sci., 45, 161-180, 2003.

The corrosion behaviours in different solutions of B4C reinforcement aluminium matrix composites

Yıl 2020, Cilt: 5 Sayı: 1, 23 - 28, 29.03.2020

İjlal Şimşek Doğan Şimşek Dursun Özyürek

https://doi.org/10.30728/boron.659969

Öz

In this study, were investigated corrosion behavior in different solutions of 12% B4C reinforced Al 2% graphite matrix composite material produced by mechanical alloying method. The prepared powders were mechanically alloying in the planetary type alloying device. Mechanical alloyed powders were produced green compacts by cold pressed under pressure of 750 MPa in a hydraulic press. The green compacts were sintered at 600 °C for 2 hours. Corrosion tests were carried out in two different solutions (3.5% NaCl and 0.1 M H2SO4) by potentiodynamic polarization method. As a result of corrosion tests, low current density was obtained in NaCl solution compared to H2SO4 solution. In addition, in the electrochemical impedance measurements showed that the Nyquist curve in H2SO4 solution had a lower semicircle diameter and an inductive cycle at low frequencies.

Anahtar Kelimeler

Al composite B4C Impedance Corrosion

Kaynakça

  • [1] Nie J., Wang F., Chen Y., Mao Q., Yang H., Song Z., Liu X., Zhao Y., Microstructure and corrosion behavior of Al-TiB2/TiC composites processed by hot rolling, Results in Phys., 14, 1-7, 2019.
  • [2] Alaneme K. K., Adewale T.M., Olubambi P. A., Corrosion and wear behaviour of Al–Mg–Si alloy matrix hybrid composites reinforced with rice husk ash and silicon carbide, J. Mater. Res. Technol., 3 (1), 9-16, 2014.
  • [3] Fattah-alhosseini A., Naser M., Alemi M. H., Corrosion behavior assessment of finely dispersed and highly uniform Al/B4C/SiC hybrid composite fabricated via accumulative roll bonding process, J. Manuf. Processes, 22, 120-126, 2016.
  • [4] Özyürek D., Tekeli S., An investigation on wear resistance of SiCp-reinforced aluminium composites produced by mechanical alloying method, Sci. Eng. Compos. Mater., 17 (1), 31-38, 2010.
  • [5] Şimşek İ., Şimşek D., Özyürek D., Production and characterization of Al-SiC composites prepared by mechanical milling and pressureless sintering, BEU Journal of Science, 8 (1), 227-233, 2019.
  • [6] Darmiani E., Danaee I., Golozar M. A., Toroghinejad M. R., Corrosion investigation of Al–SiC nano-composite fabricated by accumulative roll bonding (ARB) process, J. Alloys Compd., 552, 31-39, 2013.
  • [7] Gupta R. K., Mehrotra S. P., Gupta S. P., Evaluation and optimization of metal matrix composite strip produced by single roll continuous strip casting method, Mater. Sci. Eng. A, 465, 116-23, 2007.
  • [8] Simsek I., Ozyurek D., Investigation of the wear and corrosion behaviors of Ti5Al2.5Fe and Ti6Al4V alloys produced by mechanical alloying method in simulated body fluid environment, Mater. Sci. Eng. C, 94, 357-363, 2019.
  • [9] Hemanth J., Tribological behavior of cryogenically treated B4Cp/Al–12% Si composites, Wear, 258, 1732-1744, 2005.
  • [10] Şimşek İ., Yıldırım M., Tunçay T., Özyürek D., Şimşek D., Mekanik alaşımlama/öğütme yöntemi ile üretilen Al-SiC kompozitlerin incelenmesi, Technological Applied Sciences, 13 (2), 165-171, 2018.
  • [11] Şimşek İ., The effect of B4C amount on wear behaviors of Al-Graphite/B4C hybrid composites produced by mechanical alloying, BORON, 4(2), 100-106, 2019.
  • [12] Şimşek İ., Mekanik alaşımlama yöntemi ile üretilen farklı miktarlarda ZrO2 takviyeli Al-2Gr matrisli kompozit malzemelerin aşınma performanslarının incelenmesi, El-Cezeri F. Müh. Der., 6 (3), 594-605, (2019).
  • [13] Erek H. B., Ozyurek D., Asan A., Electrical conductivity and corrosion performances of ın situ and ex situ AA7075 aluminum composites, Acta Phys. Pol. A, 131 (1), 153-155, 2017.
  • [14] Bobıć B., Mıtrovıć S., Babıć M., Bobıć I., Corrosion of metal-matrix composites with aluminium alloy substrate, Tribol. Ind., 32 (1), 3-11, 2010.
  • [15] Han Y. M., Grant-Chen X., Electrochemical behavior of Al-B4C metal matrix composites in NaCl solution, Materials, 8, 6455-6470, 2015.
  • [16] Katkar V.A., Gunasekaran G, Rao A.G., Koli P. M., Effect of the reinforced boron carbide particulate content of AA6061 alloy on formation of the passive film in seawater, Corros. Sci., 53, 2700-2712, 2011.
  • [17] Bostan B., Ozdemir A. T., Kalkanli A., Microstructure characteristics in Al–C system after mechanical alloying and high temperature treatment, Powd. Metal., 47 (1), 37-42, 2004.
  • [18] Durai T. G., Das K., Das S., Corrosion behavior of Al–Zn/Al2O3 and Al–Zn–X/Al2O3 (X = Cu, Mn) composites synthesized by mechanical–thermal treatment, J. Alloys Compd., 462, 410-415, 2008.
  • [19] Dobrzanski L. A., Włodarczyk A., Adamiak M., Structure, properties and corrosion resistance of PM composite materials based on EN AW-2124 aluminum alloy reinforced with the Al2O3 ceramic particles, J. Mater. Process. Technol., 162-163, 27-32, 2005.
  • [20] Yerlikaya G., Ahmad A., Farsak M., Kardaş G., Yumuşak çeliğin asit ortamındaki korozyonuna thiadiazole türevi inhibitörün etkisi, XVth International Corrosion Symposium, Hatay-Türkiye, September 26–28, 2018.
  • [21] Huanhuan S., Hui W., Fanling M., Study of corrosion protection of the composite films on A356 aluminum alloy, J. Rare Earths, 29 (10), 991-996, 2011.
  • [22] Feng Z., Lin C., Pitting behavior of SiCp/2024 Al metal matrix composites, J. Mater. Sci. 33, 5637–5642, 1998.
  • [23] Kiourtsidis G.E., Skolianos S.M., Pitting corrosion of artificially aged T6 AA2024/SiCp composites in 3.5 wt% NaCl aqueous solution, Corros. Sci. 49, 2711–2725, 2007.
  • [24] Ahmad Z., Paulette P.T., Aleem B.J.A., Mechanism of localized corrosion of aluminum–silicon carbide composites in a chloride containing environment, J. Mater. Sci. 35, 2573–2579, 2000.
  • [25] Aballe A., Bethencourt M., Botana F. J., Cano M. J., Marcos M., Influence of the cathodic intermetallics distribution on the reproducibility of the electrochemical measurements on AA5083 alloy in NaCl solutions, Corros. Sci., 45, 161-180, 2003.
Toplam 25 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Research Makaleler
Yazarlar

İjlal Şimşek 0000-0001-6542-8567

Doğan Şimşek

Dursun Özyürek

Yayımlanma Tarihi 29 Mart 2020
Kabul Tarihi 17 Şubat 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 5 Sayı: 1

Kaynak Göster

APA Şimşek, İ., Şimşek, D., & Özyürek, D. (2020). B4C takviyeli alüminyum matris kompozitlerin farklı çözeltilerdeki korozyon davranışları. Journal of Boron, 5(1), 23-28. https://doi.org/10.30728/boron.659969

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