TY  - JOUR
T1  - Glisin Yakma Tekniği ile Sentezlenen Ce1-xLaxO2 (x=0,04) Nanoparçacıklarının Faz Oluşumu ve Kristal Yapıları Üzerinde Glisin Miktarının Etkisi
TT  - The Effect of Glycine Quantity on the Phase Formation and Crystal Structures of Ce1-xLaxO2 (x=0.04) Nanoparticles Synthesized by Glycine Combustion Technique
AU  - Kırkgeçit, Nurvet
AU  - Kırkgeçit, Rabia
AU  - Kırkgeçit, Ayşe
PY  - 2024
DA  - June
Y2  - 2024
JF  - KİÜ Fen, Mühendislik ve Teknoloji Dergisi
PB  - Kahramanmaraş İstiklal Üniversitesi
WT  - DergiPark
SN  - 3023-8307
SP  - 43
EP  - 50
VL  - 1
IS  - 1
LA  - tr
AB  - Bu çalışmada, glisin yakma tekniği kullanılarak sentezlenen Lantanyum katkılı Ce1-xLaxO2 (x=0,04) nanoparçacıklarının glisin miktarının faz oluşumu ve kristal yapıları üzerindeki etkisi incelenmiştir. X-ışını kırınımı (XRD) ve Raman saçılma spektroskopisi kullanılarak yapılan karakterizasyonlar sonucunda elde edilen bulgulara göre, farklı glisin miktarlarına bağlı olarak örneklerin kristalit boyutlarında değişimler gözlemlenmiş ve glisin miktarının artmasıyla kristalit boyutunda azalma tespit edilmiştir. Ayrıca, Raman saçılma spektroskopisi sonuçları, örneklerdeki Ce-O bağlarına ilişkin karakteristik piklerin ve örneklerin kristal boyutları arasındaki ilişkiyi ortaya koymuştur. Bu sonuçlar, glisin miktarının nanoparçacıkların yapısal özellikleri üzerinde belirgin bir etkisi olduğunu göstermektedir. Bu çalışma, Lantanyum katkılı Ce1-xLaxO2  nanoparçacıklarının sentezi ve yapısal karakterizasyonuyla ilgilenen araştırmacılar için önemli bir referans kaynağı olabilir.
KW  - Seryum oksit
KW  - Glisin yakma tekniği
KW  - Sentez parametreleri
N2  - In this study, the effect of glycine quantity on the phase formation and crystal structures of lanthanum-doped Ce1-xLaxO2 (x=0.04) nanoparticles synthesized using the glycine combustion technique was investigated. Characterizations were conducted using X-ray diffraction (XRD) and Raman scattering spectroscopy. According to the results obtained from these characterizations, variations in the crystal sizes of the samples were observed depending on different glycine quantities, with an observed decrease in crystal size as the glycine quantity increased. Additionally, the results from Raman scattering spectroscopy revealed the relationship between characteristic peaks corresponding to Ce-O bonds and the crystal sizes of the samples. These findings demonstrate a significant influence of glycine quantity on the structural properties of the nanoparticles. This study serves as an important reference for researchers interested in the synthesis and structural characterization of lanthanum-doped Ce1-xLaxO2 nanoparticles.
CR  - Aruna, S. T., Kini, N. S., & Rajam, K. S. (2009). Solution combustion synthesis of CeO2–CeAlO3 nano-composites by mixture-of-fuels approach. Materials Research Bulletin, 44(4), 728-733.
CR  - Barrón, V. R. O., Ochoa, F. M. E., Vázquez, C. C., & Bernal, R. (2016). Thermoluminescence of novel MgO–CeO2 obtained by a glycine-based solution combustion method. Applied Radiation and Isotopes, 117, 86-90.
CR  - Calvache-Muñoz, J., Prado, F. A., & Rodríguez-Páez, J. E. (2017). Cerium oxide nanoparticles: Synthesis, characterization and tentative mechanism of particle formation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 529, 146-159.
CR  - Chopra, L., & Kumar, R. (2024). Combustion-synthesized ZnO-CeO2 heterojunctions for advanced photocatalytic dye degradation. Inorganic Chemistry Communications, 160, 111896.
CR  - Das, S., Bhaskar, R., & Narayanan, K. B. (2024). Multifunctional applications of gadolinium-doped cerium oxide (Ce1–xGdxO2–∂) ceramics: A review. Journal of Rare Earths.
CR  - Deganello, F., & Tyagi, A. K. (2018). Solution combustion synthesis, energy and environment: Best parameters for better materials. Progress in Crystal Growth and Characterization of  Materials, 64 (2), 23-61.
CR  - Goharshadi, E. K., Samiee, S., & Nancarrow, P. (2011). Fabrication of cerium oxide nanoparticles: Characterization and optical properties. Journal of colloid and interface science, 356(2), 473-480.
CR  - Gómez, D. A., Coello, J., & Maspoch, S. (2019). The influence of particle size on the intensity and reproducibility of Raman spectra of compacted samples. Vibrational spectroscopy, 100, 48-56.
CR  - Kırkgeçit, R., Torun, H. Ö., Öztürk, E., & Dokan, F. K. (2023). Synergistic effect of CeO2: La and CeO2: La-Gd nanostructures: Photoluminescence and electrical properties. Optik, 272, 170236.
CR  - Kırkgeçit, N., & Bozgeyik, M. S. (2021). Mikroyapının Stronsiyum Bizmut Tantalat İnce Filmlerin Ferroelektrik ve Elektriksel Özelliklerine Etkisi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, 37(3), 468-478.
CR  - Mužina, K., Kurajica, S., Bach-Rojecky, H., Brleković, F., & Duplančić, M. (2024). Combustion Synthesis of Zirconium-Doped Ceria Nanocatalyst. Crystals, 14(2), 108.
CR  - Nyoka, M., Choonara, Y. E., Kumar, P., Kondiah, P. P., & Pillay, V. (2020). Synthesis of cerium oxide nanoparticles using various methods: implications for biomedical applications. Nanomaterials, 10 (2), 242.
CR  - Rajkumar, P., Selvaraj, S., & GP, S. M. (2024). Structural, Optical, and Magnetic Studies of Palladium (Pd) Doped Cerium Oxide (CeO2) Nano Particles. Physical Chemistry Research, 12(2), 407-417.
CR  - Rianjanu, A., Mustamin, A. S. P., Melati, E. K. A., Aflaha, R., Khamidy, N. I., Utami, M., ... & Taher, T. (2024). Photocatalytic degradation of aqueous Congo red dye pollutants by rare-earth metal oxide (CeO2) nanorods. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 682, 132919.
CR  - Soğuksu, A. K., Kerli, S., Kavgacı, M., & Gündeş, A. (2022). Electrochemical Properties, Antimicrobial Activity and Photocatalytic Performance of Cerium-Iron Oxide Nanoparticles. Russian Journal of Physical Chemistry A, 96(1), 209-215.
CR  - Soğuksu, A. K., Kerli, S., Kavun, Y., & Alver, Ü. (2024). Synthesis and characterizations of Ce-doped ZnO thin films for radiation shielding. Optical Materials, 148, 114941.
CR  - Subbaiah, G. C. V. (2024). Structural, optical and magnetic properties of Cu doped CeO2 nano powders synthesized by solid state reaction. Nano Express, 5(1), 015007.
CR  - Torun, H. Ö., & Kırkgeçit, R. (2024). Investigation of Photocatalytic and Photoluminescent Properties of a Novel Multifunctional Near-UV Excited NanoStucture CeO2: 0.1 Dy0. 1Ho. Indian Journal of Pure & Applied Physics (IJPAP), 62(4), 320-328.
UR  - https://dergipark.org.tr/tr/pub/kiufemte/issue//1463784
L1  - https://dergipark.org.tr/tr/download/article-file/3842083
ER  -