TY - JOUR T1 - Influence of Phosphorus Content and Preheating Conditions on Grain Size of Cu-DHP Copper Tubes TT - Influence of Phosphorus Content and Preheating Conditions on Grain Size of Cu-DHP Copper Tubes AU - Sirel, Zeynep AU - Çatalkaya, Hakan AU - Zığındere, Orçun AU - Akoy, Mehmet Ali PY - 2025 DA - May Y2 - 2024 DO - 10.34088/kojose.1475031 JF - Kocaeli Journal of Science and Engineering JO - KOJOSE PB - Kocaeli Üniversitesi WT - DergiPark SN - 2667-484X SP - 24 EP - 29 VL - 8 IS - 1 LA - en AB - “Cu-DHP” copper tubes are used in sanitary, plumbing and heat exchanger applications. For drawability and forming processes, grain size is an important factor. Grain size is affected by the process conditions and chemical content. The aim of this study is to examine the effect of phosphorus content on Cu-DHP copper tube products. For this examination, four copper billets with different phosphorus content were used to produce 9.52x0.30 mm copper tubes. The copper billets which are 305 mm in diameter and 580 mm in length were preheated in furnaces and the hot direct extrusion method was used for mother tube production. Shortened preheating time resulted in finer grain size in mother tubes. Mother tubes were cold drawn to the final dimension in subsequent steps and annealed at recrystallization temperature with the same parameters. Grain sizes of annealed 9.52x0.30 mm copper tubes are in the range of 17 to 20 µm. For the final tube dimensions, high amount of cold drawing ratio diminished the effect of the prior grain size of the mother tubes. According to the result of inspections, it is concluded that in cold-drawn and annealed products, phosphorus content has a grain coarsening effect on the final product. KW - Billet casting KW - Copper tube KW - Cu-DHP KW - Deoxidized copper KW - Grain size KW - Preheating KW - Tube drawing N2 - “Cu-DHP” copper tubes are used in sanitary, plumbing and heat exchanger applications. For drawability and forming processes, grain size is an important factor. Grain size is affected by the process conditions and chemical content. The aim of this study is to examine the effect of phosphorus content on Cu-DHP copper tube products. For this examination, four copper billets with different phosphorus content were used to produce 9.52x0.30 mm copper tubes. The copper billets which are 305 mm in diameter and 580 mm in length were preheated in furnaces and the hot direct extrusion method was used for mother tube production. Shortened preheating time resulted in finer grain size in mother tubes. Mother tubes were cold drawn to the final dimension in subsequent steps and annealed at recrystallization temperature with the same parameters. Grain sizes of annealed 9.52x0.30 mm copper tubes are in the range of 17 to 20 µm. For the final tube dimensions, high amount of cold drawing ratio diminished the effect of the prior grain size of the mother tubes. According to the result of inspections, it is concluded that in cold-drawn and annealed products, phosphorus content has a grain coarsening effect on the final product. CR - [1] Michel, J., 2013. Introduction To Copper and Copper Alloys, Copper Development Association Inc., https://copper.org/publications/pub_list/pdf/introduction-to-copper-and-copper-alloys.pdf Access Date: December 2, 2022. CR - [2] BS EN 1057:2006+A1:2010 Copper And Copper Alloys – Seamless, Round Copper Tubes For Water And Gas In Sanitary And Heating Applications. CR - [3] Chapman, D., 2016. High Conductivity Copper For Electrical Engineering, Copper Development Association – Copper Alliance, 122, pp.18, 19. CR - [4] Sarkuysan, 2023. www.sarkuysan.com/en-EN/continuous-billet-casting/152.aspx Access Date: April 24, 2023 CR - [5] Copper, 2023. www.copper.org/publications/newsletters/innovations/1998/09/howdo_tube.html Access Date: April 24, 2023 CR - [6] Dieter, G.E., 1988. Mechanical Metallurgy, SI Metric Edition, McGraw-Hill, pp. 616, 646. CR - [7] Siegert K., 2004. Extrusion. In Müller, K. (Ed.), Fundamentals Of Extrusion Technology, Giesel Verlag, p. 16. CR - [8] Laue K., Stenger H., 1981. Extrusion Processes, Machinery, Tooling, American Society For Metals, United States, p. 163. CR - [9] Clarebrough L. M., Hargreaves M. E., Loretto M. H., 1958. The Influence Of Grain Size On The Stored Energy And Mechanical Properties Of Copper. Acta Metallurgica, 6, pp 725-735. CR - [10] Balart M. J., Patel J. B., Gao F., Fan Z., 2015. Grain Refinement Of Dhp Copper By Elemental Additions. International Journal of Cast Metals Research, 28(4), pp. 248-256. CR - [11] Cziegler A., 2015. Aspects of Grain Refinement in Copper Alloys. Master Thesis, University of Leoben. CR - [12] Zhang Z., Liu H., Hua Y., Zhang B., Hou Z., Li W., Song K., 2024. Study On The Effect Of Phosphorus On Anti-Softening Performance Of, Journal Of Materials Research And Technology, 33, pp. 2612-2623. CR - [13] ASTM E112-13 Standard Test Methods for Determining Average Grain Size. CR - [14] Sandström R., 2014, The Role Of Phosphorus For Mechanical Properties In Copper, https://skb.se/wp-content/uploads/2015/05/1417069-The-role-of-phosphorus-for-mechanical-properties-in-copper.pdf CR - [15] Hayden H. W., Moffatt W. G., Wulff J., 1965. The Structure And Properties Of Materials Volume III, John Wiley & Sons, p. 169. UR - https://doi.org/10.34088/kojose.1475031 L1 - https://dergipark.org.tr/tr/download/article-file/3891436 ER -