TY - JOUR T1 - STOKİYOMETRİK OLMAYAN NBT-ST SERAMİKLERİNİN ELEKTRİKSEL ÖZELLİKLERİNE SİNTERLEME YARDIMCISI CuO KATKISI ETKİSİNİN İNCELENMESİ TT - INVESTIGATION OF THE EFFECT OF CuO SINTERING AID ON THE ELECTRICAL PROPERTIES OF NON-STOICHIOMETRIC NBT-ST CERAMICS AU - Kaya, Mustafa Yunus AU - Yaldiz İnce, Gülbeniz PY - 2024 DA - December Y2 - 2024 DO - 10.31796/ogummf.1542806 JF - Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi JO - ESOGÜ Müh Mim Fak Derg PB - Eskişehir Osmangazi Üniversitesi WT - DergiPark SN - 2630-5712 SP - 1526 EP - 1536 VL - 32 IS - 3 LA - tr AB - Son yirmi yıllık süreçte, elektromekanik cihazlarda, enerji hasadı ve enerji depolama uygulamalarında yaygın kullanıma sahip kurşun zirkonat titanat ve türevi seramiklere alternatif olarak kurşun içermeyen piezoseramiklerin araştırılması ve geliştirilmesi üzerine çok sayıda çalışma yapılmıştır. Bu araştırmalar içerisinde sodyum bizmut titanat (Na0.5Bi0.5TiO3-NBT) esaslı seramikler ve morfotropik faz sınırı (MFS) kompozisyonları sergiledikleri elektriksel özellikler ile öne çıkmaktadır. Bu çalışmada, NBT seramik bileşimi stronsiyum titanat (SrTiO3-ST) ile modifiye edilmiştir. [Na0,5Bi0,5TiO3]0,75[Sr1-xTiO3-x]0,25-NBT-SnT (x=0,25) kimyasal formülünce stokiyometrik olmayan seramik kompozisyonu katı hal kalsinasyon yöntemiyle sentezlenmiş ve CuO katkısının sinterleme performansı ve özellikleri üzerine etkisi incelenmiştir. Sentezleme işlemi sonrasında psedokübik simetride NBT-SnT fazının yüksek oranda oluştuğu görülmüştür. Sinterleme yardımcısı CuO katkısı miktarına bağlı olarak sinterleme işleminde ikincil faz oluşumu gözlenmiştir. En yüksek yoğunlaşma oranı %0,5 CuO katkılı seramiklerde 1200 °C’de 3 saat sinterleme ile elde edilmiştir. Bu seramikler için 10 kHz frekansında dielektrik sabiti (K) 570 ila 1300 arasında, dielektrik kayıp (tan ) değerleri 0,04 ila 0,11 arasında, relaksör ferroelektrik davranışa işaret eden yayınımsallık derecesi () ise 1, 84 ila 1,99 arasında değişmektedir. KW - Kurşunsuz Seramik KW - Sodyum Bizmut Titatanat KW - Ferroelektrik KW - CuO Katkı N2 - In the last two decades, extensive research has been conducted on lead-free piezoceramics to find alternatives to lead-zirconate-titanate (PZT) and its derivatives, which are widely utilized in electromechanical devices, including actuators, transducers, sensors, energy harvesting, and energy storage applications. Among these studies, sodium bismuth titanate (Na0.5Bi0.5TiO3-NBT) based ceramics and compositions near the morphotropic phase boundary (MPB) are notable for their electrical properties. A recent study modified the NBT ceramic composition with strontium titanate (SrTiO3-ST). 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