TY  - JOUR
T1  - Metalik malzemeler üzerine kendi kendini iyileştiren kaplamaların geliştirilmesi ve karakterizasyonu
TT  - Development and characterization of self-healing coatings on metallic materials
AU  - Pehlivan, Emre
AU  - Eken, Taha Yasin
AU  - Şam Parmak, Ebru Devrim
PY  - 2025
DA  - April
Y2  - 2025
DO  - 10.28948/ngumuh.1594724
JF  - Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi
JO  - NÖHÜ Müh. Bilim. Derg.
PB  - Niğde Ömer Halisdemir Üniversitesi
WT  - DergiPark
SN  - 2564-6605
SP  - 712
EP  - 721
VL  - 14
IS  - 2
LA  - tr
AB  - Malzeme yüzeylerine uygulanan koruyucu kaplamalarda, mekanik gerilim, termal dalgalanma ve kimyasal bozunma nedeniyle hasar ve çatlak oluşumu kaçınılmazdır. Çoğu zaman tespit edilmesi zor ve onarımı neredeyse imkânsız olan mikro ve iç çatlaklar malzemenin yapısal bütünlüğünü zayıflatmaktadır. Geleneksel onarım teknikleri bu tür kusurları gidermede yetersiz kalmakta, bu durum kendini onaran malzemeler gibi onarım mekanizmalarına sahip çözümlerin geliştirilmesini zorunlu kılmaktadır. Bu ileri düzey malzemeler, mikro çatlakları erken aşamada doldurarak çatlak yayılımını otomatik olarak engellemekte ve böylece kaplanmış yapıların hizmet ömrünü uzatırken bakım ve korozyon maliyetlerini önemli ölçüde azaltmaktadır. Bu çalışmada, Pickering emülsiyon yöntemiyle üretilen grafen oksit (GO) içeren keten tohumu yağlı (LO) mikrokapsüllerin çelik malzeme yüzeyine kaplanması esas alınmıştır. İyileştirici kimyasalın kapsüllendiği termal gravimetrik analiz/diferansiyel termal analiz (TGA/DTA) ile, manuel olarak oluşturulan çiziklerin kendi kendini iyileştirme süreci taramalı elektron mikroskobu (SEM) ve optik mikroskop ile incelenmiştir. Kaplanmış numunelerin korozyon direnci elektrokimyasal korozyon testi (EIS) ile tespit edilmiştir. Başarılı bir şekilde üretilen mikrokapsüller ile yapılan kaplamaların kendi kendini iyileştirdiği gözlemlenmiştir.
KW  - Mikrokapsül
KW  - Kendini İyileştiren Kaplama
KW  - Epoksi Kaplama
KW  - Pickering emülsiyon
N2  - In protective coatings applied to material surfaces, damage and crack formation are inevitable due to mechanical stress, thermal fluctuation and chemical degradation. Often difficult to detect and almost impossible to repair, micro and internal cracks weaken the structural integrity of the material. Traditional repair techniques are inadequate to eliminate such defects, which has necessitated the development of solutions with repair mechanisms such as self-healing materials. These advanced materials automatically prevent crack propagation by filling micro cracks at an early stage, thus extending the service life of coated structures and significantly reducing maintenance and corrosion costs. In this study, the coating of linseed oil (LO) microcapsules containing graphene oxide (GO) produced by the Pickering emulsion method is based on the steel material surface. The self-healing process of manually created scratches was examined with scanning electron microscope (SEM) and optical microscope by thermal analysis/ differential thermal gravimetric analysis (TGA/DTA) where the healing chemical was encapsulated. The corrosion resistance of the coated samples was determined by electrochemical corrosion test (EIS). It was observed that the coatings made with successfully produced microcapsules were self-healing.
CR  - B. Willocq, J. Odent, P. Dubois and J. M. Raquez, Advances in intrinsic self-healing polyurethanes and related composites. RSC Advances, 10 (23), 13766-13782, 2020. https://doi.org/10.1039/D0RA01394C
CR  -    M. A. Mohammadi, R. Eslami-Farsani and H. Ebrahimnezhad-Khaljiri, Experimental investigation of the healing properties of the microvascular channels-based self-healing glass fibers/epoxy composites containing the three-part healant. Polymer Testing, 91, 106862, 2020. https://doi.org/10.1016/j.polymertesting.2020.106862
CR  -    M. Zhu, J. Liu, L. Gan ve M. Long, Research progress in bio-based self-healing materials. European Polymer Journal, 129, 109651, 2020. https://doi.org/10.1016/j.eurpolymj.2020.109651
CR  -    N. I. Khan, S. Halder, S. B. Gunjan and T. Prasad, A review on Diels-Alder based self-healing polymer composites. IOP Conference Series: Materials Science and Engineering, 377 (1), 012007, 2018. https://doi.org/10.1088/1757-899X/377/1/012007
CR  -    J. Li, H. Shi, F. Liu and E. H. Han, Self-healing epoxy coating based on tung oil-containing microcapsules for corrosion protection. Progress in Organic Coatings, 156, 106236, 2021. https://doi.org/10.1016/j.porgcoat.2021.106236
CR  -    X. Wang, F. Liu, X. Zheng and J. Sun, Water‐enabled self‐healing of polyelectrolyte multilayer coatings. Angewandte Chemie International Edition, 50 (48), 11378-11381, 2011. https://doi.org/10.1002/anie.201105822
CR  -    A. Cuvellier, A. Torre-Muruzabal, G. Van Assche, K. De Clerck and H. Rahier, Selection of healing agents for a vascular self-healing application. Polymer Testing, 62, 302-310, 2017. https://doi.org/10.1016/j.polymertesting.2017.07.013
CR  -    Y. Du, D. Li, L. Liu and G. Gai, Recent achievements of self-healing graphene/polymer composites. Polymers, 10 (2), 114, 2018. https://doi.org/10.3390/polym10020114
CR  -    G. Thangavel, M. W. M. Tan and P. S. Lee, Advances in self-healing supramolecular soft materials and nanocomposites. Nano Convergence, 6 (1), 1-18, 2019. https://doi.org/10.1186/s40580-019-0199-9
CR  - M. Kosarli, D. G. Bekas, K. Tsirka, D. Baltzis, D. T. Vaimakis-Tsogkas, S. Orfanidis and A. S. Paipetis, Microcapsule-based self-healing materials: Healing efficiency and toughness reduction vs. capsule size. Composites Part B: Engineering, 171, 78-86, 2019. https://doi.org/10.1016/j.compositesb.2019.04.030
CR  - N. N. Sahir, N. A. Hassan, N. B. Hassan and N. B. Johari, Graphene oxide microcapsules (GOMs) with linseed oil core via Pickering emulsion method: Effect of disperse speed. IIUM Engineering Journal, 22 (1), 213-222, 2021. https://doi.org/10.31436/iiumej.v22i1.1426
CR  - F. Yu, H. Feng, L. Xiao and Y. Liu, Fabrication of graphene oxide microcapsules based on Pickering emulsions for self-healing water-borne epoxy resin coatings. Progress in Organic Coatings, 155, 106221, 2021. https://doi.org/10.1016/j.porgcoat.2021.106221
CR  - S. Sarkar and B. Kim, Synthesis of graphene oxide–epoxy resin encapsulated urea–formaldehyde microcapsule by in situ polymerization process. Polymer Composites, 39 (3), 636-644, 2018. https://doi.org/10.1002/pc.23979
CR  - Li, Z. Li, Q. Feng, H. Qiu, G. Yang, S. Zheng and J. Yang, Encapsulation of linseed oil in graphene oxide shells for preparation of self-healing composite coatings. Progress in Organic Coatings, 129, 285-291, 2019. https://doi.org/10.1016/j.porgcoat.2019.01.024
CR  - V. Naveen, A. P. Deshpande and S. Raja, Self-healing microcapsules encapsulated with carbon nanotubes for improved thermal and electrical properties. RSC Advances, 10 (55), 33178-33188, 2020. https://doi.org/10.1039/D0RA06631A
CR  - S. J. García, H. R. Fischer and S. Van Der Zwaag, A critical appraisal of the potential of self-healing polymeric coatings. Progress in Organic Coatings, 72 (3), 211-221, 2011. https://doi.org/10.1016/j.porgcoat.2011.06.016
CR  - A. Kausar, Polymer coating technology for high performance applications: Fundamentals and advances. Journal of Macromolecular Science, Part A, 55 (5), 440-448, 2018. https://doi.org/10.1080/10601325.2018.1453266
CR  - M. Samadzadeh, S. H. Boura, M. Peikari, S. M. Kasiriha and A. Ashrafi, A review on self-healing coatings based on micro/nanocapsules. Progress in Organic Coatings, 68 (3), 159-164, 2010. https://doi.org/10.1016/j.porgcoat.2010.01.006
CR  - S. M. Dezfuli and M. Sabzi, Deposition of self-healing thin films by the sol–gel method: A review of layer-deposition mechanisms and activation of self-healing mechanisms. Applied Physics A, 125 (8), 1-8, 2019. https://doi.org/10.1007/s00339-019-2854-8
CR  - S. Habib, R. A. Shakoor and R. Kahraman, A focused review on smart carriers tailored for corrosion protection: Developments, applications, and challenges. Progress in Organic Coatings, 154, 106218, 2021. https://doi.org/10.1016/j.porgcoat.2021.106218
CR  - N. K. Mehta and M. N. Bogere, Environmental studies of smart/self-healing coating system for steel. Progress in Organic Coatings, 64 (4), 419-428, 2009. https://doi.org/10.1016/j.porgcoat.2008.08.007
CR  - H. Y. Su, P. L. Chen and C. S. Lin, Sol–gel coatings doped with organosilane and cerium to improve the properties of hot-dip galvanized steel. Corrosion Science, 102, 63-71, 2016. https://doi.org/10.1016/j.corsci.2015.09.019
CR  - H. Hassannejad and A. Nouri, Synthesis and evaluation of self-healing cerium-doped chitosan nanocomposite coatings on AA5083-H321. International Journal of Electrochemical Science, 11, 2106-2118, 2016. https://doi.org/10.1016/S1452-3981(23)16086-X
CR  - D. G. Shchukin, M. Zheludkevich, K. Yasakau, S. Lamaka, M. G. Ferreira and H. Möhwald, Layer‐by‐layer assembled nanocontainers for self‐healing corrosion protection. Advanced Materials, 18 (13), 1672-1678, 2006. https://doi.org/10.1002/adma.200502053
CR  - M. Attaei, L. M. Calado, M. G. Taryba, Y. Morozov, R. A. Shakoor, R. Kahraman and M. F. Montemor, Autonomous self-healing in epoxy coatings provided by high efficiency isophorone diisocyanate (IPDI) microcapsules for protection of carbon steel. Progress in Organic Coatings, 139, 105445, 2020. https://doi.org/10.1016/j.porgcoat.2019.105445
CR  - D. Yuan, V. Solouki Bonab, A. Patel, T. Yilmaz, R. A. Gross and I. Manas-Zloczower, Design strategy for self-healing epoxy coatings. Coatings, 10 (1), 50, 2020. https://doi.org/10.3390/coatings10010050
CR  - G. Li, P. Xiao, S. Hou and Y. Huang, Graphene based self-healing materials. Carbon, 146, 371-387, 2019. https://doi.org/10.1016/j.carbon.2019.02.011
CR  - P. Vijayan and M. Al-Maadeed, Self-repairing composites for corrosion protection: A review on recent strategies and evaluation methods. Materials, 12 (17), 2754, 2019. https://doi.org/10.3390/ma12172754
CR  - A. H. Navarchian, N. Najafipoor and F. Ahangaran, Surface-modified poly (methyl methacrylate) microcapsules containing linseed oil for application in self-healing epoxy-based coatings. Progress in Organic Coatings, 132, 288-297, 2019. https://doi.org/10.1016/j.porgcoat.2019.03.029
CR  - H. Ullah, K. A. M. Azizli, M. B. C. Ismail, M. I. Khan and Z. B. Man, The potential of microencapsulated self-healing materials for microcracks recovery in self-healing composite systems: A review. Polymer Reviews, 56 (3), 429-485, 2016. https://doi.org/10.1080/15583724.2015.1107098
CR  - K. Wu, Y. Chen, J. Luo, R. Liu, G. Sun and X. Liu, Preparation of dual-chamber microcapsule by Pickering emulsion for self-healing application with ultra-high healing efficiency. Journal of Colloid and Interface Science, 600, 660-669, 2021. https://doi.org/10.1016/j.jcis.2021.05.066
CR  - C. Xu, W. Gou, X. Wang, J. Zhou, J. Liu and K. Chen, Synthesis of paraffin@PS/reduced graphene oxide microcapsules via Pickering emulsion for multi-protective coatings. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 613, 126054, 2021. https://doi.org/10.1016/j.colsurfa.2020.126054
CR  - H. Abdipour, M. Rezaei and F. Abbasi, Synthesis and characterization of high durable linseed oil-urea formaldehyde micro/nanocapsules and their self-healing behaviour in epoxy coating. Progress in Organic Coatings, 124, 200-212, 2018. https://doi.org/10.1016/j.porgcoat.2018.08.019
CR  - H. Ullah, K. A. M. Azizli, M. B. C. Ismail, M. I. Khan and Z. B. Man, The potential of microencapsulated self-healing materials for microcracks recovery in self-healing composite systems: A review. Polymer Reviews, 56 (3), 429-485, 2016. https://doi.org/10.1080/15583724.2015.1107098
CR  - E. Katoueizadeh, S. M. Zebarjad and K. Janghorban, Investigating the effect of synthesis conditions on the formation of urea–formaldehyde microcapsules. Journal of Materials Research and Technology, 8 (1), 541-552, 2019. https://doi.org/10.1016/j.jmrt.2018.04.013
CR  - A. S. Hicyilmaz, A. C. Bedeloglu and Y. Bhoge, In Situ Graphene Oxide Reinforced Poly (Urea-Formaldehyde) Microencapsulation of Epoxy. Materials Science Research India, 16 (1), 7, 2019. https://doi.org/10.13005/msri/160103
CR  - D. Şam, E. Arpat and V. Gunay, Hybrid Nano-Composite Sol-Gel Coatings on Glass. Key Engineering Materials, 264, 395-398, 2004. https://doi.org/10.4028/www.scientific.net/KEM.264-268.395
CR  - J. Li, Q. Feng, J. Cui, Q. Yuan, H. Qiu, S. Gao and J. Yang, Self-assembled graphene oxide microcapsules in Pickering emulsions for self-healing waterborne polyurethane coatings. Composites Science and Technology, 151, 282-290, 2017. https://doi.org/10.1016/j.compscitech.2017.07.031
CR  - M. Behzadnasab, S. M. Mirabedini, M. Esfandeh and R. R. Farnood, Evaluation of corrosion performance of a self-healing epoxy-based coating containing linseed oil-filled microcapsules via electrochemical impedance spectroscopy. Progress in Organic Coatings, 105, 212-224, 2017. https://doi.org/10.1016/j.porgcoat.2017.01.006
CR  - K. Thanawala, N. Mutneja, A. S. Khanna and R. K. Singh Raman, Development of self-healing coatings based on linseed oil as autonomous repairing agent for corrosion resistance. Materials, 7 (11), 7324-7338, 2014. https://doi.org/10.3390/ma7117324
CR  - C. Suryanarayana, K. C. Rao and D. Kumar, Preparation and characterization of microcapsules containing linseed oil and its use in self-healing coatings. Progress in Organic Coatings, 63 (1), 72-78, 2008. https://doi.org/10.1016/j.porgcoat.2008.04.008
UR  - https://doi.org/10.28948/ngumuh.1594724
L1  - https://dergipark.org.tr/tr/download/article-file/4409310
ER  -