TY  - JOUR
T1  - Korozyona Dirençli Amfifobik Yüzey Tasarımı: Silika-Perflorosilan Tabanlı Kaplamalar
AU  - Hüküm Özkan, Kübra
PY  - 2025
DA  - May
Y2  - 2025
DO  - 10.63716/guffd.1677675
JF  - Gazi Üniversitesi Fen Fakültesi Dergisi
JO  - GÜFFD
PB  - Gazi Üniversitesi
WT  - DergiPark
SN  - 2757-5543
SP  - 161
EP  - 170
VL  - 6
IS  - 1
LA  - tr
AB  - Fonksiyonel yüzey kaplamaları, özellikle metalik malzemelerin çevresel etkilerden korunması ve yüzey özelliklerinin iyileştirilmesi açısından son yıllarda önemli bir araştırma alanı haline gelmiştir. Bu çalışmada, alüminyum yüzeylere amfifobik özellik kazandırmak amacıyla, Stöber yöntemi ile sentezlenen silika nanopartiküller farklı konsantrasyonlarda yüzeye püskürtülmüş ve ardından 1H,1H,2H,2H-Perflorooktiltrietoksisilan (perflorosilan) bileşiği ile kimyasal buhar biriktirme (CVD) yöntemi kullanılarak yüzey modifikasyonu gerçekleştirilmiştir. Sentezlenen nanopartiküllerin kimyasal yapısı ve boyutu, Fourier Dönüşümlü Kızılötesi Spektroskopisi (FT-IR) ve Dinamik Işık Saçılımı (DLS) analizleri ile karakterize edilmiş; geliştirilen kaplamaların su, hekzadekan ve diiyodometan test sıvıları ile yapılan temas açısı ölçümleri sonucunda hidrofobik ve oleofobik performans sergilediği belirlenmiştir. En yüksek silika konsantrasyonuna sahip (1 mg/mL) kaplamada temas açısı değerleri sırasıyla su için 116,7°, hekzadekan için 79,2°ve diiyodometan için ise 100,1° olarak ölçülmüş; yüzey enerjisi 9,42 mJ/m2 (su ve diiyodometan temas açılarına göre) olarak hesaplanmıştır. Ayrıca, aşındırıcı pH koşulları altında gerçekleştirilen dayanıklılık testleri sonucunda kaplamaların kimyasal kararlılığını koruduğu gözlemlenmiştir. Elde edilen bulgular, uygulaması kolay ve uzun ömürlü bu amfifobik kaplama yönteminin, korozyona dayanıklı yüzey tasarımlarında geniş bir uygulama potansiyeline sahip olduğunu göstermektedir.
KW  - Fonksiyonel yüzeyler
KW  - Amfifobik kaplama
KW  - korozyon direnci
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UR  - https://doi.org/10.63716/guffd.1677675
L1  - https://dergipark.org.tr/tr/download/article-file/4780108
ER  -