TY - JOUR TT - Photocatalytic degradation of methylene blue by waste ZnO catalyst AU - Çifçi, Deniz İzlen PY - 2017 DA - December JF - Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi PB - Pamukkale Üniversitesi WT - DergiPark SN - 2147-5881 SP - 748 EP - 752 VL - 23 IS - 6 KW - Metilen mavisi KW - Fotokatalitik oksidasyon KW - ZnO KW - Atık gerikazanımı KW - Katalizör N2 - The purpose of this study,the usability of the ZnO content of waste which produces from metal wasterecycling industries as a catalyst was investigated for the removal ofmethylene blue by the photocatalytic oxidation process. For this purpose, azinc content powder which is held with the cyclones during recycling of copperand zinc containing waste is used as a catalyst. Properties of waste ZnO weredemonstrated by the SEM-EDX and FTIR analysis. ZnO/UV and ZnO/H2O2/UVprocesses have been investigated in the photocatalytic oxidation experiments.According to obtained results, 95% of methylene blue removal efficiency wasobtained for ZnO (2.5 g/L)/UV and 10 mg/L initial methylene blue. At a highinitial methylene blue concentration (50 mg/L), approximately 99% of methyleneblue removal can be obtained with the addition of 7.5 mM H2O2.According to toxicity (Daphnia Magna) experiment results, immobilization ofDaphnia Magna was observed at 100% at initial methylene blue concentrationwhile it was dropped off 5% at treated samples. As a result, the zinccontaining waste generated in the industries can be used for dye removal withphotocatalytic oxidation process. In this way, the catalyst cost and,consequently operation cost can be reduced in the photocatalytic oxidationprocess, and waste recycling and/or minimization in the waste recyclingindustries will be provided. CR - Özyonar F, Karagözoğlu B. “Elektrokoagülasyon prosesi ile tekstil sanayi atiksuyunun aritimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 28(1), 29-37, 2012. CR - Sarayu K, Sandhya S. “Current technologies for biological treatment of textile wastewater-a review”. Applied Biochemical Biotechnolgy, 167(3), 645-661, 2012. CR - Kocaer FO, Alkan U. “Boyar madde içeren tekstil atiksularinin aritim alternatifleri”. Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 7(1), 47-55, 2002. CR - Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, Gholami Z, Amouzgar P. “Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review”. Carbohydrate Polymers, 113, 115-130, 2014. CR - Eren Z, Acar FN. “Uçucu kül adsorpsiyonu ile reaktif boya giderimi”, Pamukkale Üniversitesi Mühendislik Fakültesi Mühendislik Bilimleri Dergisi, 10(2), 253-258, 2004. CR - Verma AK, Dash RR, Bhunia P. “A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters”. Journal of Environmental Management, 93(1), 154-168, 2012. CR - Ertugay N, Acar FN. “Sonokatalitik oksidasyon ile direct blue 71 azo boyasının renk giderimi”. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 3(1), 55-60, 2013. CR - Gürtekin E, Şekerdağ N. “Color removal from textile wastewater with fenton process”. Sigma Mühendislik ve Fen Bilimleri Dergisi, 26(3), 216-226, 2008. CR - Birgül A, Akal Solmaz SK. “Tekstil endüstrisi atıksuları üzerinde ileri oksidasyon ve kimyasal arıtma prosesleri kullanılarak KOİ ve renk gideriminin araştırılması”. Ekoloji, 16(62), 72-80, 2007. CR - Dhanavel S, Nivethaa EAK, Narayanan V, Stephen A. “Photocatalytic activity of chitosan/ZnO nanocomposites for degrading methylene blue”. International Journal of Chemical Techology Research, 6(3), 1880-1882, 2014. CR - Kong JZ, Li AD, Li XY, Zhai HF, Zhang WQ, Gong YP, Li H, Wu D. “Photo-Degradation of methylene blue using ta-doped ZnO nanoparticle”. Journal of Solid State Chemistry, 183, 1359-1364, 2010. CR - Chakrabarti S, Dutta BK. “Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst”. Journal of Hazardous Materials, 112(3), 269-278, 2004. CR - Wang R, Xin JH, Yang Y, Liu H, Xu L, Hu J. “The characteristics and photocatalytic activities of silver doped ZnO nanocrystallites”. Applied Surface Science, 227(1-4), 312-317, 2004. CR - Height MJ, Pratsinis SE, Mekasuwandumrong O. “Ag-ZnO catalysts for UV-Photodegradation of methylene blue”. Applied Catalysis B: Environmental, 63(3-4), 305-312, 2006. CR - Shen W, Li Z, Wang H, Liu Y, Guoa Q, Zhang Y. “Photocatalytic degradation for methylene blue using zinc oxide prepared by codeposition and sol–gel methods”. Journal of Hazardous Materials, 152(1), 172-175, 2008. CR - Whang TJ, Hsieh MT, Chen HH. “Visible-Light photocatalytic degradation of methylene blue with laser-induced Ag/ZnO Nanoparticles”. Applied Surface Science, 258(7), 2796-2801, 2012. CR - International Organization for Standardization “ISO 6341:1996 Water quality - determination of the inhibition of the mobility of Daphnia Magna Straus (Cladocera, Crustacea)”, Geneva, Switzerland, 1996. CR - Nagaraja R, Kottam N, Girija CR, Nagabhushana BM. “Photocatalytic degradation of rhodamine B dye under UV/Solar light using ZnO nanopowder synthesized by solution combustion route”. Powder Technology, 215-216, 91-97, 2012. CR - Konstantinou IK, Albanis TA. “TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review”. Applied Catalysis B: Environmental, 49(1), 1-14, 2004. CR - Daneshvar N, Rasoulifard MH, Khataee AR, Hosseinzadeh F. “Removal of C.I. acid orange 7 from aqueous solution by UV irradiation in the presence of ZnO nanopowder”. Journal of Hazardous Materials, 143(1-2), 95-101, 2007. UR - http://dergipark.org.tr/tr/pub/pajes/issue//377480 L1 - http://dergipark.org.tr/tr/download/article-file/402702 ER -