@article{article_463196, title={Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone}, journal={Natural and Applied Sciences Journal}, volume={2}, pages={27–31}, year={2019}, DOI={10.38061/idunas.463196}, author={Sert, Sema}, keywords={Metal carbonyls; Methanesulfonylhydrazone; Photochemical Reactions.}, abstract={<p>The new complexes, [M(CO)5(msh4)] (Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur. <br /> </p>}, number={1}, publisher={İzmir Demokrasi Üniversitesi}