TY  - JOUR
T1  - Biosorption of Eu(III) onto Narcissus Tazetta L. Leaf Powder
TT  - Eu (III) 'un Narcissus Tazetta L. Yaprak Tozu Üzerine Biyosorpsiyonu
AU  - İnan, Süleyman
AU  - Özkan, Bekir
PY  - 2019
DA  - September
DO  - 10.21205/deufmd.2019216324
JF  - Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi
JO  - DEUFMD
PB  - Dokuz Eylül Üniversitesi
WT  - DergiPark
SN  - 1302-9304
SP  - 955
EP  - 966
VL  - 21
IS  - 63
LA  - en
AB  - In the present study, biosorptionbehaviours of novel biosorbent, NarcissusTazetta L. leaf powder, were investigated for the separation of Eu(III)from aqueous solution. Batch experiments were conducted to examine the effectof various parameters such as contact time, initial pH, initial Eu(III)concentration, biosorbent dosage and temperature on the Eu(III) uptake. Thebiosorption process is fast, and equilibrium was established in 30 min. ofcontact time. It was found that the material has a significant biosorptioncapacity for europium in the pH range of 4-7. The results showed that the biosorptiondata fit Langmuir monolayer isotherm and pseudo-second order kinetic modelwell. Biosorption capacity of leaf powder was obtained as 122.0 mg g-1at pH 7. Thermodynamic analysis indicates that the biosorption was spontaneousand endothermic in nature. Desorption efficiency(%) of 97.17 was achieved insingle step using 0.1 mol L-1 HNO3 solution. Surface areaof the biosorbent and the average pore size were determined as 1.725 mg g-1and 1.75 nm, respectively. The critical functional groups -CH, C-O, O-H, C=Oand COO- which may have taken part for the biosorption were identified byinfrared spectra data. It was deduced that N.Tazetta leaf powder can be used as an effective, costless, and eco-friendlybiosorbent for the separation and recovery of Eu(III) from aqueous solution.
KW  - Narcissus Tazetta
KW  - Europium
KW  - Rare Earths
KW  - Biosorption
KW  - Separation
N2  - Buçalışmada, yeni bir biyosorbent olan NarcissusTazetta L. yaprak tozunun sulu çözeltilerden Eu(III) iyonlarınınayrılmasında biyosorpsiyon davranışları incelenmiştir. Eu(III) alımında temassüresi, başlangıç pH’sı, başlangıç Eu(III) derişimi, biyosorbent dozajı vesıcaklık gibi çeşitli parametrelerin etkisini incelemek için kesikli denemeleryürütülmüştür. Biyosorpsiyon prosesi hızlıdır ve 30 dakikalık temas süresisonunda dengeye ulaşılmıştır. pH 4-7 aralığında materyalin Eu(III) için önemlibir biyosorpsiyon kapasitesine sahip olduğu bulunmuştur. Biyosorpsiyon verisiLangmuir tek tabaka izotermi ve yalancı ikinci derece kinetik model ile uyumgöstermiştir. pH 7’de yaprak tozunun biyosorpsiyon kapasitesi 122.0 mg g-1olarak bulunmuştur. Termodinamik analiz biyosorpsiyonun kendiliğindengerçekleştiğini ve endotermik yapıda olduğunu göstermiştir. 0.1 mol L-1HNO3 çözeltisi ile tek kademede %97.17’lik desorpsiyon verimineulaşılmıştır. Biyosorbentin yüzey alanı ve ortalama por çapı sırasıyla 1.725 mgg-1 ve 1.75 nm olarak tespit edilmiştir. Biyosorpsiyonda rol almış olabilen-CH, C-O, O-H, C=O ve COO- gibi kritik fonksiyonel gruplar kızıl ötesispektroskopisi ile aydınlatılmıştır. Suluçözeltilerden Eu(III) ayrılması ve kazanılmasında N. Tazetta yaprak tozunun etkili, maliyetsiz ve çevre dostu birbiyosorbent olduğu sonucuna varılmıştır.
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UR  - https://doi.org/10.21205/deufmd.2019216324
L1  - https://dergipark.org.tr/tr/download/article-file/810957
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