TY  - JOUR
T1  - İki çekirdekli rutenyum II  aren komplekslerinin ketonların transfer hidrojenasyonuna uygulanması
TT  - Application of dinuclear ruthenium II  arene complexes in transfer hydrogenation of ketones
AU  - Meriç, Nermin
AU  - Kayan, Cezmi
AU  - Aydemir, Murat
AU  - Ocak, Yusuf Selim
AU  - Baysal, Akın
AU  - Temel, Hamdi
PY  - 2013
DA  - June
JF  - Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi
JO  - DUFED
PB  - Dicle Üniversitesi
WT  - DergiPark
SN  - 2146-4693
SP  - 1
EP  - 8
VL  - 2
IS  - 1
LA  - tr
AB  - Geçifl metal katalizörlerinin transfer hidrojenasyon reaksiyonuyla organik substratlara hidrojen katılmasıveya çıkarılması önemli bir sentetik araçtır. Bu amaçla, N3,N3'-di-2-hidroksibenziliden-[2,2']bipiridinil3,3'-diamin bilefliğinden elde edilen bir P-O ligandı olan N3,N3'-di-2- difenilfosfino benziliden-[2,2']bipiridinil3,3'-diaminin bir dizi metal kompleksi sentezlendi. N3,N3'-di-2- difenilfosfino benziliden-[2,2']bipiridinil3,3'-diaminin [Ru η-benzen  µ-Cl Cl] yada [Ru η-p-simen  µ-Cl Cl]2 ile reaksiyonu köprülü ve ikiçekirdekli [CH16N4{OPPh2-Ru η6-benzen Cl2}2] 1 ve [Ckomplekslerini vermektedir. Ru II -bisfosfinit kompleksleri ayrıca basit birçok alkil ve aril alkil ketonuntransfer hidrojenasyonunda katalizör olarak kullanıldı ve iyi düzeyde  % 99'a kadar  dönüflümler eldeedildi
KW  - Bis fosfinit
KW  - Transfer hidrojenasyon
KW  - Rutenyum
KW  - Kataliz
KW  - Keton
N2  - The ability of transition metal catalysts to add or remove hydrogen from organic substrates by transferhydrogenation process is a valuable synthetic tool. For this aim, a series of metal complexes with a P-Oligand, N3,N3'-di-2- diphenylphosphino benzylidene-[2,2']bipyridinyl-3,3'-diamine derived from N3,N3'di-2-hydroxybenzylidene-[2,2']bipyridinyl-3,3'-diamine were synthesized. Reaction of N3,N3'-di-2 diphenylphosphino benzylidene-[2,2']bipyridinyl-3,3'-diamine with [Ru η6-benzene  µ-Cl Cl]2 or [Ru η6p-cymene  µ-Cl Cl]2 gave bridged dinuclear complexes [C24H16N4{OPPh2-Ru η6-benzene Cl2}2] 1 and[C24H16N4{OPPh2-Ru η6-p-cymene Cl}2] 2, respectively. Ru II -bisphosphinite complexes have also beenused as catalysts for the transfer hydrogenation of a variety of simple alkyl and aryl alkyl ketones and goodconversions  up to 99 %  were obtained
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UR  - https://dergipark.org.tr/tr/pub/dufed/issue//698248
L1  - https://dergipark.org.tr/tr/download/article-file/992015
ER  -