Fabrication of Ceramics via Silicon Based Organic Polimer: Polymethylsilsesquioxane

Yıl 2014, Cilt: 14 Sayı: 3, 345 - 352, 01.12.2014

İsrafil Küçük Şenol Avcı Recep Artır

Öz

Generally, most of the conventional polysiloxanes (silicone resins) are crucial to be used as ceramic precursors owing to their main chain decompositions. These polymers have comprehensive application areas such as medicine, electronics, and defense industry. In recent years, however, diverse types of polysiloxanes with high ceramic yields, which formed dense cross-linking at relatively low temperatures, were developed. Silicon oxide carbon (SiOC) ceramic materials was synthesized by using the Polymethylsilsesquioxane (PMSQ) as a ceramic precursor. Not only the obtained ceramic materials were high strentgh, but also they can be used in medicine, refractory industry and engineering applications. In this study, the aim is to investigate PMSQ polimer, its conversion methods to ceramics, characterization of fabricated ceramics, mechanical properties, advantages and disadvantages and application areas. © Afyon Kocatepe Üniversitesi

Anahtar Kelimeler

SiOC; Polymethylsilsesquioxane; Ceramic fabrication; Organic polymers; Pyrolysis

Silikon Bazlı Organik Polimer Polimetil-Siloksan (PMSQ)'ın Seramik Üretiminde Kullanımı(025755) (345-352)

Öz

Literatürde, geleneksel poli-siloksanların (silikon bazlı) büyük bir çoğunluğunun, ana zinciri oluşturan bağlarının ayrıştırılmasının zorluğundan dolayı, seramik malzeme üretiminde kullanılması yaygın olarak yer almamaktadır. Bu polimer malzemeler genellikle, sağlık, elektronik sanayi ve savunma sanayi gibi alanlarda yaygın kullanıma sahiptir. Fakat son yıllarda, nispeten düşük sıcaklıklarda elde edilen çeşitli poli-siloksan polimerlerin seramik üretiminde kullanılması ile ilgili gelişmeler kaydedilmiştir. Polimetilsiloksan (PMSQ) polimeri kullanılarak, silikon oksi-karbon (SiOC) seramik malzemesi elde edilebilmektedir. Elde edilen bu ürün dayanıklılığı yüksek olup, tıpta, refrakter sanayinde ve mühendislikte çeşitli uygulamalar kullanılmaktadır. Bu çalışmada, organik polimer olarak bilinen ve kullanılan (PMSQ) malzemenin seramik malzemeye dönüştürülmesinde kullanılan yöntemler, elde edilen seramik yapıların karakterizasyonu, mekanik özellikleri, avantajları ve dezavantajları ve kullanım alanları incelenmiştir

Anahtar Kelimeler

SiOC; Polimetilsiloksan; Seramik

Kaynakça

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