DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS

Funda Tay; Murat Duran; Cihan İspir; Şeref Demirayak

doi:10.18038/btda.96904

EN TR

DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS

Abstract

In this work, the effect of substituents on the acidity constants of some acetamide derivatives was investigated. The acidity constants of nine acetamide derivatives were determined at 25 °C using a UV spectrophotometric method. When the molecules possessed different substituents the values of the acidity constants changed from 6.01 to 8.22 for the first protonation and from 3.07 to 4.73 for the second protonation. The first protonation under these circumstances was observed to occur on the nitrogen atom of the 2-mercaptoimidazole ring. The second protonation was observed to occur on the nitrogen atom of the thiazole ring.

Keywords

İmidazol,Tiyazol; Asetamit; Protonlanma yolları; UV spektroskopi; pKa

References

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Details

Primary Language

English

Subjects

-

Journal Section

-

Authors

Funda Tay

Murat Duran

Cihan İspir This is me

Şeref Demirayak

Publication Date

July 14, 2016

Submission Date

January 6, 2016

Acceptance Date

-

Published in Issue

Year 2016 Volume: 17 Number: 2

DOI

https://doi.org/10.18038/btda.96904

IZ

https://izlik.org/JA23NZ58UX

APA

Tay, F., Duran, M., İspir, C., & Demirayak, Ş. (2016). DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 17(2), 263-272. https://doi.org/10.18038/btda.96904

AMA

1.Tay F, Duran M, İspir C, Demirayak Ş. DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS. AUJST-A. 2016;17(2):263-272. doi:10.18038/btda.96904

Chicago

Tay, Funda, Murat Duran, Cihan İspir, and Şeref Demirayak. 2016. “DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 (2): 263-72. https://doi.org/10.18038/btda.96904.

EndNote

Tay F, Duran M, İspir C, Demirayak Ş (August 1, 2016) DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 2 263–272.

IEEE

[1]F. Tay, M. Duran, C. İspir, and Ş. Demirayak, “DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS”, AUJST-A, vol. 17, no. 2, pp. 263–272, Aug. 2016, doi: 10.18038/btda.96904.

ISNAD

Tay, Funda - Duran, Murat - İspir, Cihan - Demirayak, Şeref. “DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17/2 (August 1, 2016): 263-272. https://doi.org/10.18038/btda.96904.

JAMA

1.Tay F, Duran M, İspir C, Demirayak Ş. DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS. AUJST-A. 2016;17:263–272.

MLA

Tay, Funda, et al. “DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 17, no. 2, Aug. 2016, pp. 263-72, doi:10.18038/btda.96904.

Vancouver

1.Funda Tay, Murat Duran, Cihan İspir, Şeref Demirayak. DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS. AUJST-A. 2016 Aug. 1;17(2):263-72. doi:10.18038/btda.96904

DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS

Abstract

Keywords

DETERMINATION AND EVALUATION OF ACIDITY CONSTANTS OF SOME IMIDAZOLE AND THIAZOLE LINKED ACETAMIDE COMPOUNDS

Abstract

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

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