Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100

Elif Akbay; Ilay Aytek

doi:10.18038/btda.18655

EN TR

Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100

Abstract

The kinetics of esterification of salicylic acid with amyl alcohol has been studied batchwise in the presence of Lewatit MonoPlus S-100 as heterogeneous catalyst. The kinetic behavior of the reaction has been tested by three different models: the quasi-homogeneous model, the Eley–Rideal model and the Langmuir–Hinselwood model. L-H model fits the experimental data best among the others.

Keywords: Esterification, Salicylic Acid, n-Amyl Alcohol, Kinetic modeling, Lewatit MonoPlus S-100

References

G.D. Yadav, P.H. Mehta, Ind. Eng. Chem. Res. 33 (1994), Heterogeneous Catalysis in Esterication Reactions: Preparation of Acetate and Cyclohexyl Acetate by Using a Variety of Solid Acidic Catalysts 2198–2208.
J. Lilja, J. Aumo, T. Salmi, D. Murzin, P. Maki-Arvela, M. Sundell, K. Ekman, R. Peltonen, H. Vainio, Hydrogenation of citral over a polymer fibre catalyst, Appl. Catal. A: Gen. 228 (2002) 253– 267.
C.E. Leyes, D.F. Othmer, Esterification of Butanol and Acetic Acid, Industrial and Engineering Chemistry 37 (10) (1945) 968-975.
M.R. Altıokka, A. Cıtak, Appl. Catal. A: Gen. 239 (2003), Kinetics Study of Esterification of Acetic Acid With Isobutanol in The Presence of Amberlite Catalyst, 141–148.
M.R. Altıokka, H.L. Hosgün, Ind. Eng. Chem. Res. 46 (2007), Kinetics of Hydrolysis of Benzaldehyde Dimethyl Acetal over Amberlite IR-120, 1058–1062.
Tanabe, Misono, Ono, Hattori, New Solid Acid and Bases, Kodan-sha/Elsevier Science, Tokyo/Amsterdam, 1989.
A.E.R.S. Khder, Appl. Catal. A: Gen. 343 (1–2) (2008), Preparation, characterization and catalytic activity of tin oxide-supported 12- tungstophosphoric acid as a solid catalyst, 109–116.
A. Charkrabati, M.M. Sharma, React. Polym. 20 (1993), Cationic ion exchange resins as catalyst, 1–45. [9] M.M. Sharma, React. Funct. Polym. 26 (1995), Some novel aspects of cationic ion-exchange resins as catalysts, 3–23.
S.B. Valdeilson, C.L. Ivoneide, F.A.C. Garcia, S.C.L. Dias, J.A. Dias, Catal. Today 133–135 (2008), Kinetics of esterification of acetic acid with n-amyl alcohol in the presence of Amberlyst-36, 106–112.
T.L. Marker, G.A. Funck, T. Barger, U. Hammershaimb, US Patent, Esterification of acetic acid by isoamylic alcohol over catalytic membranes of poly(vinyl alcohol) containing sulfonic acid groups, 5504258 (1996).

D.E. Hendriksen, J.R. Lattner, M.J.G. Janssen, US Patent, Alkylation process using zeolite beta, 6002057 (1999).
R. Chitnis, M.M. Sharma, React. Funct. Polym. 32 (1997), Industrial applications of acid-treated clays as catalysts, 93–115.
J.T. Kloprogge, J. Porous Mater. 5 (1998), Synthetics of smectites and porous pillared clay catalysts, 5–41.
C.S.M. Pereira, S.P. Pinho, V.M.T.M. Silva, A.E. Rodrigues, Ind. Eng. Chem. Res. 47 (2008), Multifunctional Reactor for the Synthesis of Dimethylacetal, 1453–1463.
V.T.M.M. Silva, A.E. Rodrigues, Chem. Eng. Sci. 61 (2006), Kinetic study of transesterification of methyl acetate with n-butanol catalyzed by NKC-9, 316–331.
Y. Fuchigami, J. Chem. Eng. Jpn. 23 (1990), Hydrolysis of Methyl Acetate in Distillation Column, 354–358.
Z.P. Xu, K.T. Chuang, Chem. Eng. Sci. 52 (17) (1997), inetic of Acetic Acid Esterication Over Ion Exchange Catalysts 3011–3017.
J. Gangadwala, S.Mankar, S.M.Mahajani, A. Kienle, E. Stein, Ind. Eng. Chem. Res. 42 (2003), Esterification of acetic acid with butanol in the presence of ion-exchange resins as catalysts 2146– 2155. [20] B. Erdem, M. Cebe, Korean J. Chem. Eng. 23 (6) (2006), Kinetics of Esterification of Propionic Acid with n-amyl Alcohol in the Presence of Cation Exchange Resin, 896–901.
M.T. Sanz, R. Murga, S. Beltran, J.L. Cabezas, Ind. Eng. Chem. Res. 41 (2002) 512–517.
M.R. Altıokka, E. Ödes¸ Appl. Catal. A: Gen. 362 (2009), Reaction kinetics of the catalytic esterification of acrylic acid with propylene glycol, 115–120.
W.T. Liu, C.S. Tan, Ind. Eng. Chem. Res. 40 (2001), eactive-extraction of 2,3-butanediol from Fermentation Broth by Propionaldehyde: Equilibrium and Kinetic Study, 3281–3286.
S.R. Kirumakki, N Nagaraju, K.V.V.S.B.S.R Murthy, S. Narayanan, Appl. Catal. A: Gen. 226 (1– 2) (2002), Esterification of salicylic acid over zeolites using dimethyl carbonate, 175–182.
H. Shi, W. Zhu, H. Li, H. Liu, M. Zhang, Y. Yan, Z. Wang, Catal. Comm. 11 (7) (2010), Syntheses of novel halogen-free Brİnsted–Lewis acidic ionic liquid catalysts and their applications for synthesis of methyl caprylate, 588–591.
F.F. Bamoharrama, M.M. Heravib, M. Roshania, M. Jahangira, A. Ghariba, Appl. Catal. A: Gen. 302 (1) (2006), H14[NaP5W30O110]: A heteropoly acid catalyzed acetylation of alcohols and phenols in acetic anhydride, 42–47.
F.F. Bamoharram, M.M. Heravi, J. Ebrahimi, A. Ahmadpour, M. Zebarjad, Chin. J. Catal. 32 (5) (2011), Synthesis of Ibuprofen Using Silica-Supported Preyssler Nanoparticles as an Eco-Friendly, Inexpensive, and Efficient Catalyst, 782–788.
Y. Zhenga, X. Su, X. Zhang, W. Wei, Y. Sun, Stud. Surf. Sci. Catal. 156 (2005), Enhanced magneto-optical response in dumbbell like Ag-CoFe2O4 nanoparticle pairs, 205–212.
H.S. Fogler, Elements of Chemical Reaction Engineering, third ed., Prentice Hall, New Jersey, 1999. [31] M.J. Lee, J.Y. Chiu, H.M. Lin, Ind. Eng. Chem. Res. 41 (2002), Kinetics of Catalytic Esterification of Propionic Acid and n-Butanol over Amberlyst 35, 2882–2887.
H.T.R. Teo, B. Saha, J. Catal. 228 (2004), Heterogeneous catalysed esterification of acetic acid
with isoamyl alcohol: kinetic studies, 174–182.
M.J. Lee, H.T. Wu, H.M. Lin, Ind. Eng. Chem. Res. 39 (2000), Kinetics of Catalytic Esterification of Acetic Acid and Amyl Alcohol over Dowex, Ind. Eng. Chem. Res., 4094–4099.
M.J. Lee, H.T. Wu, C.H. Kang, H.M. Lin, J. Chin. Inst. Chem. Eng. 30 (2) (1999), Kinetic Behavior of Amyl Acetate Synthesis Catalyzed by Acidic Cation Exchange Resin, 117–122.
A. Palani, A. Pandurangan, J. Mol. Catal. A: Chem. 226 (2005), Esterification of acetic acid over mesoporous Al-MCM-41 molecular sieves, 129–134.
P. Delgado, M.T. Sanz, S. Beltran, Chem. Eng. J. 126 (2007), Kinetic study for esterification of lactic acid with ethanol and hydrolysis of ethylactate, 111–118.
V.J. Cruz, J.F. Izquierdo, F. Cunill, J. Tejero, M. Iborra, C. Fite, R. Bringue, React. Funct. Polym. 67 (3) (2007), Etherification of tert-Amyl Alcohol with Methanol over Ion-Exchange Resin, 210–224. [37] M.P. Titus, M. Bausach, J. Tejero, M. Iborra, C. Fite, F. Cunill, J.F. Izquierdo, Appl. Catal. A: Gen. 323 (2007), Liquid-phase synthesis of isopropyl tert-butyl ether by addition of 2-propanol to isobutene on the oversulfonated ion-exchange resin Amberlyst-35, 38–50.
H.T.R. Teo, B. Saha, J. of Catalysis 228 (2004), Heterogeneous catalysed esterification of acetic acid with isoamyl alcohol: kinetic studies, 174–182.

Details

Primary Language

English

Subjects

-

Journal Section

-

Authors

Elif Akbay

Ilay Aytek This is me

Publication Date

April 25, 2016

Submission Date

April 23, 2016

Acceptance Date

-

Published in Issue

Year 2016 Volume: 17 Number: 1

DOI

https://doi.org/10.18038/btda.18655

IZ

https://izlik.org/JA79LT34EA

APA

Akbay, E., & Aytek, I. (2016). Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 17(1), 25-36. https://doi.org/10.18038/btda.18655

AMA

1.Akbay E, Aytek I. Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100. AUJST-A. 2016;17(1):25-36. doi:10.18038/btda.18655

Chicago

Akbay, Elif, and Ilay Aytek. 2016. “Kinetics of Esterification of Salicylic Acid With N-Amyl Alcohol in the Presence of Lewatit MonoPlus S-100”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 (1): 25-36. https://doi.org/10.18038/btda.18655.

EndNote

Akbay E, Aytek I (June 1, 2016) Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 1 25–36.

IEEE

[1]E. Akbay and I. Aytek, “Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100”, AUJST-A, vol. 17, no. 1, pp. 25–36, June 2016, doi: 10.18038/btda.18655.

ISNAD

Akbay, Elif - Aytek, Ilay. “Kinetics of Esterification of Salicylic Acid With N-Amyl Alcohol in the Presence of Lewatit MonoPlus S-100”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17/1 (June 1, 2016): 25-36. https://doi.org/10.18038/btda.18655.

JAMA

1.Akbay E, Aytek I. Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100. AUJST-A. 2016;17:25–36.

MLA

Akbay, Elif, and Ilay Aytek. “Kinetics of Esterification of Salicylic Acid With N-Amyl Alcohol in the Presence of Lewatit MonoPlus S-100”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 17, no. 1, June 2016, pp. 25-36, doi:10.18038/btda.18655.

Vancouver

1.Elif Akbay, Ilay Aytek. Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100. AUJST-A. 2016 Jun. 1;17(1):25-36. doi:10.18038/btda.18655

Cited By

Post-synthetically modified hierarchical Mordenite and ZSM-5 zeolite and their catalytic performances in benzylation of acetic acid to benzyl acetate

Journal of Materials Science

https://doi.org/10.1007/s10853-023-08770-3

Kinetics of esterification of salicylic acid with n-amyl alcohol in the presence of Lewatit MonoPlus S-100

Abstract

KINETICS OF ESTERIFICATION OF SALICYLIC ACID WITH N-AMYL ALCOHOL IN THE PRESENCE OF LEWATIT MONOPLUS S-100

Abstract

Keywords

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

Post-synthetically modified hierarchical Mordenite and ZSM-5 zeolite and their catalytic performances in benzylation of acetic acid to benzyl acetate