Research Article

RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES

Volume: 18 Number: 5 December 31, 2017
M.Mürşit Temüz
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Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering Cover Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering
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AKRİLOMORFOLİN İLE 2-HİDROKSİETİL METAKRİLAT'IN RADİKAL POLİMERİZASYONU: MONOMER REAKTİVİTE ORANLARI VE TERMAL ÖZELLİKLERİ

Abstract

                Poli (akriloilmorfolin-co-2-hidroksietil metakrilat) geleneksel serbest radikal polimerizasyonu ile hazırlandı. Akriloilmorfolin (ACM) ve 2-hidroksietil metakrilat (HEMA) monomerleriyle kopolimerizasyon, başlatıcı olarak 2,2'-azobisizobutironitril (AIBN) kullanılarak 60 ° C'de tetrahidrofuran çözeltisi içinde gerçekleştirildi. Kopolimerler, FT-IR, 1H ve 13C nükleer manyetik rezonans (NMR) ile karakterize edildi. Kopolimerlerin monomer bileşimleri, elemental analizin azot sonuçlarıyla tahmin edildi. Kopolimerdeki ACM(r1) ve HEMA(r2) monomerlerinin reaktivite oranları, çeşitli yöntemlerle hesaplandı. Bu yöntemlere göre, r1 değeri 1.73-2.01 ve r2 değeri 0.48-0.74'tür. Kopolimerlerin termal özelliklerini araştırmak için Termogravimetrik analiz kullanıldı.


Keywords

acryloylmorpholine,2-hydroxyethyl methacrylate

References

  1. [1] Elpida Karra, Ionna Petrakau, Paraskevi Driva, Marinos Pitsikatis, Macromolecules, 2013; Volume 9, Issue 2, 68-77 [2] G. Jayasimha Reddy, M. Mohan Reddy*, S. Venkata Naidu* Indian Journal of Advances in Chemical Science, 2014; 2(4) , 264-270 [3] N.L. Zutty, J.A. Faucher, J.Polym.Sci., 1962; 60, s36 [4] P.J. Flory, Principles of Polymer Chemistry Cornell University Press, Ithaca, 1953 [5] Hooda Sunita, Goyal Ashok Kubar, Journal of the Indian Chemical Society,2008; Volume:85, Issue:8, Pages:818-824 [6] Shidan Cummings, Yujie Zhang, Niousha Kazemi, Alexander Penlids, Marc A. Dube, J. Appl. Poly. Scı., 2016; 133, 44014 [7] Mehmet Coşkun, M. Mürşit Temüz and Misir A. Ahmedov, Macromolecular Reports, 1996; A33, 409-421 [8] Mehmet Mürşit Temüz, Mehmet Coşkun, J. Poly. Sci. Part A: Poly. Chem.,2005; 43, 3771-3777 [9] Nevin Çankaya and M. Mürşit Temüz, Cellulose Chem. Technol.,2012; 46(9-10), 551-558 [10] Nevin Çankaya and M. Mürşit Temüz, Cellulose Chem. Technol.,2014; 48(3-4), 209-215 [11] Finemann M., Ross S., J. Polym. Sci. Part A: Gen Pap,1964; 2, 1687 [12] Yezrielev A. L., Brokhina E. L., Roskin Y. S., Vysokomol Soedin A, 1969; 11, 1670 [13] Kelen T., Tüdos F., J. Macromol. Sci. Chem.,1975; 9, 1 [14] Kelen T., Tüdos F., J. Macromol. Sci. Chem.,1981; 16, 1238

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Publication Date

December 31, 2017

Submission Date

April 17, 2017

Acceptance Date

September 7, 2017

Published in Issue

Year 2017 Volume: 18 Number: 5

DOI

https://doi.org/10.18038/aubtda.306626

IZ

https://izlik.org/JA66GK38TY

Cite

RIS / Bibtex
APA
Temüz, M. (2017). RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 18(5), 929-938. https://doi.org/10.18038/aubtda.306626
AMA
1.Temüz M. RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES. AUJST-A. 2017;18(5):929-938. doi:10.18038/aubtda.306626
Chicago
Temüz, M.Mürşit. 2017. “RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 (5): 929-38. https://doi.org/10.18038/aubtda.306626.
EndNote
Temüz M (December 1, 2017) RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 5 929–938.
IEEE
[1]M. Temüz, “RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES”, AUJST-A, vol. 18, no. 5, pp. 929–938, Dec. 2017, doi: 10.18038/aubtda.306626.
ISNAD
Temüz, M.Mürşit. “RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18/5 (December 1, 2017): 929-938. https://doi.org/10.18038/aubtda.306626.
JAMA
1.Temüz M. RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES. AUJST-A. 2017;18:929–938.
MLA
Temüz, M.Mürşit. “RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 18, no. 5, Dec. 2017, pp. 929-38, doi:10.18038/aubtda.306626.
Vancouver
1.M.Mürşit Temüz. RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES. AUJST-A. 2017 Dec. 1;18(5):929-38. doi:10.18038/aubtda.306626

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