CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM

Evrim Hür; Andaç Arslan; Müjdat Çağlar

doi:10.18038/btd-a.27481

EN TR

CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM

Abstract

Poly(N-ethylaniline) (PNEA) and poly(aniline-co-N-ethylaniline) (co-PNEA) films have been synthesized on a pencil graphite electrode (PGE) by using cyclic voltammetry (CV) in an acetonitrile (ACN) solution of tetraethylammonium tetrafluoroborate (TEABF₄). The electrochemical properties of the electrodeposited coatings have been characterized using CV method in monomer free solution. The surface morphologies of the films have been investigated by Scanning Electron Microscope (SEM). The electrochemical storage properties of polymer coated PGE (PGE/PNEA and PGE/co-PNEA) have been evaluated by CV, electrochemical impedance spectroscopy (EIS), galvanostatic charge-discharge and repeating chronopotentiometry tests. The highest specific capacitance values of PGE/PNEA and PGE/co-PNEA have obtained as 1112.72 mF g^-1 and 1830.00 mF g^-1 at 0.01 mA by using galvanostatic charge-discharge, respectively. According to repeating chronopotentiometry tests, it is observed that charge-discharge stability of PGE/PNEA is longer than PGE/co-PNEA

Keywords

Conducting Polymer; Polyaniline; Electropolymerization; Energy Storage; Supercapacitor

References

Arbizzani, C., Mastragostino, M., Meneghello, L., Supercapacitors: A Comparative Study”, Electrochimica doi:1016/0013-4686(95)00289-Q. 41, 21
Arslan, A., Hür, E., (2012) “Supercapacitor
Applications of Polyaniline and Poly(N- methylaniline) Coated Pencil Graphite Electrode”, Electrochemical Science, 7, 12558-12572. Journal
Bakhmatyuk, B.P., Venhryn, B.Y., Grygorchak, I.I., Micov, M.M., (2008) “Influence of
Chemical Modification Carbon Surface on Characteristics of Supercapacitors”, Sources, doi:1016/j.jpowsour.2008.02.045. 890-8
Bhadra, S., Chattopadhyay, S., Singha, N.K., Khastgir, D., (2008) “Improvement of Conductivity
Synthesized Polyaniline”, Applied Polymer Science, 108, 57-64. doi:1002/app.26926. Electrochemically Journal of
Bhadra, S., Khastgir, D., Singha, N.K., Lee, J.H., (2009) Processing Polyaniline”, Science, doi:1016/j.progpolymsci.2009.04.003. 783-8
Cebeci, F.C., Geyik, H., Sezer, E., Saraç, A.S., (2007)
Characterization and Impedance Studies on Novel Thiophene-Nonylbithiazole- Thiophene Comonomer”, Electroanalytical Chemistry, 610, 113- doi:10.1016/j.jelechem.2007.07.012.

Devaraj, S., Munichandraiah, M., (2007)
“Electrochemical Supercapacitor Studies of Synthesized by Microemulsion Method and The Effect of Annealing”, Journal of The Electrochemical Society, 154, A80- A doi:10.1149/1.2404775.
Ganesh, B., Kalpana D., Renganathan, N.G., (2008)
Conducting Polymer Gel Electrolyte for Electric Double Layer Capacitors”, Ionics, 14, 0230- Based Proton 339-3 doi:1007/s11581-008
Genies, E.M., Picart, S., (1995) “Polypyrrole- Latex Electrochemical
Spectroelectrochemical Synthetic doi:1016/0379-6779(94)02507-U. and Studies”, 165-1 69,
Genies, E.M., Syed, A.A., Tsintavis, C., (1985)
“Electrochemical Study of Polyaniline in Aqueous and Organic Medium - Redox and Crystals and Liquid Crystals, 121, 181- 1 doi:10.1080/00268948508074858.
Genies, E.M., Tsintavis, C., (1985) “Redox
Mechanism and Electrochemical-Behavior of Polyaniline Deposits”, Journal of Electroanalytical Chemistry, 195, 109- doi:10.1016/0022-0728(85)80009-7.
Hashmi, S.A., (2004) “Supercapacitor: An Emerging
Academy Science Letters-India, 27, 27-46. National Hashmi, S.A., Latham, R.J., Linford, R.G., Schlindwein, W.S., Electrolyte Based Solid State Redox Supercapacitors with Poly (3-Methyl Thiophene) and Polypyrrole Conducting Polymer Electrodes”, Ionics, 3, 177-183. doi:1007/BF02375614. “Polymer
Heli, H., Yadegari, H., Jabbari, A., (2012) “Graphene aminophenol)
Supercapacitor Applications”, Materials Chemistry and Physic, doi:1016/j.matchemphys.2012.02.065. 134, 21-25.
Hu, C.C., Chu, C.H., (2001) “Electrochemical Impedance
Polyaniline-coated Graphite Electrodes for Electrochemical Capacitors – Effects of Film Coverage/Thickness and Anions”, Journal of Electroanalytical Chemistry, 503, 0728(01)00385-0. of 105- doi:1016/S0022
Hu, C.C., Chu, C.H., (2009) “Electrochemical and Textural Characterization of Iridium- Doped
Electrochemical Capacitors”, Materials Chemistry and Physics, 65, 329-338. doi:1016/S0254-0584(00)00254-6. for
Hu, Y., Zhu, Z., Wang, J., Chen, Z., (2011)
“Synthesis of Layered Birnessite-Type Manganese Oxide Thin Films on Plastic Substrates by Chemical Bath Deposition for Flexible Transparent Supercapacitors”, Journal of Alloys and Compounds, 509, 10234-10240. doi:1016/j.jallcom.2011.08.080. Huggins, R.A., “Supercapacitors”,
Transactions of The Royal Society A- Mathematical Physical and Engineering Sciences, doi:1098/rsta.1996.0064. R., Philosophical 1555-1566.
Khomenko, V., Raymundo-Pinero, E., Beguin, F., Graphite/AC Electrolyte”, Journal of Power Sources, 177,643-651. Density Organic in doi:1016/j.jpowsour.2007.11.101.
Kim, H.S., Popov, B.N., (2003) “Synthesis and Characterization of MnO2-based Mixed
Oxides as Supercapacitors”, Journal of The Electrochemical Society, 150, D56- D doi:10.1149/1.1541675.
Kotz, R., Carlen, M., (2000) “Principles and Applications
Capacitors”, Electrochimica Acta, 45, 2483-2498. doi:1016/S0013-4686(00)00354-6. Laforgue, A., (2011) “All-textile Flexible
Supercapacitors using Electrospun Poly(3,4- ethylenedioxythiophene) Journal of Power Sources, 196, 559-564. doi:1016/j.jpowsour.2010.07.007.
Lota, K., Khomenko, V., Frackowiak, E., (2004) “Capacitance ethylenedioxythiophene)/Carbon Nanotubes
Composites”, Journal of Physics and Chemistry of Solids, doi:1016/j.jpcs.2003.10.051. 65, 295-301.
Ma, R.Z., Liang, J., Wei, B.Q., Zhang, B., Xu, C.L., Wu, C.L., (1999) “Study of Electrochemical
Carbon Nanotube Electrodes”, Journal of Power doi:1016/S0378-7753(99)00252-9. 84, 126
Michael, I., Prabaharan, S.R.S., (2004) “High
Voltage Electrochemical Double Layer Capacitors using Conductive Carbons as Additives”, Journal of Power Sources, 136,250-256. doi:1016/j.jpowsour.2004.03.006.
Mujawar, S.H., Ambade, S.B., Battumur, T., Ambade, R.B., “Electropolymerization of Polyaniline on Titanium Supercapacitor Application”, Electrochimica Nanotubes for 56, 4462-4466.
Naoi, K., Kawase, K.I., Mori, M., Komiyama, M., (1997) “Electrochemistry of Poly(2,2'- dithiodianiline): A New Class of High Energy
Interconnected with S-S bonds”, Journal of the Electrochemical Society, 144, L173- L1 doi:10.1149/1.1837715. Polymer
Nishino, A., (1996) “Capacitors: Operating
Principles, Current Market and Technical Trends”, Journal of Power Sources, 60, 137- doi:1016/S0378-7753(96)80003-6.
Pandolfo, A.G., Hollenkamp, A.F., (2006)
“Carbon Properties And Their Role In Supercapacitors”, Sources, doi:1016/j.jpowsour.2006.02.065. 11
Patil, U.M., Kulkarni, S.B., Jamadede, V.S., Lokhande, C.D., (2011) “Chemically
Synthesized Hydrous Ruo2Thin Films for Supercapacitor Application”, Journal of Alloys and Compounds, 509, 1677-1682. doi:1016/j.jallcom.2010.09.133.
Portet, C., Chmiola, J., Gogotsi, Y., Park, S., Lian, K., Characterizations of Carbon Nanomaterials by The Cavity Microelectrode Technique”, Electrochimica Acta, doi:1016/j.electacta.2008.05.019. 53, 7675-7680.
Prasad, K.R., Munichandraiah, N., (2002)
“Fabrication and Evaluation of 450 F Electrochemical Redox Supercapacitors using Inexpensive and High-Performance, Polyaniline Electrodes”, Journal of Power Sources, 112, 443-451. doi:1016/S0378-7753(02)00419-6.
Şahin, Y., Perçin, S., Özkan, G., (2003a)
“Electrochemical Synthesis of Poly(2- iodoaniline) iodoaniline) in Acetonitrile”, Journal of Applied Polymer Science, 89, 1652-1658. doi:1002/app.12395. Poly(aniline-co-2
Şahin, Y., Perçin, S., Şahin, M., Özkan, G., (2003b) “Electrochemical Preparation of
Poly(2-bromoaniline) and Poly(aniline-co- 2-bromoaniline) in Acetonitrile” Journal of Applied Polymer Science, 90, 2460- 24 doi:10.1002/app.12994.
Şahin, Y., Perçin, S., Şahin, M., Özkan, G., (2004) “Electrochemical Polymerization of
Anilines and Copolymers with Aniline”, Journal of Applied Polymer Science, 9, 2302-2312. doi:10.1002/app.13367.
Saraç, A.S., Doğru, E., Ateş, M., Parlak, E.A., (2006) “Electrochemical Synthesis of N- Methylpyrrole Copolymer Microelectrodes, Characterization”, Chemistry, 30, 401-408. Carbon and Their Turkish Journal of
Sarangapani, S., Tilak, B.V., Chen, C.P., (1996)
“Materials For Electrochemical Capacitors -Theoretical and Experimental Constraints”, Journal of Electrochemical Society, 143, 3791-3799. doi:10.1149/1.1837291.
Sen, P., De, A., (2010) “Electrochemical Performances ethylenedioxythiophene)-NiFe2O4 Nanocomposite
Supercapacitor”, Electrochimica Acta, 55, 4677-4684. doi:1016/j.electacta.2010.03.077. for
Sharma, R.K., Oh, H.S., Shul, Y.G., Kim, H.S., (2007)
Structured, Manganese Oxide Composite Electrode Supercapacitor”, Sources, doi:1016/j.jpowsour.2007.08.076. 1024-1028. 173,
Sharma, R.K., Oh, H.S., Shul, Y.G., Kim, H.S., (2008) “Growth and Characterization of
Carbon-Supported Mno2 Nanorods for Supercapacitor Electrode”, Physica B, 403,1763-1769. doi:1016/j.physb.2007.10.007.
Sharma, R.K., Zhai, L., (2009) “Multiwall
Carbon Nanotube Supported Poly(3,4- ethylenedioxythiophene)/Manganese Oxide Nano-Composite Electrode Super-Capacitors”, Electrochimica Acta, 54,7148-7155. doi:1016/j.electacta.2009.07.048. for
Wang, J., Xu, Y., Chen, X., Du, X., (2007)
“Electrochemical supercapacitor Electrode Material ethylenedioxythiophene)/Polypyrrole Composites, Journal of Power Sources, 163,1120-1125. doi:1016/j.jpowsour.2006.10.004.
Wang, Q., Li, J.L., Gao, F., Li, W.S., Wu, K.S., Wang, X.D., (2008) “Activated Carbon
Coated with Polyaniline as An Electrode Material Carbon doi:1016/S1872-5805(08)60030-X. 23, 275-2
White, A.M., Slade, R.C.T., (2003) “Polymer Electrodes
Heteropolymetallates and Their use within Solid-State Supercapacitors”, Metals, 139, 123-131. doi:10.1016/S0379- 6779(03)00039-0. with Synthetic
Yang, C.M., Kim, Y.J., Endo, M., Kanoh, H., Yudasaka, M., Iijima, S., Kaneko, K., (2007) “Nanowindow-Regulated Specific
Capacitance of Supercapacitor Electrodes of Single-Wall Carbon Nanohorns”, Journal of The American Chemical Society, doi:1021/ja065501k. 20

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Evrim Hür

Andaç Arslan This is me

Müjdat Çağlar

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February 13, 2015

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February 13, 2015

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Year 2015 Volume: 16 Number: 1

DOI

https://doi.org/10.18038/btd-a.27481

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https://izlik.org/JA34SK73NL

APA

Hür, E., Arslan, A., & Çağlar, M. (2015). CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(1), 39-52. https://doi.org/10.18038/btd-a.27481

AMA

1.Hür E, Arslan A, Çağlar M. CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM. AUJST-A. 2015;16(1):39-52. doi:10.18038/btd-a.27481

Chicago

Hür, Evrim, Andaç Arslan, and Müjdat Çağlar. 2015. “CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 (1): 39-52. https://doi.org/10.18038/btd-a.27481.

EndNote

Hür E, Arslan A, Çağlar M (August 1, 2015) CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 1 39–52.

IEEE

[1]E. Hür, A. Arslan, and M. Çağlar, “CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM”, AUJST-A, vol. 16, no. 1, pp. 39–52, Aug. 2015, doi: 10.18038/btd-a.27481.

ISNAD

Hür, Evrim - Arslan, Andaç - Çağlar, Müjdat. “CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/1 (August 1, 2015): 39-52. https://doi.org/10.18038/btd-a.27481.

JAMA

1.Hür E, Arslan A, Çağlar M. CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM. AUJST-A. 2015;16:39–52.

MLA

Hür, Evrim, et al. “CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 1, Aug. 2015, pp. 39-52, doi:10.18038/btd-a.27481.

Vancouver

1.Evrim Hür, Andaç Arslan, Müjdat Çağlar. CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM. AUJST-A. 2015 Aug. 1;16(1):39-52. doi:10.18038/btd-a.27481

CHARACTERIZATION OF POLY(N-ETHYLANILINE) AND POLY(ANILINE-CO-N-ETHYLANILINE) AS SUPERCAPACITOR ACTIVE MATERIALS IN NONAQUEOUS MEDIUM

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