SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER

Ebru Ozkutuk

doi:10.18038/btd-a.59620

EN TR

SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER

Abstract

The aim of this study is to prepare ion-imprinted polymers which can be used for the selective removal of Cd(II) from synthetic water. Ion-imprinted polymer particles have prepared by molecular imprinting technique using 3-mercaptopropyl-trimethoxysilane as monomer, tetraethoxysilane as crosslinking agent in the presence of Cd(II) and dodecylamine. After that, the template ions have removed using 0.1M HNO₃/ethanol. A batch procedure has used for the determination of the characteristics of the Cd(II) solid phase. The results obtained have shown that the IIP has the greatest adsorption capacity (98.2 mgg^-1). Optimum pH and adsorption time have found as pH 5.0 and 2h. In selectivity study, it has found that imprinting results in increased affinity of the material toward Cd(II) ion over other competitor metal ions with the same charge. The selectivity of Cd(II)/Zn(II), Cd(II)/Cu(II) and Cd(II)/Hg(II) have found as 2.73, 8.83 and 112.8, respectively

Keywords

Ion-imprinted, Cadmium Separation, Preconcentration, Sol-gel

References

Amorim, F. A. C., Ferreira, S. L. C., (2005) Determination of cadmium and lead in table salt by sequential multi-element flame atomic absorption spectrometry. Talanta, 65, 960- 964
Andac, M., Say, R., A. Denizli, (2004). Molecular recognition based cadmium removal from human plasma Journal of Chromatography B., 811, 119-126.
Andac, M., Ozyapi, E., Senel, S., Say, R., A.Denizli, (2006). Ion-Selective Imprinted Beads for Aluminum Removal from Aqueous Solutions Industrial Research., 45(5), 1780-1786. Chemistry
Araki, K., Maruyama, T., Kamiya, N., Goto M., (2005) prepared by surface molecular imprinting.J. Chromatography B., 818, 141-145.
Bae, S. Y., Southard G. L., Murray, G. M., (1999).
Molecularly imprinted ion exchange resin for
purification preconcentration and determination
of UO22+ by spectrophotometry and plasma
spectrometry Analytica Chimica Acta 397 (1-3), 173-181.
Biju, V. M., Gladis, J. M., Rao T. P., (2003) Ion imprinted polymer particles: synthesis, characterization and dysprosium ion uptake properties suitable for analytical applications Analytica Chimica Acta 478, 43-51.

Birlik, E., Ersöz A., Denizli A., Say, R., (2006). Preconcentration of Copper usind Double- Imprinted Polymer via Solid Phase Extraction Analytica Chimica Acta 565, 145-151.
Büyüktiryaki, S., Say, R., Ersöz, A., Birlik, E., Denizli, preconcentration of thorium in the presence of UO22+, Ce3+ and La3+ using Th(IV)-imprinted polymer ,Talanta., 67 640-645. Selective
Daniel, S., Babu, P. E. J., Rao, T. P., (2005) Preconcentrative Separation of Palladium(II) Using ... of Binding Parameters Based on Adsorption Isotherm Models, Talanta, 65(2): 441-452 .
Davis, A. C., Wu, P., Zhang, X. F., Hou, X. D., Jones B. T., (2006). Determination of cadmium in biological samples, Applied Spectroscopy Reviews 41, 35-75.
Ersöz, A., Say, R., Denizli A., (2004). Nickel(II) Ion- Imprinted Solid Phase Extraction and Preconcentration In Aqueous Solutions in Packed-Bed Columns, Analytica Chimica Acta, 502, 91-97
Fang, G. Z., Tan, J., Yan X. P., (2005). An ion- imprinted functionalized silica gel sorbent prepared techniquecombined with a sol–gel process for selective cadmium(II). Analytical Chemistry 77:1734– 1739 surface imprinting
solid-phaseextraction of
Gladis, J. M., Rao, T. P., (2003) Synthesis and analytical applications of uranyl ion imprinted polymer particles, Analytical Letters, 36, 2107-2121 .
Kala, R., Gladis, J. M., Rao, T. P., (2004). Preconcentrative separation of erbium from Y, Dy, Ho, Tb and Tm by using ion imprinted polymer particles viasolid phase extraction . Analytica Chimica Acta, 518: 143-150.
Karabork, M., Ersoz, A., Denizli, A., Say, R., (2008). Polymer-Clay Nanocomposite Iron Traps Based Industrial Research, 47, 2258-2264 .
Ion-Imprinting & Engineering Chemistry
Hg(II)-imprinted Chimica Acta, 538
Lu, Y. K., Yan, X. P., (2004). An imprinted organic- inorganic hybrid sorbent for selective separation of cadmium from aqueous solution Analytical Chemistry,76, 453-457.
Makote, R. D., Dai, S., (2001). Matrix-induced modification of imprinting effect for Cu2+ adsorption in hybrid silica matrices Analytica Chimica Acta, 435, 169-176.
Prasad, K., Kala, R., Rao, T. P., Naidu, G. R. K., (2006). Ion imprinted polymer based ion- selective electrode for the trace determination of dysprosium(III) ions Analytica Chimica Acta, 566, 69-74
Prasad, K., Gopikrishna, P., Kala, R., Rao, T. P., Naidu, G. R. K., (2006). Solid phase extraction preconcentration of cadmium and lead from soils embedded benzophenone and determination by FAAS, Talanta., 69, 938-945.
Ramstrom, O., Ye, L., Mosbach, K., (1996). Artificial prepared by molecular imprinting, Chemistry and Biology, 3, 471-477. to corticosteroids
Rosatzin, T., Andersson, L. I., Simon, W., Mosbach K., (1991). Preparation of Ca2+ selective sorbents by molecular imprinting using polymerizable ionophores, Journal of the Chemical Society, Perkin Transactions 2, 1261-1265 .
Saunders, G. D., Foxon, S. P., Walton, P. H., Joyce M. J., Port S. N., (2000).A selective uranium extraction agent prepared by polymer imprinting. Chemical Communications, 273- 274
Say, R., Birlik, E., Ersöz, A., Yilmaz, F., Gedikbey, T., Denizli, A., (2003). Preconcentration of copper on ion-selective imprinted polymer microbeads, Analytica Chimica Acta, 480, 251-258.
Vigneau, O., Pinel, C., Lemaire, M., (2002). “Solid- liquid separation of lanthanide/lanthanide and lanthanide/actinide using ionic imprinted polymer derivativeChemistry Letters, 202-203. on a DTPA
Wulff, G. (1995). Molecular imprinting in cross- linked materials with the aid of molecular templates - a way towards artificial antibodiesAngewandte Chemie International Edition 34 (17), 1812-1832.
Xie, F., Lin, X., Wu, X., Xie, Z. (2008). Solid phase extraction of lead (II), copper (II), cadmium (II) and nickel (II) using gallic acid-modified silica gel prior to determination by flame atomic absorption spectrometry Talanta., 74, 836–843

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English

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Ebru Ozkutuk

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May 11, 2015

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May 11, 2015

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Year 2015 Volume: 16 Number: 1

DOI

https://doi.org/10.18038/btd-a.59620

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https://izlik.org/JA95ZH65AF

APA

Ozkutuk, E. (2015). SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(1), 15-22. https://doi.org/10.18038/btd-a.59620

AMA

1.Ozkutuk E. SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. AUJST-A. 2015;16(1):15-22. doi:10.18038/btd-a.59620

Chicago

Ozkutuk, Ebru. 2015. “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 (1): 15-22. https://doi.org/10.18038/btd-a.59620.

EndNote

Ozkutuk E (August 1, 2015) SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 1 15–22.

IEEE

[1]E. Ozkutuk, “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”, AUJST-A, vol. 16, no. 1, pp. 15–22, Aug. 2015, doi: 10.18038/btd-a.59620.

ISNAD

Ozkutuk, Ebru. “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/1 (August 1, 2015): 15-22. https://doi.org/10.18038/btd-a.59620.

JAMA

1.Ozkutuk E. SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. AUJST-A. 2015;16:15–22.

MLA

Ozkutuk, Ebru. “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 1, Aug. 2015, pp. 15-22, doi:10.18038/btd-a.59620.

Vancouver

1.Ebru Ozkutuk. SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. AUJST-A. 2015 Aug. 1;16(1):15-22. doi:10.18038/btd-a.59620

SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER

SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER

Abstract

Keywords

SENTETİK SUDAN ÇİFT BASKILI POLİMER KULLANILARAK Cd(II)'NİN SEÇİCİ UZAKLAŞTIRILMASI

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