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  2. Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik
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  4. Cilt 17, Sayı 2
Yıl 2016, Cilt 17 , Sayı 2, Sayfalar 273 - 277 2016-07-14

SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA

Cemal PARLAK [1] , Özgür ALVER [2]

Öz

The adsorption of 1,4-dioxane on a natural bentonite sample from Ünye region of Turkey has been examined using infrared and solid state magic angle spinning nuclear magnetic resonance spectroscopic techniques. It was observed that adsorption on bentonite is due to hydrogen bonding between the waters of interlayer and either hydrogen atoms of –CH2 or oxygen atom of –CH2OCH2 groups of 1,4-dioxane. No noticeable interactions, however, are observed at the Al-(Mg)-OH edges by FT-IR (Fourier Transform Infrared) and CP/MAS NMR (Cross Polarization/Magic Angle Spinning Nuclear Magnetic Resonance) techniques.

Anahtar Kelimeler

Bentonite, 29Si, 13C, CP/MAS NMR

Kaynakça

  • Grim RE, Güven N. Bentonites, Geology, Mineralogy, Properties and Uses: Development in Sedimentology. Amsterdam: Elsevier, 1978.
  • Tabak A, Yilmaz N, Eren E, Caglar B, Afsin B, Sarihan A. Structural analysis of naproxen- intercalated bentonite (Unye). Chem Eng J 2011; 174: 281-288.
  • Newman ACD. Chemistry of Clays and Clay Minerals. London: Longman Scientific &Technical/Mineralogical Society, 1987.
  • Murray HH. Applied clay mineralogy today and tomorrow. Clay Miner 1999; 34: 39-49.
  • Murray HH. Traditional and new applications for kaolin, smectite and palygorskite: A general overview. App Clay Sci 2000: 17; 207-221.
  • Erdoğan B, Sakızcı M, Yörükoğulları E. Characterization and ethylene adsorption of natural and modified clinoptilolites. App Surface Sci 2008: 254(8); 2450-2457.
  • Inoue T, Takeuchi Y, Hisanaga N, Ono Y, Iwata M, Ogata M, Saito K, Sakurai H, Hara I, Matsushita T, Ikeda M. A nationwide survey on organic solvent components in various solvent products: Part 1. Homogeneous products such as thinners, degreasers and reagents. Ind Health 1983: 21; 175-183.
  • Kumai M, Koizumi A, Saito K, Sakurai H, Inoue T, Takeuchi Y, Hara I, Ogata M, Hara I, Matsushita T, Ikeda M. A nationwide survey on organic solvent components in various solvent products: Part 2. Heterogeneous products such as paints, inks and adhesives. Ind Health 1983: 21; 185- 197.
  • Johnstone RT. Death due to Dioxane? Arch Ind Health 1959: 20; 445-447.
  • Rowe VK, Wolf MA. Dioxane. In Patty’s Industrial Hygiene and Toxicology. 3nd ed. New York: John Wiley & Sons, 1982.
  • Erdoğan Alver B, Alver Ö. The investigation of the effect of thermal treatment on bentonites from Turkey with Fourier transform infrared and solid state nuclear magnetic resonance spectroscopic methods. Spectrochim. Acta A 2012: 94; 331-333.
  • Fratiello A, Luongo JP. Infrared and nuclear magnetic resonance hydrogen-bonding study of dioxane and pyridine. J Am Chem Soc 1963: 85(20); 3072-3075.
  • Luong TQ, Verma PK, Mitra RK, Havenith M. Onset of hydrogen bonded collective network of water in 1,4-dioxane. J Phys Chem A 2011: 115; 14462-14469.
  • Sirotkin VA, Solomonow BN, Faizullin DA, Fedotov VD. IR spectroscopic study of the state of water in dioxane and acetonitrile: Relationship with thermodynamic activity of water. J Struct Chem 2000: 41; 997-1003.
  • Günzler H, Gremlich HU. IR spectroscopy: An introduction. Germany: Wiley-VCH, 2002.
  • Ramsay DA. The vibration spectrum and molecular configuration of 1: 4-dioxane. P Roy Soc Lond A Mat 1947: 190; 562-574.
  • Chapman DM, Hester RE. Ab initio conformational analysis of 1,4-Dioxane. J Phys Chem A 1997: 101(18); 3382-3387.
  • Mizuno K, Imafuji S, Fujiwara T, Ohta T, Tamiya Y. Hydration of the CH groups in 1,4-dioxane probed by NMR and IR: Contribution of blue-shifting CH···OH2 hydrogen bonds. J Phys Chem B, 2003: 107(16); 3972-3978.
  • Malherbe FE, Bernstein HJ. The infrared and Raman spectra of p-dioxane. J Am Chem Soc 1952: 74(17); 4408-4410.
  • Janiak C, Deblon S, Uehlin L. Synthesis of 6,6’-diamino-2,2’-biquinoline and 2,2’-bi-1,6- naphthyridine. Synthesis 1999: 6; 959-964.
  • Zolek T, Paradowska K, Wawer I. 13C CP MAS NMR and GIAO-CHF calculations of coumarins. Solid State Nucl Mag Reson 2003: 23; 77-87.

Ayrıntılar

Bölüm Araştırma Makalesi
Yazarlar

Yazar: Cemal PARLAK

Yazar: Özgür ALVER
Tarihler

Yayımlanma Tarihi : 14 Temmuz 2016

Kaynak Göster

Bibtex @ { aubtda257961, journal = {Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering}, issn = {1302-3160}, eissn = {2146-0205}, address = {}, publisher = {Eskişehir Teknik Üniversitesi}, year = {2016}, volume = {17}, pages = {273 - 277}, doi = {10.18038/btda.87236}, title = {SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA}, key = {cite}, author = {Parlak, Cemal and Alver, Özgür} }
APA Parlak, C , Alver, Ö . (2016). SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA . Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering , 17 (2) , 273-277 . DOI: 10.18038/btda.87236
MLA Parlak, C , Alver, Ö . "SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA" . Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 (2016 ): 273-277 <https://dergipark.org.tr/tr/pub/aubtda/issue/24338/257961>
Chicago Parlak, C , Alver, Ö . "SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA". Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 (2016 ): 273-277
RIS TY - JOUR T1 - SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA AU - Cemal Parlak , Özgür Alver Y1 - 2016 PY - 2016 N1 - doi: 10.18038/btda.87236 DO - 10.18038/btda.87236 T2 - Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering JF - Journal JO - JOR SP - 273 EP - 277 VL - 17 IS - 2 SN - 1302-3160-2146-0205 M3 - doi: 10.18038/btda.87236 UR - https://doi.org/10.18038/btda.87236 Y2 - 2021 ER -
EndNote %0 Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA %A Cemal Parlak , Özgür Alver %T SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA %D 2016 %J Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering %P 1302-3160-2146-0205 %V 17 %N 2 %R doi: 10.18038/btda.87236 %U 10.18038/btda.87236
ISNAD Parlak, Cemal , Alver, Özgür . "SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA". Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 / 2 (Temmuz 2016): 273-277 . https://doi.org/10.18038/btda.87236
AMA Parlak C , Alver Ö . SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA. AUBTD-A. 2016; 17(2): 273-277.
Vancouver Parlak C , Alver Ö . SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering. 2016; 17(2): 273-277.
IEEE C. Parlak ve Ö. Alver , "SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA", Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, c. 17, sayı. 2, ss. 273-277, Tem. 2016, doi:10.18038/btda.87236
Makalenin Yazarları
Cemal PARLAK [1]
Özgür ALVER [2]
Arşiv
Editör Kurulu
İletişim
TR Dizin
TR Dizin