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CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID

Yıl 2011, Cilt: 12 Sayı: 1, 1 - 10, 17.06.2011

Öz

This study examines the use of benzotriazole (Bt) and N-mesyl benzotriazole (BtSO2CH3) for improvement of corrosion resistance of low carbon steel in 0,1 M sulfuric acid (H2SO4). The inhibitor effect of Bt and BtSO2CH3 on the corrosion behavior of LCS was studied using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization curves and polarization resistance techniques. Under the present experimental condition these compounds revealed a good corrosion inhibition. The inhibition efficiency of BtSO2CH3 is more than inhibition efficiency of Bt. The potentiodynamic polarization curves indicate that compounds are mixed type inhibitors. The inhibiting properties of compounds were found to depend on the concentration. The adsorption mechanism of compounds was investigated using different adsorption isotherm. At the same time from the adsorption isotherms values of equilibrium constant and values of free energies of adsorption were calculated.

Kaynakça

  • Abdel-Gaber, A.M., Abd-El-Nabey, B.A., Sidahmed, I.M., El-Zayady, A.M. and Saadawy, M. (2006). Kinetics and thermodynamics of aluminium dissolution in 1.0 M sulphuric acid containing chloride ions. Mater. Chem. Phys. 98, 291-297.
  • Abd El-Maksoud, S.A. and Fouda, A.S. (2005). Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium. Mater. Chem. Phys. 93, 84-90.
  • Abd El-Maksoud, S.A. (2003). The influence of some arylazobenzoyl acetonitrile derivatives on the behaviour of carbon steel in acidic media. Appl. Surf. Sci. 206, 129136.
  • Amin, M.A., Khaled, K.F., Mohsen, Q. and Arida, H.A. (2010). A study of the inhibition of iron corrosion in HCl solutions by some amino acids. Corros. Sci. 52, 16841695.
  • Bentiss, F., Lagrenee, M., Traisnel, M. and Hornez, J.C. (1999). The corrosion inhibition of mild steel in acidic media by a new triaazole derivative. Corros. Sci. 41, 789-803.
  • Bentiss, F., Traisnel, M. and Lagrenee, M. (2000). The substutied 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media. Corros. Sci. 42, 127-146.
  • Diard, J.P., Le Canut, J.M., Le Garrec, B. and Mantella, C. (1998). Copper electrodissolution in 1 M HCl at low current densities. I. General steady-state study. Electrochim. Acta 43, 2469-2483.
  • Elachouri, M., Hajji, M.S., Salem, M., Kertit, S., Aride, J., Coudert, R. and Essassi, E. (1996). Some Nonionic Surfactants as Inhibitors of the Corrosion of Iron in Acid Chloride Solutions. Corrosion 52, 103108.
  • El-Shafei, A.A., Moussa, M.N.H. and El-Far, A.A. (2001). The corrosion inhibition character of thiosemicarbazide and its derivatives for C-steel in hydrocholoric acid solution. Mater. Chem. Phys. 70, 175180.
  • Fouda, A.S., Abdallah., M., Al-Ashrey, S.M. and Abdel-Fattah, A.A. (2010). Some crown ethers as inhibitors for corrosion of stainless steel type 430 aqueous solutions. Desalination 250, 538-543.
  • Gasparac, R., Martin, C.R. and Stupnisek-Lisac, E. (2000). In situ and ex situ studies of imidazole and its derivatives as copper corrosion inhibitors II: AC Impedance, XPS and SIMS studies. J. Electrochem. Soc. 147, 991-998.
  • Gomma, G.K. (1998a). Efect of azole compounds on corrosion of copper in acid medium. Mater. Chem. Phys. 56, 27-34.
  • Gomma, G.K. (1998b). Corrosion inhibition of steel by benzotriazole in sulphuric acid. Mater. Chem. Phys. 55, 235-240.
  • Gomma, G.K. (1998c). Infuence of copper cation on inhibition of corrosion for steel in presence of benzotriazole in sulfuric acid. Mater. Chem. Phys. 55, 131-138.
  • Hosseini, M., Mertens, S.F.L., Ghorbani, M. and Arshadi, M.R. (2003). Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media. Mater. Chem. Phys. 78, 800-808.
  • Katritzky, A.R., Shobana, N., Pernak, J., Afridi, A.S. and Fan, W.Q. (1992). Sulfonyl derivatives of benzotriazole: Part 1. A novel approach to the activation of carboxylic acids. Tetrahedron 48, 7817-7822.
  • Kertit, S. and Hammouti, B. (1996). Corrosion inhibition of iron in 1 M HCl by 1phenyl-5-mercapto-1,2,3,4,-tetrazole. Appl. Surf. Sci. 93, 59-66.
  • Larabi, L., Benali, O., Mekelleche, S.M. and Harek, Y. (2006). 2-Mercapto-1methylimidazole as corrosion inhibitor for copper in hydrochloric acid. Appl. Surf. Sci. 253, 1371-1378.
  • Li, X., Deng, S., Fu, H. and Mu, G. (2010). Synergistic inhibition effect of rare earth cerium(IV) ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution. Corros. Sci. 52, 11671178.
  • Oguzie, E.E., Li, Y. and Wang, F.H. (2007). Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion. J. Colloid Interface Sci. 310, 90-96.
  • Popova, A. and Christov, M. (2006). Evaluation of impedance measurements on mild steel corrosion in acid media in the presence of heterocyclic compounds. Corros. Sci. 48, 3208-3221.
  • Popova, A., Christov, M. and Zwetanova, A. (2007). Effect of the molecular structure on the inhibitor properties of azoles on mild steel corrosion in 1 M hydrochloric acid. Corros. Sci. 49, 2131-2143.
  • Qu, Q., Jiang, S.A., Bai, W. and Li, L. (2007). Effect of ethylenediamine tetraacetic acid disodium on the corrosion of cold rolled steel in the presence of benzotriazole in hydrochloric acid. Electrochim. Acta 52, 6811-6820.
  • Quraishi, M.A., Sardar, R. and Jamal, D. (2001). Corrosion inhibition of mild steel in hydrochloric acid by some aromatic hydrazides. Mater. Chem. Phys. 71, 309313.
  • Satpati, A.K. and Ravindran, P.V. (2008). Electrochemical study of the inhibition of corrosion of stainless steel by 1,2,3benzotriazole in acidic media. Mater. Chem. Phys. 109, 352-359.
  • Sherif, E.M. and Park, S. (2006). Effects of 2amino-5-ethylthio-1,3,4-thiadiazole on copper corrosion as a corrosion inhibitor in aerated acidic pickling solutions. Electrochim. Acta 51, 6556-6562.
  • Trabanelli, G. (1991). Inhibitors – An old remedy for a new challenge. Corrosion 47, 410-419.

Uygulamalı Bilimler ve Mühendislik

Yıl 2011, Cilt: 12 Sayı: 1, 1 - 10, 17.06.2011

Öz

Bu çalışma 0,1 M sülfürik asit içinde düşük karbon çeliğinin (LCS) korozyon direncini arttırmak için benzotriazol (Bt) ve yeni sentezlenen N-mesil benzotriazol (BtSO2CH3) kullanımını incelemektedir. LCS’nin korozyon davranışına karşı Bt ve BtSO2CH3’ün inhibitör etkisi, elektrokimyasal empedans spektroskopisi (EIS), potansiyodinamik polarizasyon eğrileri ve polarizasyon direnci teknikleri kullanılarak çalışılmıştır. Belirtilen deneysel koşullarda bu bileşikler iyi bir korozyon inhibisyonu göstermektedir. BtSO2CH3’ün inhibitör etkinliği, Bt’ün inhibitör etkinliğinden daha fazladır. Potansiyodinamik polarizasyon eğrileri bileşiklerin karma inhibitör olduğunu göstermektedir. Bileşiklerin inhibisyon özelliklerinin derişime bağlı olduğu bulunmuştur. Bileşiklerin adsorpsiyon mekanizmaları farklı adsorpsiyon izotermleri kullanılarak incelenmiştir. Aynı zamanda serbest enerji ve denge sabiti değerleri adsorpsiyon izotermlerinden hesaplanmıştır

Kaynakça

  • Abdel-Gaber, A.M., Abd-El-Nabey, B.A., Sidahmed, I.M., El-Zayady, A.M. and Saadawy, M. (2006). Kinetics and thermodynamics of aluminium dissolution in 1.0 M sulphuric acid containing chloride ions. Mater. Chem. Phys. 98, 291-297.
  • Abd El-Maksoud, S.A. and Fouda, A.S. (2005). Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium. Mater. Chem. Phys. 93, 84-90.
  • Abd El-Maksoud, S.A. (2003). The influence of some arylazobenzoyl acetonitrile derivatives on the behaviour of carbon steel in acidic media. Appl. Surf. Sci. 206, 129136.
  • Amin, M.A., Khaled, K.F., Mohsen, Q. and Arida, H.A. (2010). A study of the inhibition of iron corrosion in HCl solutions by some amino acids. Corros. Sci. 52, 16841695.
  • Bentiss, F., Lagrenee, M., Traisnel, M. and Hornez, J.C. (1999). The corrosion inhibition of mild steel in acidic media by a new triaazole derivative. Corros. Sci. 41, 789-803.
  • Bentiss, F., Traisnel, M. and Lagrenee, M. (2000). The substutied 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media. Corros. Sci. 42, 127-146.
  • Diard, J.P., Le Canut, J.M., Le Garrec, B. and Mantella, C. (1998). Copper electrodissolution in 1 M HCl at low current densities. I. General steady-state study. Electrochim. Acta 43, 2469-2483.
  • Elachouri, M., Hajji, M.S., Salem, M., Kertit, S., Aride, J., Coudert, R. and Essassi, E. (1996). Some Nonionic Surfactants as Inhibitors of the Corrosion of Iron in Acid Chloride Solutions. Corrosion 52, 103108.
  • El-Shafei, A.A., Moussa, M.N.H. and El-Far, A.A. (2001). The corrosion inhibition character of thiosemicarbazide and its derivatives for C-steel in hydrocholoric acid solution. Mater. Chem. Phys. 70, 175180.
  • Fouda, A.S., Abdallah., M., Al-Ashrey, S.M. and Abdel-Fattah, A.A. (2010). Some crown ethers as inhibitors for corrosion of stainless steel type 430 aqueous solutions. Desalination 250, 538-543.
  • Gasparac, R., Martin, C.R. and Stupnisek-Lisac, E. (2000). In situ and ex situ studies of imidazole and its derivatives as copper corrosion inhibitors II: AC Impedance, XPS and SIMS studies. J. Electrochem. Soc. 147, 991-998.
  • Gomma, G.K. (1998a). Efect of azole compounds on corrosion of copper in acid medium. Mater. Chem. Phys. 56, 27-34.
  • Gomma, G.K. (1998b). Corrosion inhibition of steel by benzotriazole in sulphuric acid. Mater. Chem. Phys. 55, 235-240.
  • Gomma, G.K. (1998c). Infuence of copper cation on inhibition of corrosion for steel in presence of benzotriazole in sulfuric acid. Mater. Chem. Phys. 55, 131-138.
  • Hosseini, M., Mertens, S.F.L., Ghorbani, M. and Arshadi, M.R. (2003). Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media. Mater. Chem. Phys. 78, 800-808.
  • Katritzky, A.R., Shobana, N., Pernak, J., Afridi, A.S. and Fan, W.Q. (1992). Sulfonyl derivatives of benzotriazole: Part 1. A novel approach to the activation of carboxylic acids. Tetrahedron 48, 7817-7822.
  • Kertit, S. and Hammouti, B. (1996). Corrosion inhibition of iron in 1 M HCl by 1phenyl-5-mercapto-1,2,3,4,-tetrazole. Appl. Surf. Sci. 93, 59-66.
  • Larabi, L., Benali, O., Mekelleche, S.M. and Harek, Y. (2006). 2-Mercapto-1methylimidazole as corrosion inhibitor for copper in hydrochloric acid. Appl. Surf. Sci. 253, 1371-1378.
  • Li, X., Deng, S., Fu, H. and Mu, G. (2010). Synergistic inhibition effect of rare earth cerium(IV) ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution. Corros. Sci. 52, 11671178.
  • Oguzie, E.E., Li, Y. and Wang, F.H. (2007). Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion. J. Colloid Interface Sci. 310, 90-96.
  • Popova, A. and Christov, M. (2006). Evaluation of impedance measurements on mild steel corrosion in acid media in the presence of heterocyclic compounds. Corros. Sci. 48, 3208-3221.
  • Popova, A., Christov, M. and Zwetanova, A. (2007). Effect of the molecular structure on the inhibitor properties of azoles on mild steel corrosion in 1 M hydrochloric acid. Corros. Sci. 49, 2131-2143.
  • Qu, Q., Jiang, S.A., Bai, W. and Li, L. (2007). Effect of ethylenediamine tetraacetic acid disodium on the corrosion of cold rolled steel in the presence of benzotriazole in hydrochloric acid. Electrochim. Acta 52, 6811-6820.
  • Quraishi, M.A., Sardar, R. and Jamal, D. (2001). Corrosion inhibition of mild steel in hydrochloric acid by some aromatic hydrazides. Mater. Chem. Phys. 71, 309313.
  • Satpati, A.K. and Ravindran, P.V. (2008). Electrochemical study of the inhibition of corrosion of stainless steel by 1,2,3benzotriazole in acidic media. Mater. Chem. Phys. 109, 352-359.
  • Sherif, E.M. and Park, S. (2006). Effects of 2amino-5-ethylthio-1,3,4-thiadiazole on copper corrosion as a corrosion inhibitor in aerated acidic pickling solutions. Electrochim. Acta 51, 6556-6562.
  • Trabanelli, G. (1991). Inhibitors – An old remedy for a new challenge. Corrosion 47, 410-419.
Toplam 27 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Araştırma Makalesi
Yazarlar

Evrim Hür

Andaç Arslan Bu kişi benim

Handan Sakarya Bu kişi benim

Deniz Hür

Yayımlanma Tarihi 17 Haziran 2011
Yayımlandığı Sayı Yıl 2011 Cilt: 12 Sayı: 1

Kaynak Göster

APA Hür, E., Arslan, A., Sakarya, H., Hür, D. (2011). CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 12(1), 1-10.
AMA Hür E, Arslan A, Sakarya H, Hür D. CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID. AUBTD-A. Haziran 2011;12(1):1-10.
Chicago Hür, Evrim, Andaç Arslan, Handan Sakarya, ve Deniz Hür. “CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 12, sy. 1 (Haziran 2011): 1-10.
EndNote Hür E, Arslan A, Sakarya H, Hür D (01 Haziran 2011) CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 12 1 1–10.
IEEE E. Hür, A. Arslan, H. Sakarya, ve D. Hür, “CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID”, AUBTD-A, c. 12, sy. 1, ss. 1–10, 2011.
ISNAD Hür, Evrim vd. “CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 12/1 (Haziran 2011), 1-10.
JAMA Hür E, Arslan A, Sakarya H, Hür D. CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID. AUBTD-A. 2011;12:1–10.
MLA Hür, Evrim vd. “CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, c. 12, sy. 1, 2011, ss. 1-10.
Vancouver Hür E, Arslan A, Sakarya H, Hür D. CORROSION INHIBITION OF BENZOTRIAZOLE AND N-MESYL BENZOTRIAZOLE ON LOW CARBON STEEL IN SULFURIC ACID. AUBTD-A. 2011;12(1):1-10.