Yeni Bir Schiff Bazı Ve Geçiş Metalleri İle Oluşturdukları Komplekslerin Sentezi Ve Karakterizasyonu

Yıl 2012, Cilt: 1 Sayı: 1, 34 - 39, 01.06.2012

Oğuz Kağan Taşkın Ömer Faruk Öztürk Erdal Canpolat

Öz

Bu çalışmada, salisilaldehit ve 1,2-diborometan’ın kondenzesyonundan 2.2’-[etan-1,2-diilbis (oksi)] dibenzaldehid bileşiği sentezlendi. Bu bileşiğin 2-aminofenol ile reaksiyonundan yeni bir Schiff bazı ligandı (LH2) hazırlandı. Bu Schiff bazı ligandı ile Co+2, Ni+2 ve Zn+2 asetat tuzları reaksiyona sokularak Co(L)(H2O)2, Ni(L)(H2O)2 ve Zn(L)(H2O)2 kompleksleri elde edildi. Schiff bazı ve komplekslerinin yapıları, elementel analiz, IR, 1H-NMR, 13C-NMR, UV, manyetik duyarlılık ve termogravimetrik analiz ile aydınlatıldı.

Anahtar Kelimeler

Schiff Bazları, Geçiş Metal Kompleksleri, Okso Grubu, Termal Analiz

Kaynakça

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