Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties

Serdal Ünal; Mehmet Canbaz

Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties

Abstract

It is estimated that approximately 0.5-1 million tons of boron waste is generated annually in Turkey. Most of these wastes are concentrated in Kırka (Eskişehir), Bandırma (Balıkesir) and Bigadiç (Balıkesir) plants. Disposal of these wastes is an important environmental problem. In this study, the usability of colemanite concentrator waste from Kütahya-Emet Eti Maden Company as cement and concrete admixture was investigated by experiments on concrete specimens. The strengths of colemanite concentrator waste at 5%, 10%, 20% and by changing the proportions of colemanite concentrator waste and adding fly ash with the waste into cement at 10% and 20% were investigated. When the mechanical properties were examined, 5% colemanite waste gave the best results in the specimens. It was also observed that it reduced the setting time.

Keywords

Thanks

The authors would like to thank the companies that provided support in supplying raw materials for this study.

References

A. M. Kılıç, “Importance of boron mine for Turkey and place in the future,” in Proceedings of the 2nd International Boron Symposium, Eskişehir, Turkey, pp. 31-41, Sep. 23–25, 2004.
E. Demiryılmaz, “The use of boron and its products in concrete road pavements,” PhD dissertation, Dept. Civ. Eng., Balıkesir University, Turkey, 2023.
İ. Dal and Ş. Aktepe Dal, “Use of boron mineral in textile industry and its contribution to Turkish economy,” Pamukkale J. Eurasian Socioecon. Stud., vol. 8, no. 2, pp. 53-69, Sept. 2021, doi: 10.34232/pjess.970104.
İ. Kayandan et al., “Concentration of low grade colemanite ore by calcination” in Proceedings of the 2nd International Boron Symposium, Eskişehir, Turkey, pp. 65-69, Sep. 23–25, 2004.
İ. Kula, “Utulization of boron industry wastes in cement producing as an additive material”, PhD dissertation, Dept. Chemistry, Sakarya University, Turkey, 2000. T. Özturan, “Investigation of the use of fly ash in concrete production,” in Proceedings of the 11th Technical Congress of Turkish Civil Engineering, TBMMO Chamber of Civil Engineers, pp. 149-158, İstanbul, Turkey, 1991. F. Oruç, E. Sabah and Z.E. Erkan, “Evaluation Strategies of Boron Tailings according to Sector,” in Proceedings of the 2nd International Boron Symposium, Eskişehir, Turkey, pp. 385-392, Sept. 23–25, 2004.
H. Şensöz and Z.E. Sayın, “Recovery of lithium from solid waste clays of Emet colemanite beneficiation plant by roasting and acid leaching method,” Pamukkale U. J. Eng. Sc., vol. 30, no. 3, pp. 405-413, Jun. 2024, doi: 10.5505/pajes.2023.69705.
E. Sönmez and S. Yorulmaz, “Investigation of usability of Kırka Borax Plant waste clays in brick making,” Industrial Raw Materials Symposium, TMMOB Chamber of Mining Engineers, İzmir, Turkey, pp. 163-168, 1995.
E. Sabah and L. Yeşilkaya, “Investigation of sedimentation behavior of Kırka borax plant tincal concentrator tailings with different types of polymers,” Mineral Processing, Mineral Processing and Enrichment Association Publication, no. 3, pp. 1-12, İzmir, Turkey, 2000.

R. Boncukcuoğlu et al., “Utilization of borogypsum as set retarder in Portland cement production,” Cem. Conc. Res. , vol. 32, no. 3, pp. 471-475, Mar. 2002, doi: 10.1016/S0008-8846(01)00711-6.
F. Altun, “Boron,” National Boron Research Institute, Ankara, Turkey, 2005.
S. Türk et al., “Heat of hydration and shrinkage properties of Boron containing active belite cements,” in Proceedings of ConcreteLife'06: International RILEM-JCI Seminar on Concrete Durability and Service Life Planning (RILEM proceedings ; No. 46), K. Kovler (Ed.), pp. 397-404, 2006.
C.D. Atış et al.,“The use of a non-standard high calcium fly ash in concrete and its response to accelerated curing,” Materiales de Construccuion, vol. 52, No.267, pp.5-17, Jan. 2002.
F. Özmal et al., “Investigation of physical and mechanical properties of cements containing boron industrial wastes, fly ash and alunite,” in Proceedings of the 1st National Boron Workshop, Ankara, Turkey, 2005.
G. Keles, M.M. Kocakerim and R. Boncukcuoglu, “Use of borogips and colemanite concentration waste in cement,” in Proceedings of the 1st National Boron Workshop, Ankara, Turkey, 2005.
A. Ramão et al., “Exploring the potential of belitic cement produced from industrial waste: systematic mapping of the literature,” Sustainability, vol. 17, no. 6, Art. no. 2377, Mar. 2025, doi: 10.3390/su17062377.
İ.E. Kalafatoğlu and S.N. Örs, “Boron technologies and applications in the 21st century,” Journal of Balıkesir University Institute of Science, vol. 5, no. 1, pp. 59-71, Jun. 2003.
M.Ş. Yön et al., “Sustainable use of boron waste and volcanic scoria in slag-based self-compacting alkali-activated mortars: fresh, mechanical and durability properties,” Sustain. Chem. Pharm., vol. 41, Art. no. 101664, Jun. 2024, doi: 10.1016/j.scp.2024.101664.
C.Ç. Kızıltepe, İ. Yüksel and S. Aydın, “One-part geopolymer binder based on boron wastes: effects of calcination temperature and NaOH dosage on strength and microstructure,” J. Innov. Sci. Eng., vol. 8, no. 1, pp. 53-62, Jun. 2024.
Z. Çelik, E. Turan and M. Oltulu, “High temperature performance of geopolymer: Contribution of boron tincal waste,” J. Sustain. Constr. Mater. Technol., vol. 9, no. 3, pp. 255-267, Sept. 2024.
Ö. Biricik, S. Özen and A. Mardani, “Effect of boron waste on mechanical and durability properties of concrete” Eur. J., Eng. Sci., Tech. (EJENS), vol. 8, no. 1, Oct. 2023.

Details

Primary Language

English

Subjects

Construction Materials

Journal Section

Research Article

Authors

Serdal Ünal
0000-0002-5200-9969
Türkiye

Mehmet Canbaz ^*
0000-0002-0175-6155
Türkiye

Publication Date

May 1, 2025

Submission Date

March 27, 2025

Acceptance Date

April 14, 2025

Published in Issue

Year 2025 Volume: 22 Number: 1

IZ

https://izlik.org/JA28AK39UJ

Cite

RIS / Bibtex

APA

Ünal, S., & Canbaz, M. (2025). Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties. Cankaya University Journal of Science and Engineering, 22(1), 23-32. https://izlik.org/JA28AK39UJ

AMA

1.Ünal S, Canbaz M. Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties. CUJSE. 2025;22(1):23-32. https://izlik.org/JA28AK39UJ

Chicago

Ünal, Serdal, and Mehmet Canbaz. 2025. “Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties”. Cankaya University Journal of Science and Engineering 22 (1): 23-32. https://izlik.org/JA28AK39UJ.

EndNote

Ünal S, Canbaz M (May 1, 2025) Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties. Cankaya University Journal of Science and Engineering 22 1 23–32.

IEEE

[1]S. Ünal and M. Canbaz, “Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties”, CUJSE, vol. 22, no. 1, pp. 23–32, May 2025, [Online]. Available: https://izlik.org/JA28AK39UJ

ISNAD

Ünal, Serdal - Canbaz, Mehmet. “Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties”. Cankaya University Journal of Science and Engineering 22/1 (May 1, 2025): 23-32. https://izlik.org/JA28AK39UJ.

JAMA

1.Ünal S, Canbaz M. Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties. CUJSE. 2025;22:23–32.

MLA

Ünal, Serdal, and Mehmet Canbaz. “Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties”. Cankaya University Journal of Science and Engineering, vol. 22, no. 1, May 2025, pp. 23-32, https://izlik.org/JA28AK39UJ.

Vancouver

1.Serdal Ünal, Mehmet Canbaz. Effect of Colemanite-Based Boron Concentrator Waste on Concrete Properties. CUJSE [Internet]. 2025 May 1;22(1):23-32. Available from: https://izlik.org/JA28AK39UJ