Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study

Ali Rıza Kul; Eda Gökırmak Söğüt; Necla Çalışkan Kılıç

EN

Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study

Abstract

This study investigates the adsorption of neutral red (NR) on the natural clayey material of Adilcevaz/ Bitlis located the northwest of Van Lake in Eastern Anatolia (Turkey). The adsorbent used was characterized by XRD, XRF, FTIR, SEM and TG-DTA analyzes. The effect of various parameters such as pH, contact time, initial concentration and temperature on NR removal was investigated using a batch process to optimize the maximum adsorption conditions. Equilibrium data for NR adsorption were analyzed using nonlinear two-parameter isotherms such as Langmuir, Freundlich, Dubinin-Radushkevich, and Tempkin, and three-parameter isotherm models, such as nonlinear Redlich-Peterson, Sips, and Koble-Corrigan. The modelling results showed that it was best adapted to the Freundlich isotherm model for the NR dye, with relatively higher R² values and smaller S.E. The maximum adsorption capacity obtained from the experimental data was determined to be 4.2810 mg g^-1. The adsorption process follows pseudo-second-order kinetics with a rate constant of 0.0110 g mg^-1 min^-1. The thermodynamic parameters indicate that a physical mechanism controls the NR adsorption on the natural clay and spontaneously occurs.

Keywords

Adsorption, dye, natural clay, non-linear isotherm models, thermodynamic, kinetic

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Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Ali Rıza Kul
0000-0001-9331-775X
Türkiye

Eda Gökırmak Söğüt ^*
0000-0002-7707-3924
Türkiye

Necla Çalışkan Kılıç
0000-0001-5451-3192
Türkiye

Publication Date

December 31, 2021

Submission Date

June 5, 2021

Acceptance Date

August 16, 2021

Published in Issue

Year 2021 Volume: 63 Number: 1

IZ

https://izlik.org/JA57ZS42YK

APA

Kul, A. R., Gökırmak Söğüt, E., & Çalışkan Kılıç, N. (2021). Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, 63(1), 27-60. https://izlik.org/JA57ZS42YK

AMA

1.Kul AR, Gökırmak Söğüt E, Çalışkan Kılıç N. Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study. Commun. Fac. Sci. Univ. Ank. Ser. B. 2021;63(1):27-60. https://izlik.org/JA57ZS42YK

Chicago

Kul, Ali Rıza, Eda Gökırmak Söğüt, and Necla Çalışkan Kılıç. 2021. “Adsorption of Neutral Red Dye from Aqueous Solutions by Natural Adsorbent: an Equilibrium, Kinetic and Thermodynamic Study”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 63 (1): 27-60. https://izlik.org/JA57ZS42YK.

EndNote

Kul AR, Gökırmak Söğüt E, Çalışkan Kılıç N (December 1, 2021) Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 63 1 27–60.

IEEE

[1]A. R. Kul, E. Gökırmak Söğüt, and N. Çalışkan Kılıç, “Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study”, Commun. Fac. Sci. Univ. Ank. Ser. B, vol. 63, no. 1, pp. 27–60, Dec. 2021, [Online]. Available: https://izlik.org/JA57ZS42YK

ISNAD

Kul, Ali Rıza - Gökırmak Söğüt, Eda - Çalışkan Kılıç, Necla. “Adsorption of Neutral Red Dye from Aqueous Solutions by Natural Adsorbent: an Equilibrium, Kinetic and Thermodynamic Study”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 63/1 (December 1, 2021): 27-60. https://izlik.org/JA57ZS42YK.

JAMA

1.Kul AR, Gökırmak Söğüt E, Çalışkan Kılıç N. Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study. Commun. Fac. Sci. Univ. Ank. Ser. B. 2021;63:27–60.

MLA

Kul, Ali Rıza, et al. “Adsorption of Neutral Red Dye from Aqueous Solutions by Natural Adsorbent: an Equilibrium, Kinetic and Thermodynamic Study”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, vol. 63, no. 1, Dec. 2021, pp. 27-60, https://izlik.org/JA57ZS42YK.

Vancouver

1.Ali Rıza Kul, Eda Gökırmak Söğüt, Necla Çalışkan Kılıç. Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study. Commun. Fac. Sci. Univ. Ank. Ser. B [Internet]. 2021 Dec. 1;63(1):27-60. Available from: https://izlik.org/JA57ZS42YK

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

Adsorption of neutral red dye from aqueous solutions by natural adsorbent: an equilibrium, kinetic and thermodynamic study

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