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LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS

Year 1995, Volume: 41 , 0 - 0, 01.01.1995
https://doi.org/10.1501/Commub_0000000403

Abstract

The isobaric separation of multicomponent mixtures by distillation require reliable vapour¬liquid equilibrium data. Since the experimental determination of multicomponent vapour-liqu¬id equilibrium data is laborious and time consuming, there is a need to use a predictive method for the liquid-phase activity coefficients. The abilities of Wilso and UNIQUAC equationsto predict isobaric quinary vapour-liquid equilibria using only binary constants of both equations were compared in this paper. The quinary system under study, is n. Hexane / Methylcyclopen¬tane I Cyclohexane / Benzene / Toluene. UNIQUAC equation was found to be superior in the prediction of quinary vapour-liquid equilibria with the R.M.S. Devications ranging from 0,0033- 0,0103 where as the Wilson equation could predict the quinary vapour phase with the accuracy of 0,0048-0,0104 R.M.S.D.

References

  • LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS
Year 1995, Volume: 41 , 0 - 0, 01.01.1995
https://doi.org/10.1501/Commub_0000000403

Abstract

References

  • LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS
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Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Article
Authors

Ülkü Özalp This is me

Publication Date January 1, 1995
Published in Issue Year 1995 Volume: 41

Cite

Vancouver Özalp Ü. LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS. Commun. Fac. Sci. Univ. Ank. Ser. B. 1995;41.

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

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